Aplicação de técnicas eletroquímicas na determinação do potencial de corrosividade de ligas de alumínio em água produzida

The resistance of aluminum and their alloys, to the corrosion phenomenon, in aqueous solutions, is a result of the oxide layer formed. However, the corrosion process in the aluminum alloy is associated with the presence a second phase of particles or the presence of chloride ions which promote the disruption of the oxide layer located producing the corrosion process. On the other hand, the term water produced is used to describe the water after the separation of the oil and gas in API separators. The volumes of produced water arrive around 5 more times to the volume of oil produced. The greatest feature of the water is the presence of numerous pollutants. Due to the increased volume of waste around the world in the current decade, the outcome and the effect of the discharge of produced water on the environment has recently become an important issue of environmental concern where numerous treatments are aimed at reducing these contaminants before disposal. Then, this study aims to investigate the electrochemical corrosion behavior of aluminum alloy 6060 in presence of water produced and the influence of organic components as well as chloride ions, by using the electrochemical techniques of linear polarization. The modification of the passive layer and the likely breakpoints were observed by atomic force microscopy (AFM). In the pit formation potential around -0.4 to -0.8 V/EAg/AgCl was observed that the diffusion of chloride ions occurs via the layer formed with the probable formation of pits. Whereas, at temperatures above 65 °C, it was observed that the range of potential for thepit formation was -0.4 to -0.5 V/EAg/AgCl. In all reactions, the concentration of Al(OH)3 in the form of a gel was observed

Influência da corrente de pulso, do tempo de pulso e diâmetro de gota sobre a estabilidade da transferência metálica no processo MIG-P

To obtain a process stability and a quality weld bead it is necessary an adequate parameters set: base current and time, pulse current and pulse time, because these influence the mode of metal transfer and the weld quality in the MIG-P, sometimes requiring special sources with synergistic modes with external control for this stability. This work aims to analyze and compare the effects of pulse parameters and droplet size in arc stability in MIG-P, four packets of pulse parameters were analysed: Ip = 160 A, tp = 5.7 ms; Ip = 300 A and tp = 2 ms, Ip = 350 A, tp = 1.2 ms and Ip = 350 A, tp = 0.8 ms. Each was analyzed with three different drop diameters: drop with the same diameter of the wire electrode; droplet diameter larger drop smaller than the diameter of the wire electrode. For purposes of comparison the same was determined relation between the average current and welding speed was determined generating a constant (Im / Vs = K) for all parameters. Welding in flat plate by simple deposition for the MIG-P with a distance beak contact number (DBCP) constant was perfomed subsequently making up welding in flat plate by simple deposition with an inclination of 10 degrees to vary the DBCP, where by assessment on how the MIG-P behaved in such a situation was possible, in addition to evaluating the MIG-P with adaptive control, in order to maintain a constant arc stability. Also high speed recording synchronized with acquiring current x voltage (oscillogram) was executed for better interpretation of the transfer mechanism and better evaluation in regard to the study of the stability of the process. It is concluded that parameters 3 and 4 exhibited greater versatility; diameters drop equal to or slightly less than the diameter of the wire exhibited better stability due to their higher frequency of detachment, and the detachment of the drop base does not harm the maintenance the height of the arc

Avaliação da fissuração por fadiga em tubos durante transporte marítimo

Tubos de aço são transportados diariamente em todo o mundo, por caminhão, trem ou navio. Conseqüentemente, danos de transporte, podem ocorrer com freqüência e regularidade. O tipo de dano particular selecionado para este estudo foi o de trinca por fadiga, o qual é considerado como um dos mais críticos. Neste trabalho foram estudados tubos de aço fabricados de acordo com os requisitos da norma API 5L [1]. Foram efetuadas caracterizações químicas, mecânicas e metalográficas de um tubo com diâmetro 609,6 mm e espessura 15,87 mm grau X-65. A simulação do transporte por navio de tubos de aço foi feita submetendo-se seções de tubo com comprimento igual a 0,1 metro, a ciclos de fadiga por meio de máquina servo-hidráulica. Foi possível concluir que em tubos soldados, a região adjacente ao cordão de solda é a mais crítica, e que quando o posicionamento do tubo na carga é efetuado de maneira que a solda fique apoiada sobre alguma superfície rígida, a ocorrência de trinca por fadiga torna-se possível principalmente se os procedimentos de manuseio, carregamento e transporte não forem executados da maneira como recomendada pelos fabricantes de tubos e pela norma API [2].

