Estudo do transporte eletrônico em nanoestruturas baseadas em carotenoides e tétrades com fulereno C60

Neste Trabalho é apresentado um estudo teórico da estrutura eletrônica de uma molécula de fulereno C60 com junções em quatro terminais baseados em grupos doadores de elétron – etratiofulvaleno (TTF) – e grupos aceitadores de elétrons – fenilpropanodinila (FPP) e dispositivos moleculares baseados em derivados dos Carotenoides. O mecanismo de transporte investigado para os derivados dos Carotenoides foram utilizados para o melhor entendimento das curvas de Fowler- Nordheim (FN) e Millikan-Lauritsen (ML) para os sistemas baseados em fulereno C60. Em todos os casos foi possível confirmar que a análise empírica de Millikan-Lauritsen (ML) também é suficiente para descrever em todos os aspectos a espectroscopia de voltagem de transição (TVS). Para estudar os sistemas, foram feitas otimizações de geometria sistematicamente e observado uma transferência eletrônica calculada por métodos derivados de Hartree-Fock e Teoria do Funcional Densidade (DFT). Os resultados apresentados mostram um estudo detalhado do rearranjo de carga molecular para a estrutura, que sob a ação de um campo elétrico externo apontou que o transporte de carga está diretamente ligado ao tipo de junção que esse sistema é submetido de forma que a voltagem aplicada é intensa o bastante para criar um potencial de saturação nos sistemas em estudo: fulereno C60 com três terminais de tetratiofulvaleno e um terminal de fenil-propanodinila (C60-(TTF)₃-FPP); fulereno C60 com quatros terminais de fenil-propanodinila (C60-(FPP)₄). Os resultados mostram que se tem um retificador molecular que pode trabalhar corretamente como um retificador macroscópico.

Desenvolvimento de sistema para verificação metrológica de transformadores de corrente IN SITU em sistemas de alta tensão utilizando transdutor óptico

Este trabalho apresenta o desenvolvimento e a aplicação em campo de um sistema para verificação metrológica de transformadores de corrente em alta tensão. O sistema foi desenvolvido utilizando como premissas básicas a portabilidade e a confiabilidade metrológica, de tal forma que pudesse ser facilmente transportado e instalado, sem interrupção do fornecimento de energia elétrica nem o uso de infraestrutura complexa de transporte e montagem. O sistema utiliza como padrão de referência um transdutor ótico, cujo sensor mede a corrente elétrica do primário do transformador de corrente a ser verificado através do efeito magneto-ótico de Faraday. Ele também é composto por outros instrumentos padrão que medem a corrente elétrica do secundário do transformador de corrente sob verificação, e realizam a comparação entre esta e o sinal da saída do transdutor ótico padrão. Foram realizados ensaios em laboratório e em campo. Os ensaios em campo foram realizados em duas subestações em Belém/PA, visando avaliar a correta operação do sistema em condições de alta tensão e alta corrente. Os ensaios foram realizados em seis transformadores de corrente conectados em 230 kV, em condições médias de carga, e obtiveram resultados satisfatórios.

Estudo da formação de gelo não detectável em aeronaves de transporte

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Particle swarm optimization aplicada ao planejamento da expansão de sistemas de transmissão

Pós-graduação em Engenharia Elétrica - FEIS

Avaliação da erosão hídrica, transporte de sedimentos e qualidade da água na bacia do córrego Monjolo Grande

Understanding the linkages between the natural elements is essential for being promoted the land use, occupation and sustainable management of environmental systems. Universal Soil Loss Equation (USLE), as a predictive model of erosion, is important to allowing the prevention of possible environmental impacts which may drastically interfere in natural or anthropic environments, as well as prevent potential financial wastes and even contribute to greater efficiency of agricultural production. This research will be working some USLE parameters, emphasizing topographic factor from Ribeirão Monjolo Grande watershed. Among the factors considered by the USLE, the Topographic Factor interferes directly in the erosive dynamic of a watershed because it involves variables related to hydrological processes that occur on it. In this research, were discussed different methods for obtaining the Topographic Factor (BERTONI e LOMBARDI NETO, 1985; MOORE e BURCH, 1986; DESMET E GOVERS, 1996) in GIS environment. After comparison between the methods, was indicated that best represents the conditions of geometry strand of the study area. Finally, other factors (R, K, C, P) considered by the USLE were obtained. The attainment of these parameters were guided by the use of geotechnologies, especially in Geographic Information Systems (GIS), with the assistance of secondary data and periodic field visits. The results obtained contributed to the understanding of hydrosedimentological dynamic in this area and serve as a viable strategy for studies of soil loss, aiming at developing consistent material for future researches about environmental planning and land management

