Levantamento e avaliação de critérios para a ampliação de escala da produção de biossurfactantes utilizando melaço como substrato

Biosurfactants are amphiphilic molecules synthesized by microorganisms such as bacteria, yeast or filamented fungi cultivated in various carbon sources among sucrose and hydrocarbons. These molecules are composed by a hydrophilic and hydrophobic part. They operate mostly at interfaces of fluids of different polarities. Because of this characteristic, they are potentially employed in numerous industries, such as the textile, medical, cosmetics, food and mainly in the petrochemical ones. Therefore industry has interest in developing new biosurfactant production processes in high scale, in order to become them economically competitive when compared to synthetic biosurfactants. This work aims to evaluate the biosurfactant production applying a non-conventional substrate sugar cane molasses proceeding from the sugar industry thus reducing the production costs. The strain identified as AP029/GLIIA, isolated from oil wells in Rio Grande do Norte state and used in these experiments belongs to the culture collection of Antibiotics Department of UFPE. The fermentation were carried out using different conditions according to a factorial planning 24 with duplicate at center point, in which the studied factors were molasse concentration, nitrate concentration, agitation and aeration ratio. The experiments were performed in a shaker at 38ºC of temperature. Samples were withdrawn in regular periods of time of up to 72 hours of fermentation in order to analyze substrate consumption, cellular concentration, superficial tension, critical micelle dilution (CMD-1 e CMD-2) as well as extracelullar protein production. The results showed a production of 3,480 g/L of biomass, a reduction of 41% on superficial tension, 67% of substrate consumption and 0,2805 g/L of extracellular protein

Incorporação de resíduo de perfuração em matriz cerâmica: estabilização por solidificação

One of the waste generated during the drilling of oil wells are gravel which are impregnated of drilling fluid. This residue consists of highly toxic chemicals, including toxic metals. This study suggests an alternative process to the treatment of this waste, by incorporating it the form of raw material in the ceramic matrix , and by solidification and stabilize the metals present, Aluminum (Al), Iron (Fe), Manganese (Mn) and Zinc (Zn). The raw materials were characterized by the techniques of X ray fluorescence (FRX), X ray diffraction (DRX), laser granulometry (GL), thermogravimetry (TG) and differential thermal analysis (ADT). To evaluate the percentage of gravel effect the environmental and technological properties were obtained from formulations containing 0, 10 and 20 % by weight of gravel in the ceramic matrix. After sintering at temperatures 1080, 1120 and 1160 °C, the samples were tested for water absorption, the linear shrinkage firing, voltage of rupture and solubility. The results obtained showed that the stabilization by solidification, is a viable alternative to safe disposal of waste drilling. Ceramics products can be used in the manufacture of solid bricks

Aplicação de tensoativos não iônicos na recuperação de fluidos de perfuração poliméricos

The drilling fluid used to assist in the drilling operation of oil wells, accumulates solids inherent in the formation as it is circulated in the well, interfering in the fluid performance during operation. It is discarded after use. The disposal of these fluids causes one of the most difficult environmental problems in the world. This study aims to promote liquid phase separation of drilling fluids, which have circulated in oil wells, and enable this recovered liquid to formulate a new fluid. For this, non-ionic surfactants were used in order to select the best outcome in phase separation. Five real water-based drilling fluids were utilized, which were collected directly from the fields of drilling oil wells, classified as polymeric fluids. The methodology used consisted in combining the fluid with surfactant and then subjecting it to a process of centrifugation or decantation. The decantating tests were scheduled through experimental planning 23 and 32, using as variables the percentage (%) of surfactant utilized and the stirring time in minutes. The surfactants used were ethoxylated nonylphenol and lauryl alcohol ethoxylated with different degrees of ethoxylation. Phase separation was monitored first by tests of stability, and subsequently by the height of the interface in beakers of 100 mL. The results showed that from the surfactants studied, the lauryl alcohol ethoxylated with 3 ethoxylation units has been the most effective in the phase separation process of the drilling fluids tested. The statistical tool used was of great industrial value regarding the programming phase separation in drilling fluids. In conclusion, the liquid phase separated using surfactant can be reused for a new formulation of drilling fluid with similar properties of a new fluid, assuring its efficiency. And in the resulting analysis it is also suggested that the adsorption is the mechanism that leads the phase separation, with surfactant adsorbing in the active solids

