The effect of acidity on olefin aromatization over potassium modified ZSM-5 catalysts

The transformation of olefin to aromatics over ZSM-5 catalysts with different K-loadings has been investigated both in a continuous flow fixed-bed reactor and in a pulse microreactor. Investigation of variation of olefin aromatization activity with K-loadings shows that strong acid sites are indispensable for the converting of olefin to aromatics. As intermediates of olefin aromatization process, butadiene and cyclopentene not only show much higher aromatization activity than mono-olefins, but also can be transformed into aromatics over relatively weak acid sites of K/ZSM-5. A proposal is put forward, stating that among all the steps experienced in olefins aromatization, the formation of diene or cycloolfin from mono-olefins through hydrogen transfer is the key step and can be catalyzed by strong acid sites.

施钾水平对烟叶含钾量的影响

通过盆栽试验 ,采用定位叶片的方法 ,进行不同钾肥用量试验 ,研究了增施钾肥对石灰性土壤上烤烟吸钾和土壤供钾的影响及提高石灰性土壤上烤烟含钾量的可能途径。结果表明 ,增施钾肥可以显著提高烟叶含钾量 ;而当施钾量达一定水平时 ,只有大幅度增加钾肥施用量 ,烟叶含钾量才显著增加 ,但对烟叶产量影响不大。施钾对烟叶含钾量的提高作用在生育后期最为显著。保证生育后期充足的钾素供应对提高烟叶含钾量可能具有重要意义

陕北中部丘陵区土壤肥力现状及提高土地生产力的途径

调查分析了延安宝塔区和安塞县 7个乡镇近三年来的粮食生产 ,肥料投入以及各土地类型的土壤肥力状况 ,表明 :投入的化肥中 ,氮肥以低浓度养分的碳铵为主 ,平均占肥料总量的 38.3% ,从施入土壤的 N、P、K养分来看 ,K比例很小 ,结构不合理。土壤肥力总体水平低 ,且不同土地类型差异大 ;由于各乡镇自然和经济状况的差异 ,土地投入量不同 ,从而导致粮食产量相差悬殊 ,并且年际波动大。提高土地生产力的有效途径是培肥土壤和大力推广农作物高产栽培技术

供钾方式对烟叶含钾量的影响

通过大田试验 ,研究了不同供钾方式对烟叶含钾量的影响及提高石灰性土壤上烤烟含钾量的可能途径。结果表明 ,施钾能显著提高烟叶产量 ,其中以粉肥结合喷优丰处理效果最好。在干旱条件下 ,增施钾肥可以显著提高烟叶含钾量 ,尤其能较大幅度提高中上部烟叶含钾量。粉肥对提高烟叶含钾量的效果稍优于粒肥。采用喷施“优丰 98- 2”进行根外补钾 ,可显著提高烟叶含钾量。在石灰性土壤上 ,干旱是提高烟叶含钾量的障碍因子。仅凭土壤施钾来提高烟叶含钾量 ,效果不稳定 ,受气候影响较大。土施结合喷施叶肥 ,是提高该区烤烟烟叶含钾量的有效途径。

Electrolytic Deposition and Diffusion of Lithium onto Magnesium-9 Wt Pct Yttrium Bulk Alloy in Low-Temperature Molten Salt of Lithium Chloride and Potassium Chloride

The electrolytic deposition and diffusion of lithium onto bulk magnesium-9 wt pct yttrium alloy cathode in molten salt of 47 wt pct lithium chloride and 53 wt pct potassium chloride at 693 K were investigated. Results show that magnesium-yttrium-lithium ternary alloys are formed on the surface of the cathodes, and a penetration depth of 642 mu m is acquired after 2 hours of electrolysis at the cathodic current density of 0.06 A center dot cm(-2). The diffusion of lithium results in a great amount of precipitates in the lithium containing layer. These precipitates are the compound of Mg41Y5, which arrange along the grain boundaries and hinder the diffusion of lithium, and solid solution of yttrium in magnesium. The grain boundaries and the twins of the magnesium-9 wt pct yttrium substrate also have negative effects on the diffusion of lithium.

Potassium-Lead-Switched G-Quadruplexes: A New Class of DNA Logic Gates

A cation-driven allosteric G-quadruplex DNAzyme (PW17) was utilized to devise a conceptually new class of DNA logic gate based on cation-tuned ligand binding and release. K+ favors the binding of hemin to parallel-stranded PW17, thereby promoting the DNAzyme activity, whereas Pb2+ induces PW17 to undergo a parallel-to-antiparallel conformation transition and thus drives hemin to release from the G-quadruplex, deactivating the DNAzyme. Such a K+-Pb2+ switched G-quadruplex, in fact, functions as a two-input INHIBIT logic gate. With the introduction of another input EDTA, this G-quadruplex can be further utilized to construct a reversibly operated IMPLICATION gate.

Direct dissolution of Au nanoparticles induced by potassium ferricyanide

In this work, we studied the reaction between Au nanoparticles (Au NPs) and [Fe(CN)(6)](3-) by the UV-vis absorption spectroscopy, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy. The absorption peak of Au NPs disappeared after adding [Fe(CN)(6)](3-) and the XPS data conformed the formation of [Au(CN)(2)](-). The results demonstrated that [Fe(CN)(6)](3-) could induce the dissolution of Au NPs, where the CN- from the dissociation of [Fe(CN)(6)](3-) played an important role.