Investigação numérica do desempenho de um sensor de fibra ótica de índice de refração, baseado em SPR e utilizando COMSOL multiphysics

Esta tese é dedicada aos sensores de fibra ótica especificamente aos sensores baseados no fenómeno de ressonância de plasmão de superfície, SPR (Surface Plasmon Resonance), gerados em fibras óticas com configuração do tipo “D”, para aplicação em sensores refratométricos. Numa primeira parte desta dissertação são descritos os aspetos teóricos fundamentais para a compreensão dos fenómenos de ressonância de plasmões de superfície e a sua utilização em sistemas sensores. Estes fenómenos ocorrem na superfície de interface entre metais e outros meios materiais, sendo capazes de afetar as propriedades em reflexão e transmissão de uma onda eletromagnética incidente (feixe luminoso), de uma forma que é fortemente dependente dos meios na proximidade do metal. Assim, a medição das propriedades do feixe luminoso, como por exemplo o comprimento de onda de ressonância com SPR, permite monitorizar esses meios. Numa segunda fase foi implementada a simulação destes modelos, em COMSOL Multiphysics, que permitia não só a obtenção dos espetros de transmissão dos fenómenos de ressonância de plasmões de superfície, mas também a obtenção das distribuições do campo elétrico e magnético em função das dimensões do sensor. O COMSOL permitiu também a obtenção das curvas do deslocamento do comprimento de onda ressonante, perante variações do índice de refração exterior, da espessura do metal, da espessura da bainha e da espessura de outro elemento de elevado índice de refração. A fase seguinte foi verificar que os resultados dos métodos teóricos para os diferentes parâmetros de estudo eram semelhantes aos resultados obtidos no COMSOL. Conclui-se que com este programa é possível criar novos sensores em fibra ótica, baseados em SPR, para melhorar e otimizar os parâmetros de ressonância e sensibilidade do sensor. A última fase do trabalho baseou-se na modelização de uma fibra cuja configuração seja tal que possa criar um pequeno efeito de antena e fazer com que parte da luz seja guiada para o exterior da fibra e possa interatuar com o meio externo para melhor sensibilidade.

Portable smart films for ultrasensitive detection and chemical analysis using SERS and SERRS

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Espectro de Polariton de Plasmons e Ondas de Luz em Quasi-Cristais

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Preparação de vidros e vitrocerâmicas de óxidos de metais pesados contendo prata: propriedades ópticas, estruturais e eletroquímicas

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Identification of Rv3852 as a nucleoid-associated protein in Mycobacterium tuberculosis

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Chaotic thermalization in Yang-Mills-Higgs theory on a spacial lattice

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Y2O3:Eu3+ (5 mol%) with Ag nanoparticles prepared by citrate precursor

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Plasmonic Coupling in Er3+:Au Tellurite Glass

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Intersubband excitations at finite temperatures and their roles in different quasi-one-dimensional systems

We theoretically study many-body excitations in three different quasi-one-dimensional (Q1D) electron systems: (i) those formed on the surface of liquid Helium; (ii) in two coupled semiconductor quantum wires; and (iii) Q1D electrons embedded in polar semiconductor-based quantum wires. Our results show intersubband coupling between higher subbands and the two lowest subbands affecting even the lower energy intersubband plasmons on the liquid Helium surface. Concerning the second system, we show a pronounced extra peak appearing in the intersubband impurity spectral function for temperatures as high as 20 K. We finally show coupled intersubband plasmon-phonon modes surviving for temperatures up to 300 K.

Nanoscale manipulation of CdSe quantum dots in layer-by-layer films: influence of the host polyelectrolyte on the luminescent properties

Thioglycolic acid-capped Use quantum dots (QDs) were assembled on glass substrates with two distinct polyelectrolytes, viz poly(allylamine hydrochloride) (PAH) and poly(amidoamine) (PAMAM), generation 4 dendrimer, via the layer-by-layer (LbL) technique. Films containing up to 30 polyelectrolyte/QD bilayers were prepared. The growth of the multilayers was monitored with UV-vis spectroscopy, which showed an almost linear increase in the absorbance of the 2.8 nm QDs at 535 nm with the number of deposited bilayers. AFM measurements estimated a film thickness of 3 nm per bilayer for the PAH/Cdse films. The adsorption process and the optical properties of the PAMAM/CdSe LbL films were further analyzed layer-by-layer using surface plasmon resonance (SPR), from which a thickness of 3.2 nm was found for a PAMAM/CdSe bilayer. Photoluminescence measurements revealed higher photooxidation of the quantum dots in PAH/CdSe than in PAMAM/CdSe films. (c) 2004 Elsevier B.V. All rights reserved.