Priorização de alternativas para melhoria do transporte aéreo de passageiros no eixo Rio-SP

Este trabalho estuda uma aplicação de um Método Multicritério (AHP do inglês Analytic Hierarchy Process) para analisar os problemas do congestionamento do tráfego aéreo nos aeroportos brasileiros, focando-se na ponte São Paulo-Rio de Janeiro. Primeiramente com um estudo em grupo mediante comparação em pares e posteriormente mediante um estudo individual com ratings. O objetivo deste trabalho será obter a alternativa mais adequada para os interesses do tráfego aéreo de Brasil

O transporte coletivo urbano em São José do Rio Preto - SP e sua relação com as transformações do espaço urbano

The process of urbanization that happened in Brazil during the twentieth century led to processes of structuring and re-organization of space, besides the emergence of many urban problems. Industrialization and urbanization are some of the main causes that could be cited as consequences of this process. As a result of the steep rise of cities, the transport systems became fundamental in boosting flows (immaterial) and the mobility of people and stuff (materials) in the territory. The urban model created for the city of São Paulo in the 1930s was repeated over the years in the medium-sized cities, being repeated the same problems that occurred in the metropolis. In this context our work fits in analyzing the changes occurring in the urban area of São José do Rio Preto - SP, from his relationship with the public transportation system in the face of intra-urban spatial configuration of the city. Transport, while it is recognized by authors as being really important for the analysis and intra-urban spatial configuration, has been little analyzed as the object of study by a geographer, and so, our work has more value

Desenvolvimento de conexões hidráulicas: aplicação em sistemas de basculamento de cabines de caminhões no mercado brasileiro

The main goal of this thesis is to describe in details the development and manufacturing of hydraulic fittings for application in truck's cabin tilting lines, covering all of the pre-project, drawing, quotation and supplying processes. This development was planned due to Eaton Corporation - Hydraulics Group's interest in competing on this market with this kind of application. Company's standard procedures were executed until the final supplying stage could be reached. Moreover, the year in which this project was conducted was ruled by a crisis in the automotive segment and new opportunities had to be pursued and developed. Eaton's USA, India and China (facilities located in Aurora, Pune and Shanghai, respectively) engineering team offered all the support in order for this project to come true. As a result there are new part numbers in the company's portfolio, which now offers new fittings and a new type of adapter that was unknown prior to the project. This way Eaton has conquered even more space with this cabin tilting application and the customers (OEMs) have an alternative and homologated supplier to purchase from. Financially speaking, the project's sales income may vary from US$800,000.00 to US$1,300,000.00 worth during the following supplying years

Avaliação da construção e operação de técnicas compensatórias de drenagem urbana: o transporte de finos, a capacidade de infiltração, a taxa de infiltração real do solo e a permeabilidade da manta geotêxtil

This work aimed to evaluate some aspects of construction and operation of full-scale best management practices and their effects on infiltration loading rate. Two systems were studied: i) filter-swale-trench (FST) and ii) infiltration well (IW). In these units, field essays and full-scale measurements were made in order to assess the soil permeability. Further, the fine particles transportation and the geotextile blanket permeability were determined before and after operation. The results pointed out that there were soil transportation to inside the FST and IW systems, despite of the installed protections, and that these material were responsible for diminishing the geotextile (reduction from 30 to 90% for FST and 40 to 70% for IW) and the full-scale infiltration loading rates (varying from 4,7 x 10-6 to 10-5 m.s-1).

