Mixing performance evaluation of additive manufactured milli-scale reactors

The mixing performance of three passive milli-scale reactors with different geometries was investigated at different Reynolds numbers. The effects of design and operating characteristics such as mixing channel shape and volume flow rate were investigated. The main objective of this work was to demonstrate a process design method that uses on Computational Fluid Dynamics (CFD) for modeling and Additive Manufacturing (AM) technology for manufacture. The reactors were designed and simulated using SolidWorks and Fluent 15.0 software, respectively. Manufacturing of the devices was performed with an EOS M-series AM system. Step response experiments with distilled Millipore water and sodium hydroxide solution provided time-dependent concentration profiles. Villermaux-Dushman reaction experiments were also conducted for additional verification of CFD results and for mixing efficiency evaluation of the different geometries. Time-dependent concentration data and reaction evaluation showed that the performance of the AM-manufactured reactors matched the CFD results reasonably well. The proposed design method allows the implementation of new and innovative solutions, especially in the process design phase, for industrial scale reactor technologies. In addition, rapid implementation is another advantage due to the virtual flow design and due to the fast manufacturing which uses the same geometric file formats.

Two “pillars” of cold-water coral reefs along Atlantic European margins: Prevalent association of Madrepora oculata with Lophelia pertusa, from reef to colony scale

The scleractinian coral Lophelia pertusa has been the focus of deep-sea research since the recognition of the vast extent of coral reefs in North Atlantic waters two decades ago, long after their existence was mentioned by fishermen. These reefs where shown to provide habitat, concentrate biomass and act as feeding or nursery grounds for many species, including those targeted by commercial fisheries. Thus, the attention given to this cold-water coral (CWC) species from researchers and the wider public has increased. Consequently, new research programs triggered research to determine the full extent of the corals geographic distribution and ecological dynamics of “Lophelia reefs”. The present study is based on a systematic standardised sampling design to analyse the distribution and coverage of CWC reefs along European margins from the Bay of Biscay to Iceland. Based on Remotely Operated Vehicle (ROV) image analysis, we report an almost systematic occurrence of Madrepora oculata in association with L. pertusa with similar abundances of both species within explored reefs, despite a tendency of increased abundance of L. pertusa compared to M. oculata toward higher latitudes. This systematic association occasionally reached the colony scale, with “twin” colonies of both species often observed growing next to each other when isolated structures were occurring off-reefs. Finally, several “false chimaera” were observed within reefs, confirming that colonial structures can be “coral bushes” formed by an accumulation of multiple colonies even at the inter-specific scale, with no need for self-recognition mechanisms. Thus, we underline the importance of the hitherto underexplored M. oculata in the Eastern Atlantic, re-establishing a more balanced view that both species and their yet unknown interactions are required to better elucidate the ecology, dynamics and fate of European CWC reefs in a changing environment.

Elemental Anisotropic Growth and Atomic-Scale Structure of Shape-Controlled Octahedral Pt–Ni–Co Alloy Nanocatalysts

Multimetallic shape-controlled nanoparticles offer great opportunities to tune the activity, selectivity, and stability of electrocatalytic surface reactions. However, in many cases, our synthetic control over particle size, composition, and shape is limited requiring trial and error. Deeper atomic-scale insight in the particle formation process would enable more rational syntheses. Here we exemplify this using a family of trimetallic PtNiCo nanooctahedra obtained via a low-temperature, surfactant-free solvothermal synthesis. We analyze the competition between Ni and Co precursors under coreduction “one-step” conditions when the Ni reduction rates prevailed. To tune the Co reduction rate and final content, we develop a “two-step” route and track the evolution of the composition and morphology of the particles at the atomic scale. To achieve this, scanning transmission electron microscopy and energy dispersive X-ray elemental mapping techniques are used. We provide evidence of a heterogeneous element distribution caused by element-specific anisotropic growth and create octahedral nanoparticles with tailored atomic composition like Pt1.5M, PtM, and PtM1.5 (M = Ni + Co). These trimetallic electrocatalysts have been tested toward the oxygen reduction reaction (ORR), showing a greatly enhanced mass activity related to commercial Pt/C and less activity loss than binary PtNi and PtCo after 4000 potential cycles.

Humanizing the facade of the public commercial building in a contemporary American culture

The projects studied for this thesis show that the more the façades match the values, tastes, and needs of its target individuals, the more frequently the place will be visited. They endow it with a sense of place and uniqueness and create an emotional bond with the individuals. The intent of this research was to derive a framework of principles to be used in the design of façades, and to establish a relationship between the facade, human scale, urban context, and building. The methodology for developing this framework is based on the analysis of building façades from the Renaissance to current examples of New York Times Square. The principles were generated from strategies of the case studies analyzed. Principles of monumentality, symbolism, and iconography were used to perceive façades as essential forms of architecture. The scale of facades emphasizes human dimensions. In turn, the façade is a device of communication to inform individuals, and its impact on retelling culture for a city.

