Concentration and composition of aerosols in the near-water atmosphere layer above the Laptev Sea in July-September 1995

During the ARK-XI/1 expedition of R/V Polarstern in July-September 1995 12 samples of aerosols were collected in lower atmosphere layer over the Laptev Sea by filtration of air through AFA-HA filters. Element composition of the samples was determined by instrumental neutron activation analysis. Average atmospheric concentrations of Cr, Mn, Fe, Co, Zn and As are higher than in other regions of the Arctic. This can be explained by natural reasons: (1) by input of particles from the surface microlayer of sea water enriched by many chemical elements, (2) by atmospheric transfer of organic matter and lithogenic material from the land, and (3) by resuspension of particles from ice-rafted sediments. In some samples anthropogenic pollution was registered.

Impact of elevated pCO2 on paralytic shellfish poisoning toxin content and composition in Alexandrium tamarense

Ocean acidification is considered a major threat to marine ecosystems and may particularly affect primary producers. Here we investigated the impact of elevated pCO2 on paralytic shellfish poisoning toxin (PST) content and composition in two strains of Alexandrium tamarense, Alex5 and Alex2. Experiments were carried out as dilute batch to keep carbonate chemistry unaltered over time. We observed only minor changes with respect to growth and elemental composition in response to elevated pCO2. For both strains, the cellular PST content, and in particular the associated cellular toxicity, was lower in the high CO2 treatments. In addition, Alex5 showed a shift in its PST composition from a nonsulfated analogue towards less toxic sulfated analogues with increasing pCO2. Transcriptomic analyses suggest that the ability of A. tamarense to maintain cellular homeostasis is predominantly regulated on the post-translational level rather than on the transcriptomic level. Furthermore, genes associated to secondary metabolite and amino acid metabolism in Alex5 were down-regulated in the high CO2 treatment, which may explain the lower PST content. Elevated pCO2 also induced up-regulation of a putative sulfotransferase sxtN homologue and a substantial down-regulation of several sulfatases. Such changes in sulfur metabolism may explain the shift in PST composition towards more sulfated analogues. All in all, our results indicate that elevated pCO2 will have minor consequences for growth and elemental composition, but may potentially reduce the cellular toxicity of A. tamarense.

Abundance and composition of Fe-Mn nodules and host sediments in the Pacific Ocean

Data on internal structure, distribution, and chemical composition of iron-manganese nodules from the central part of the South Pacific are reported. Nodules with relatively high contents of Fe, Ti, Co, and Pb were found. Formation of these nodules in pelagic regions of the ocean with low sedimentation rates is tentatively ascribed by the authors to leaching of Fe, Mn, and some minor elements during submarine lava outflow and to geochemical mobility of these elements. The role of diagenetic re-distribution of ore elements during formation of nodules is also discussed.

Accumulation and composition of terrigenous material on Ceara rise over the past 55 Ma

Ceara Rise, located east the Amazon River mouth, is covered with a thick blanket of pelagic carbonate and hemipelagic terrigenous sediment. The terrigenous component has been extracted from 57 bulk sediment samples at Ocean Drilling Program (ODP) Sites 925 and 929 on Ceara Rise to obtain a Cenozoic record of riverine discharge from northern South America. From the early Eocene to early Miocene (55-20 Ma), terrigenous accumulation was dominated by moderate amounts of generally large-grained, gray to green sediment especially depleted in elements that are enriched in post-Archaean shale (e.g. Cs, Th, Yb). However, pulsed inputs of relatively small-grained, gray to green terrigenous sediment less depleted in the above elements occurred in the late Eocene and Oligocene. The accumulation of terrigenous sediment decreased significantly until 16.5 Ma. In the middle Miocene (16.5-13 Ma), terrigenous accumulation was dominated by small amounts of small-grained, tan sediment notably depleted in Na and heavy rare earth elements. The accumulation rate of terrigenous sediment increased markedly from the latest Miocene (10 Ma) to the present day, a change characterized by deposition of gray-green sediment enriched in elements that are enriched in post-Archaean shale. Observed changes in terrigenous sediment at Ceara Rise record tectonism and erosion in northern South America. The Brazil and Guyana shields supplied sediment to the eastern South American margin until the middle Miocene (20-16.5 Ma) when a period of thrusting, shortening and uplift changed the source region, probably first to highly weathered and proximal Phanerozoic sediments. By the late Miocene (9 Ma), there was a transcontinental connection between the Andes and eastern South America. Weathering products derived from the Andes have increasingly dominated terrigenous deposition at Ceara Rise since the Late Miocene and especially since the late Pliocene.

(Table 2) Concentrations and composition of aliphatic hydrocarbons in bottom sediments of the Sakhalin shelf

Aliphatic and polycyclic aromatic hydrocarbons were examined in the surface layer of bottom sediments from the eastern part of the Sakhalin Island shelf (materials were sampled in summer 2002). Concentrations of hydrocarbons were determined to know changed since beginning of development of oil fields (compared with earlier years). According to distribution of markers in hydrocarbon compositions, bottom sediments are dominated by allochthonous (terrigenous) hydrocarbons that are the most stable compounds. Occurrence of transformed anthropogenic oil alkanes that have never been found before may be indicative of increasing pollution in the region.