Avaliação da erosão hídrica e transporte de sedimentos através do modelo hidrossedimentológico SWAT (Soil and Water Assessment Tool)

Pós-graduação em Geociências e Meio Ambiente - IGCE

Análise energética de sistemas de produção de etanol de mandioca, cana-de-açúcar e milho

The objective of this work was the analysis of the energetic ethanol production systems using as source of carbohydrates, manioc, sugar cane and maize crops. The searches were carried from the field in the Paranapanema River Valley, state of Sao Paulo in the operations of cultivation and industrial processing of raw materials for analysis. The expenditure of energy concerning the agricultural part was made by the energy consumption of stage production of one hectare of sugar cane, cassava and corn, tillage and planting procedure, inputs, driving the crop, harvest, transport industry and energy draining. The expenditure of energy referring to the part was made by the industry energy consumption of stage processing of one tonne of sugar cane, cassava and corn, in the operations of disintegration / milling, hydrolysis / treatment of the broth, fermentation, distillation and maintenance of equipment. Under the system of agronomic production of raw materials, manioc presented an energy expenditure below that of sugar cane and maize (9,528.33 MJ ha-1; 14,370.90 MJ ha-1 and 15,633.83 MJ ha-1, respectively). For the ethanol produced, the operations of cultivation has consumed 1.54 MJ l-1 with manioc; MJ 1.99 l-1 with sugar cane, and 7.9 MJ l-1 with the corn. In the industrial processing of a ton of raw material, sugar cane presented an energy cost less than the cassava and maize (1,641.56 MJ t-1; 2,208.28 MJ t-1 and MJ 3,882.39 t-1, Respectively), however, showed a higher cost than when they related to ethanol produced (19.38 MJ l-1; 11.76 MJ l-1 and 11.76 MJ l-1, respectively). In the final energy balance for each megajoules of energy invested in sugar cane were required 1.09 MJ (9%), for each megajoules of energy invested in manioc were required 1.76 MJ (76%) and for each megajoules energy invested in maize were required 1.19 MJ (19%). Overall, it appears that the manioc consumes less energy than sugar cane and corn crops in the process of agribusiness obtaining ethanol.

Avaliação de sistemas de manejo de palhiço de cana-de-açúcar no campo e na indústria

This work presents and it evaluates the systems of crop of sugar-cane trash for energy ends, through studies accomplished in three industries of sugar and alcohol, of the State of São Paulo, as withdrawal in the field and crop partially integral with separation of the trash in the industry (cleaning the dry). it is Treated of a development of opportunities, because only when there is pulp shortage it is that remembers the energy use of the trash, which presents a larger cost for equivalent ton in energy again that the pulp of the sugar-cane, that already has a very spread trade in the section the sugar and alcohol. Another factor that should be outstanding is the environmental, because the Environmental Protocol exists, sanctioned by most of the producing of sugar-cane, that reduces the period for elimination burned of the sugar-cane before the crop implanted by the Law 11.241 of 2002. However it is important to highlight that the crop of the sugar-cane without it burns her previous, it increases the difficulty in the combat the pest denominated “cigarrinha-da-raiz”, turning necessary the retreat of part of the trash non beneficial for the soil, contributing like this, with the practice of removal of the trash for energy use. Of the obtained results it is ended that the most interesting modality economically, was the separation of the trash in the industry and that for better efficiency, the sugar-cane should go by a double process of blowing for cleaning, pointing out, however, that there was reduction of the capacity of transport of the sugar-cane as adult was the amount of trash partially in the crop integral.

Análisis experimental y teórico de diversas propiedades termofísicas de sistemas ternarios compuestos de glimes alcoholes y DI-N-Butiléter, y de sus componentes binarios

Programa de doctorado: Química Ambiental y Ecológica

Análisis del comportamiento de los viajeros del transporte interurbano en la isla de Gran Canaria

Máster Universitario en Sistemas Inteligentes y Aplicaciones Numéricas en Ingeniería (SIANI)

Monitorización del transporte de cantos y caracterización morfológica de la Playa de San Felipe (Gran Canaria)

[ES]Uno de los principales efectos de la subida del nivel del mar es el aumento de la erosión costera. Las Islas Canarias tienen una longitud de costa de 1554 km, de los cuales 10% corresponden a playas de cantos y mixtas. Debido a la inexistencia de trabajos en este tipo de sistemas en el archipiélago canario, el objetivo de esta tesis es realizar un seguimiento de los cantos en la playa de San Felipe, Gran Canaria, mediante la tecnología RFID. Además, se desarrollarán los modelos morfodinámicos de evolución lo que permitirá comprender los patrones de respuesta de las playas de cantos frente al clima marítimo y así tratar de proteger nuestras costas a corto y largo plazo.