Radiografia digital para inspeção de soldas de dutos - melhor sensibilidade

The conventional radiographic technique using industrial radiographic films is with the days finishing. The Digital Radiography is taking place in several sectors, e.g., the medical, aerospace, security, automotive, etc. In addition to representing a technological trend, it has been demonstrated that digital radiography offers a series of benefits in terms of productivity, sensitivity, environmental aspects, image treatment tools, cost reduction, etc. If one weld seam to be inspected is from a serried product, as example a pipe, the best option to be implemented is the Flat Panel Detector with this equipment is possible to reduce the obtaining digital radiographic images in place of films and reducing the inspection cycle time due to its high degree of automation. In the experiments described in this paper this new technique was tested and the results were compared with those obtained by the conventional radiography. The welded specimens were prepared using the submerged-arc welding process and small artificial cracks of the most varied dimensions, present in the specimens, were used to establish a comparison of the sensitivities presented by the techniques employed After conducting several experiments, the digital method presented the highest sensitivity to the wire-type Image Quality Indicator (IQI) and in the detection of small defects, leading to the conclusion that the use of digital radiography using the flat-panel detector offers advantages over the conventional technique [1, 2]. This work was carried out based on the API 5L Edition 2004 [3] and ISO 3183 Edition 2007 [4] specifications.

Red Mud from Brazil: Thermal Behavior and Physical Properties

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Microestrutura e resistência à corrosão do Ti c.p. soldado a laser utilizando em prótese sobre implantes

Foram realizados estudos para avaliar a microestrutura, a dureza e a resistência à corrosão do titânio comercialmente puro-Ti c.p. soldado por laser e utilizado na confecção de prótese sobre implantes. Verificou-se que na soldagem a laser a microestrutura apresentou três regiões distintas: o cordão de solda, a zona afetada pelo calor - ZAC e o metal base. O Ti c.p. possui microestrutura granular, a microestrutura do cordão de solda é mais refinada e de maior dureza do que o metal base. A ZAC obtida por este processo de soldagem foi relativamente pequena quando comparada com o processo de soldagem por brasagem. Os ensaios eletroquímicos mostraram que a região da solda apresentou menor resistência à corrosão em meio de NaCl 0,15 molL-1 à temperatura ambiente.

Estudo microestrutural e resistência à corrosão de uma liga de Au soldada a laser, empregada em prótese sobre implantes

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Investigação da Interface Metal-Porcelana da Liga Ni-Cr-Mo Soldada a LASER

The interface formed between the metal and the porcelain of a LASER welded Ni-Cr-Mo alloy was studied. The characterization was carried out through optical microscopy, scanning electron microscopy, X-ray dispersive spectroscopy-EDS and mechanical testing by three-point flexion test-TPE in the region LASER welded with and without the porcelain. The porcelain adhesion with the alloy alone is possible after the oxidation of the metallic surface and subsequent application of an adhesive called opaco. The applied porcelain, on the base metal and fusion zone presented some distinct behaviors. After the TPF test the base metal presented fractures while that in the fusion zone was completely gone. One noticed that the region submitted to the LASER welding showed less porcelain adhesion than the region of the base metal due to the microestructural refinement of the fusion zone. These results can be evidenced by the EDS of the studied regions. The TPF had demonstrated that the Ni-Cr-Mo alloy submitted to the LASER welding, undergone significant alterations in its mechanical properties after the application of the porcelain.

Uma comunidade sucessional dominada por Pteridium aquilinum ( L.) Kuhn. no município de Lavras, estado de Minas Gerais

Numa área situada no município de Lavras, MG, o desmatamento realizado há cerca de dez anos propiciou a formação de uma comunidade infestante dominada por Pteridium aquilium (L.) Khun., te ndo como codominantes Imperara brasiliensis Trin. e Andropogon bicornis L.. Como fatores que mantém esta comu nidade devem ser considerados: a) as queimadas intermiten te s; b) a acidez do solo; c) a alta percentagem de saturação de aluminio ; d) a ação fitotóxica do próprio P. aquilinum; e) a falta de palatabilidade das espécies dominantes.

Avaliação da resistência à corrosão de aços inoxidáveis com Nb endurecíveis por precipitação

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Estudo Comparativo de Juntas Soldadas a TIG e Laser Empregando-se Ti com Pureza Comercial Utilizado em Prótese sobre Implantes

Welding in the dentistry has been used for great part of the specialized dentist-surgeons in the implants area to solve prosthesis supported by implant adaptation problems. The development of new equipments Laser and TIG allowed a larger use of these processes in the prosthesis production. In this work, it was studied welded joints made by Laser and TIG, using commercial purity titanium, cpTi, applied in prosthesis supported by implants. The weld characterizations were carried out by light microscopy, EDS_elementary mapping, microhardness and tensile test. Through metallographic characterization, the weld bead presented a martensitic microstructure in the Laser welding process, originated from shear provoked by deformations in the lattice. This caused structural changes of the transformed area, which determines a fine plate-like morphology. In the weld bead from TIG, besides presenting higher hardness, was observed formation of Widmansttaten structure, which is characteristic of a geometric model, resulted of new phase formation along of the crystallographic plans. The martensitic structure is more refined than Widmansttaten structure, due to the high-speed cooling (10(3)degrees C/s) imposed by the Laser process.

Metodología y estimación del índice de producción industrial de Jujuy. Un aporte a la cuantificación de los objetivos de desarrollo del milenio

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América Latina: las exportaciones de productos básicos durante los años noventa

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Estrategia de desarrollo de clusters basados en recursos naturales: el caso de la bauxita en el norte de Brasil

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Silício na tolerância ao alumínio por plantas de arroz

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)