Lithium-lanthanum double chromates

Synthesis and crystallographic data are reported for low and high temperature forms of LiLa(CrO4)2. The compounds are closely related to lamellar rare earth phosphates and arsenates of sodium and to RbLu(CrO4)2. Lattice parameters of the orthorhombic (low temperature) and monoclinic (high temperature) forms are given. The low temperature form is moisture sensitive and Li+ ions are easily displaced by protons. Thermal decomposition takes place at 250 °C and results in the formation of LiCrO2, LaCrO4, LaCrO3 and Cr2O3. © 1993.

Particle growth during calcination of polycation oxides synthesized by the polymeric precursors method

The particle-growth kinetics of sodium niobate and zirconium titanate powders that were processed by the polymeric precursors method were studied. The growth kinetics that were studied for the particle, in the final stage of crystallization, showed that the growth process occurs in two different stages. For temperatures <800°C, the particle-growth mechanism is associated with surface diffusion, with an activation energy in the range of 40-80 KJ/mol. For temprratures >800°C, particle growth is controlled by densification of the nanometric particle cluster and by a neck-size-controlled particle-growth mechanism. The results suggest that this behavior was typical of the synthesis method, because two different polycation oxides presented the same behavior.

Electric and magnetic properties of polymer electrolyte/carbon black composites

Measurements of 1H Nuclear Magnetic Resonance (NMR) relaxation times, Electron Paramagnetic Resonance (EPR) and AC Impedance Spectroscopy (IS) are reported for composites based on PEO8:LiClO4 and carbon black (CB), prepared by two methods: solvent and fusion processing. Three nuclear relaxation processes were identified for 1H nuclei: (i) belonging to the polymer chains in the amorphous phase, loosely bound to the CB particles, whose dynamics is almost the same as for unfilled polymer, (ii) belonging to the polymer chains which are tightly attached to the CB particles, and (iii) belonging to the crystalline phase in the loose polymer chain. The paramagnetic electronic susceptibility of the composite samples, measured by EPR, was interpreted by assuming a contribution of localized spin states that follow a Curie law, and a Pauli-like contribution of delocalized spins. A significant change of the EPR linewidth was observed at 40 K, which is the temperature where the Curie and Pauli susceptibilities equally contribute to the paramagnetic electronic susceptibility. The electrical properties are very sensitive to the preparation methods of the composites, which conditions the interaction between carbon particle-carbon particle and carbon particle-polymer chain. Classical statistic models to describe the conductivity in these media were not satisfactory. © 1998 Published by Elsevier Science B.V. All rights reserved.

Effect of atmosphere and dopants on sintering of SnO2

Tin oxide is an n-type semiconductor material with a high covalent behavior. Mass transport in this oxide depends on the surface state promoted by atmosphere or by the solid solution of a non-isovalent oxide doping The sintering and grain growth of this type of oxide powder is then controlled by atmosphere and by extrinsic oxygen vacancy formation. For pure SnO2 powder the surface state depends only on the interaction of atmosphere molecules with the SnO2 surface. Inert atmosphere like argon or helium promotes oxygen vacancy formation at the surface due to reduction of SnO2 to SnO at the surface and liberation of oxygen molecules forming oxygen vacancies. As consequence surface diffusion is enhanced leading to grain coarsening but no densification. Oxygen atmosphere inhibits the SnO2 reduction decreasing the surface oxygen vacancy concentration. Addition of dopants with lower valence at sintering temperature creates extrinsic charged oxygen vacancies that promote mass transport at grain boundary leading to densification and grain growth of this polycrystalline oxide.

Investigation of New Ion Conducting Ormolytes Silica-Polypropyleneglycol

Two groups of hybrid organic-inorganic composites exhibiting ionic conduction properties, so called ORMOLYTES (organically modified electrolytes), have been prepared by the sol-gel process. The first group has been prepared from mixture of a lithium salt and 3-isocyanatopropyltriethoxysilane(IsoTrEOS),O,O′-bis(2-aminopropyl) polypropyleneglycol. These materials produce chemical bonds between the organic (polymer) and the inorganic (silica) phases. The second group has been prepared by an ultrasonic method from a mixture of tetraethoxysilane (TEOS), polypropyleneglycol and a lithium salt. The organic and inorganic phases are not chemically bonded in these samples. The Li+ ionic conductivity, σ, of all these materials has been studied by AC impedance spectroscopy up to 100°C. Values of σ up to 10-6 Ω-1·cm-1 have been found at room temperature. A systematic study of the effects of lithium concentration, polymer chain length and the polymer to silica weight ratio on σ shows that there is a strong dependence of σ on the preparation conditions. The dynamic properties of the Li+ ion and the polymer chains as a function of temperature between -100 and 120°C were studied using 7Li solid-state NMR measurements. The ionic conductivity of both families are compared and particular attention is paid to the nature of the bonds between the organic and inorganic components.

Oxygen related defects excitation and photoconductivity dependence of SnO2 sol-gel films with several light sources

Since oxygen vacancies act as donors in SnO2, the electrical properties are related to deviation from stoichiometric composition. Depending on stoichiometry SnO2 can be highly insulating or may exhibit fairly high n-type conductivity. Since bandgap transitions are in the ultraviolet range, its photoconductivity is strongly dependent on the excitation source. We have measured variation of photoconductivity excitation with wavelength for tin dioxide grown by dip-coating sol-gel technique using several light sources: tungsten lamp, xenon, mercury and deuterium, and present selected results. The main band is obtained in the range 3-4eV according to light source spectrum in the ultraviolet range. The presence of oxygen in the cryostat also affects the spectrum since electron-hole pairs react with adsorbed oxygen specimens. © 1999 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint.