Urban Agriculture Oriented towards Self-Supply, Social and Commercial Purpose: A Typology

Urban agriculture, a dynamic multifunctional phenomenon, affects the spatial diversification of urban land use, its valorization and its governance. Literature acknowledges its contribution to the development of sustainable cities. The dimension and extent of this contribution depends significantly on the particular form and function of urban agriculture. However, the complexity of interests and dimensions is insufficiently covered by theory. This paper proposes a typology for urban agriculture, supporting both theory building and practical decision processes. We reviewed and mapped the diversity of the types of agriculture found along three beneficial dimensions (self-supply, socio-cultural, commercial) for product distribution scale and actors. We distinguish between ideal types, subtypes and mixed types. Our intention is to include a dynamic perspective in the typology of urban agricultural land use because transition processes between types are observable due to the existence of complex motivations and influences. In a pilot study of 52 urban agriculture initiatives in Germany, we tested the validity of the typology and discussed it with stakeholders, proving novelty and relevance for profiling discussions.

Discards from experimental trammel nets in southern European small-scale fisheries

Trammel net discards in four southern European areas were considerable, with a total of 137 species (79.7% of the total) discarded 65, 105, 46 and 32 species in the Basque country (Spain), Algarve (Portugal), Gulf of Cadiz (Spain) and Cyclades islands (Greece), respectively. The overall discard rate in terms of catch numbers ranged from 15% for the Cyclades to 49% for the Algarve, with the high discard rate for the latter due largely to small pelagic fishes. Discards in the four areas consisted mainly of Trisopterus luscus (Basque country), Scomber japonicus (Algarve), Torpedo torpedo (Cadiz) and Sardina pilchardus (all three areas), and Diplodus annularis in the Cyclades. Strong seasonal variation in discarding was found, reflecting differences in metiers and the versatility of trammel nets as a gear. Discarding, both in terms of numbers of species and individuals decreased with increasing inner panel mesh size. The main reasons for discarding were: (1) species of no or low commercial value (e.g. Scomber japonicus; Torpedo torpedo), (2) commercial species that were damaged or spoiled (e.g. Merluccius merluccius), (3) undersized commercial species (e.g. Lophius piscatorius), and (4) species of commercial value but not caught in sufficient quantities to warrant sale (e.g. Sardina pilchardus). A decrease in soak time together with the appropriate choice of mesh sizes could contribute to a reduction in discarding and to improved sustainability and use of scarce resources in the small-scale, inshore multi-species fisheries of southern Europe. (C) 2007 Elsevier B.V. All rights reserved.

Size selectivity of trammel nets in southern European small-scale fisheries

Trammel net size selectivity was studied for the most important metiers in four southern European areas: the Cantabrian Sea (Atlantic, Basque Country, Spain), the Algarve (Atlantic, southern Portugal), the Gulf of Cadiz (Atlantic, Spain) and the Cyclades Islands (Mediterranean, Aegean Sea, Greece). These metiers were: cuttlefish (Sepia officinalis) and soles (Solea senegalensis, Microchirus azevia, Synaptura lusitanica) in the Algarve and the Gulf of Cadiz, sole (Solea solea) in the Cantabrian Sea and mixed fin-fish in the Cyclades. In each area, experimental trammel nets of six different types (combinations of two large outer panel mesh sizes and three small inner panel meshes) were constructed. Fishing trials were carried out on a seasonal basis (four seasons in the Cantabrian Sea, Algarve and Cyclades and two seasons in the Gulf of Cadiz) with chartered commercial fishing vessels. Overall, size selectivity was estimated for 17 out of 28 species for which sufficient data were available. Trammel nets generally caught a wide size range of the most important species, with length frequency distributions that were skewed to the right and/or bi-modal. In many cases the length frequency distributions of the different nets were highly overlapped. The Kolmogorov-Smirnov test also showed that the large outer panel meshes generally had no effect in terms of size selectivity, while the opposite was true for the small inner panel ones. Six different selectivity models (normal scale, normal location, gamma, log-normal, bi-modal and gamma semi-Wileman) were fitted to data for the most abundant species in the four areas. For fish, the bi-modal model provided the best fits for the majority of the data sets, with the uni-modal models giving poor fits in most cases. For Sepia officinalis, where trammelling or pocketing was the method of capture in 100% of the cases, the logistic model fitted by maximum likelihood was judged to be more appropriate for describing the size selective properties of the trammel nets. Our results, which are among the first ones on trammel net selectivity in European waters, will be useful for evaluating the impacts of competing gear for the socio-economically important small-scale static gear fisheries. (c) 2006 Elsevier B.V All rights reserved.