Analytic properties of thermal corrected boson propagators

We investigate the analytic properties of finite-temperature self-energies of bosons interacting with fermions at one-loop order. A simple boson-fermion model was chosen due to its interesting features of having two distinct couplings of bosons with fermions. This leads to a quite different analytic behavior of the bosons self-energies as the external momentum K-mu=(k(0),k) approaches zero in the two possible limits. It is shown that the plasmon and Debye masses are consistently obtained at the pole of the corrected propagator even when the self-energy is analytic at the origin in the frequency-momentum space.

Catechol biosensing using a nanostructured layer-by-layer film containing Cl-catechol 1,2-dioxygenase

dThe detection of aromatic compounds from pesticides and industrial wastewater has become of great interest, since these compounds withstand chemical oxidation and biological degradation, accumulating in the environment. In this work, a highly sensitive biosensor for detecting catechol was obtained with the immobilization of Cl-catechol 1,2-dioxygenase (CCD) in nanostructured films. CCD layers were alternated with poly(amidoamine) generation 4 (PAMAM G4) dendrimer using the electrostatic layer-by-layer (LbL) technique. Circular dichroism (CD) measurements indicated that the immobilized CCD preserved the same conformation as in solution. The thickness of the very first CCD layers in the LbL films was estimated at ca. 3.6 nm, as revealed by surface plasmon resonance (SPR). PAMAM/CCD 10-bilayer films were employed in detecting diluted catechol solutions using either an optical or electrical approach. Due to the mild immobilization conditions employed, especially regarding the pH and ionic strength of the dipping solutions, CCD remained active in the films for periods longer than 3 weeks. The optical detection comprised absorption experiments in which the formation of cis-cis muconic acid, resulting from the reaction between CCD and catechol, was monitored by measuring the absorbance at 260 nm after film immersion in catechol solutions. The electrical detection was carried out using LbL films deposited onto gold-interdigitated electrodes immersed in aqueous solutions at different catechol concentrations. Using impedance spectroscopy in a broad frequency range (1Hz-1kHz), we could detect catechol in solutions at concentrations as low as 10(-10) M. (c) 2005 Elsevier B.V. All rights reserved.

Efficient plasmonic coupling between Er3+:(Ag/Au) in tellurite glasses

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Infrared-to-visible upconversion in Yb3+/Er3+ co-doped PbO-GeO2 glass with silver nanoparticles

Enhanced frequency upconversion (UC) emission was studied in Yb3+/Er3+ co-doped PbO-GeO2 glass containing silver nanoparticles (NPs). Optical excitation was achieved with a laser operating at 980 nm in resonance with the Yb3+ transition F-4(5/2)-> F-4(7/2). The intensity of the whole UC spectrum from 400 to 700 nm was intensified due to the influence of silver NPs. The green and red emissions were enhanced by more than 300%. Emission bands centered at 408 nm and 480 nm were also detected corresponding to the H-2(9/2)-> I-4(15/2) and F-4(7/2)-> I-4(15/2) transitions of Er3+ ion. An intensity enhancement of approximate to 150% due to the NPs was measured. For the first time the influence of silver NPs on the blue emission of Yb3+/Er3+ co-doped PbO-GeO2 glass is reported. The large enhancement in the whole UC spectrum is due to the increased local field in the Er3+ ions locations and the proximity between the luminescence wavelengths and the NPs surface plasmon resonance. (C) 2010 Elsevier B.V. All rights reserved.

Metal-Organic Semiconductor Nanostructures for Surface-Enhanced Raman Scattering

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)