Influência de Manejos de irrigação sobre aspectos de Ecofisiologia e de produção da videira cv. Syrah / Paulsen 1103

O manejo de irrigação pode influenciar o comportamento ecofisiológico e a produção da videira. O objetivo desse trabalho, conduzido em 2010 em Petrolina – PE, no Submédio do Vale do São Francisco, foi avaliar a influência de diferentes estratégias de manejo de irrigação no potencial de água na folha e em aspectos qualitativos e quantitativos das uvas do primeiro ciclo de produção da videira cv. Syrah/Paulsen 1103. O sistema de irrigação utilizado foi gotejamento e a lâmina de água foi estimada com base na evapotranspiração da cultura. O delineamento experimental utilizado foi o de blocos casualizados, em 4 repetições e com 3 tratamentos: irrigação plena, realizada durante todo o ciclo de produção; a irrigação com déficit, onde a aplicação de água foi interrompida na fase fenológica de cacho fechado; e a irrigação com déficit controlado, onde a irrigação, também interrompida na fase de cacho fechado, foi eventualmente realizada após a interrupção, de acordo com o monitoramento da água no solo. A imposição de déficit hídrico às plantas favoreceu uma maior concentração de açúcares e a redução da acidez nos frutos, contribuindo para a melhoria da qualidade das uvas para vinificação.

Fertilizantes orgânicos e resíduo de bauxita na disponibilidade de nutrientes e nutrição da cana-de- açúcar irrigada com água potável e residuária

The objective of this study was to evaluate the effect of organic fertilizers (urban solid waste and swine manure) as a source of nutrients and residue from bauxite processing as a corrective of soil acidity, in area cultivated with sugar cane irrigated with potable water and served in the availability of phosphorus (P), potassium (K), calcium (Ca), magnesium (Mg) and sulfur (S) levels in the soil and plants. For this experiment was carried out in pots, using a Alfisol, assessing the availability of the elements in the 0-20 cm layer and the concentration of these nutrients in the leaves of sugarcane. The data showed that the residues increased the concentrations of Ca and Mg in soil, as the concentration of K was not changed and S was not detected, due to the low concentration in the soil. In the leave +1 of sugarcane the residue of bauxite increased levels of N, P, K, Ca and Mg (15.68, 1.73, 10.43, 3.50 and 1.08 g kg-1, respectively). The application of urban solid waste and swine manure also increased the levels of N, K and Ca (11.56, 9.18 and 2.81 g kg-1, respectively). The quality of irrigation water did not alter the availability of P, K, Ca, Mg and S in the soil as well as the levels of these macronutrients in the plant.

Design of biogas pipeline - Energy and sanitation

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Growth of calcium phosphate coating on Ti-7.5Mo alloy after anodic oxidation

Titanium and its alloys are widely used as biomaterials due to their mechanical, chemical and biological properties. To enhance the biocompatibility of titanium alloys, various surface treatments have been proposed. In particular, the formation of titanium oxide nanotubes layers has been extensively examined. Among the various materials for implants, calcium phosphates and hydroxyapatite are widely used clinically. In this work, titanium nanotubes were fabricated on the surface of Ti-7.5Mo alloy by anodization. The samples were anodized for 20 V in an electrolyte containing glycerol in combination with ammonium fluoride (NH4F, 0.25%), and the anodization time was 24 h. After being anodized, specimens were heat treated at 450 °C and 600°C for 1 h to crystallize the amorphous TiO2 nanotubes and then treated with NaOH solution to make them bioactive, to induce growth of calcium phosphate in a simulated body fluid. Surface morphology and coating chemistry were obtained respectively using, field-emission scanning electron microscopy (FEG-SEM), AFM and X-ray diffraction (XRD). It was shown that the presence of titanium nanotubes induces the growth of a sodium titanate nanolayer. During the subsequent invitro immersion in a simulated body fluid, the sodium titanate nanolayer induced the nucleation and growth of nano-dimensioned calcium phosphate. It was possible to observe the formation of TiO2 nanotubes on the surface of Ti-7.5Mo. Calcium phosphate coating was greater in the samples with larger nanotube diameter. These findings represent a simple surface treatment for Ti-7.5Mo alloy that has high potential for biomedical applications. © (2013) Trans Tech Publications, Switzerland.

Processo de obtenção de vinagre de gengibre

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Efeito da escória de siderurgia na nutrição e desenvolvimento inicial de eucalipto

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Composição dos tubérculos, extração e caracterização de amidos de diferentes cultivares de batata

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Fertilizante nitrogenado alternativo na produção de matéria seca, nutrientes da parte aérea e atributos químicos do solo da Brachiaria brizantha cv. Xaraés

Pós-graduação em Ciência Animal - FMVA

Doses e fontes de fertilizantes nitrogenados e seus efeitos nos atributos químicos do solo, produção e estado nutricional da Brachiaria brizantha cv. Xaraés

Pós-graduação em Ciência Animal - FMVA