Análise de resíduos em modelos de tempo de falha acelerado com efeito aleatório

We present residual analysis techniques to assess the fit of correlated survival data by Accelerated Failure Time Models (AFTM) with random effects. We propose an imputation procedure for censored observations and consider three types of residuals to evaluate different model characteristics. We illustrate the proposal with the analysis of AFTM with random effects to a real data set involving times between failures of oil well equipment

Caracterização mecânica e microestrutural de um aço baixo carbono microligado com estrutura multifásica

Neste trabalho foi realizada a caracterização mecânica e microestrutural de um aço microligado com estrutura multifásica. Foi aplicado tratamento térmico pré-determinado, objetivando a formação de uma microestrutura multifásica no material. Na caracterização microestrutural foram utilizados ataques químicos à base de metabissulfito de sódio e ácido pícrico, enquanto a caracterização mecânica foi realizada através de ensaios de tração. Os resultados demonstram o elevado potencial dos aços multifásicos em aplicações que necessitem de valores superiores de resistência e ductilidade, pois tanto para temperatura isotérmica de 400ºC quanto para 350ºC houve um ganho no limite de resistência à tração ficando em torno de 786MPa e 773MPa respectivamente, representando um aumento de 15,5% e 13,6% com relação ao material fornecido.

Um estudo algorítmico da programação da intervenção de sondas de produção

This work approaches the Scheduling Workover Rigs Problem (SWRP) to maintain the wells of an oil field, although difficult to resolve, is extremely important economical, technical and environmental. A mathematical formulation of this problem is presented, where an algorithmic approach was developed. The problem can be considered to find the best scheduling service to the wells by the workover rigs, taking into account the minimization of the composition related to the costs of the workover rigs and the total loss of oil suffered by the wells. This problem is similar to the Vehicle Routing Problem (VRP), which is classified as belonging to the NP-hard class. The goal of this research is to develop an algorithmic approach to solve the SWRP, using the fundamentals of metaheuristics like Memetic Algorithm and GRASP. Instances are generated for the tests to analyze the computational performance of the approaches mentioned above, using data that are close to reality. Thereafter, is performed a comparison of performance and quality of the results obtained by each one of techniques used

Métodos estatísticos recursivos aplicados ao problema de estimação de vazão de gás em plantas de Plunger-lift

This work has as main objective to find mathematical models based on linear parametric estimation techniques applied to the problem of calculating the grow of gas in oil wells. In particular we focus on achieving grow models applied to the case of wells that produce by plunger-lift technique on oil rigs, in which case, there are high peaks in the grow values that hinder their direct measurement by instruments. For this, we have developed estimators based on recursive least squares and make an analysis of statistical measures such as autocorrelation, cross-correlation, variogram and the cumulative periodogram, which are calculated recursively as data are obtained in real time from the plant in operation; the values obtained for these measures tell us how accurate the used model is and how it can be changed to better fit the measured values. The models have been tested in a pilot plant which emulates the process gas production in oil wells

Aplicação do método B ao projeto formal de software embarcado

This work shows a project method proposed to design and build software components from the software functional m del up to assembly code level in a rigorous fashion. This method is based on the B method, which was developed with support and interest of British Petroleum (BP). One goal of this methodology is to contribute to solve an important problem, known as The Verifying Compiler. Besides, this work describes a formal model of Z80 microcontroller and a real system of petroleum area. To achieve this goal, the formal model of Z80 was developed and documented, as it is one key component for the verification upto the assembly level. In order to improve the mentioned methodology, it was applied on a petroleum production test system, which is presented in this work. Part of this technique is performed manually. However, almost of these activities can be automated by a specific compiler. To build such compiler, the formal modelling of microcontroller and modelling of production test system should provide relevant knowledge and experiences to the design of a new compiler. In ummary, this work should improve the viability of one of the most stringent criteria for formal verification: speeding up the verification process, reducing design time and increasing the quality and reliability of the product of the final software. All these qualities are very important for systems that involve serious risks or in need of a high confidence, which is very common in the petroleum industry

Arquitetura hardware/software de um núcleo NCAP segundo o padrão IEEE 1451.1: uma prova de conceito

Os sensores inteligentes são dispositivos que se diferenciam dos sensores comuns por apresentar capacidade de processamento sobre os dados monitorados. Eles tipicamente são compostos por uma fonte de alimentação, transdutores (sensores e atuadores), memória, processador e transceptor. De acordo com o padrão IEEE 1451 um sensor inteligente pode ser dividido em módulos TIM e NCAP que devem se comunicar através de uma interface padronizada chamada TII. O módulo NCAP é a parte do sensor inteligente que comporta o processador. Portanto, ele é o responsável por atribuir a característica de inteligência ao sensor. Existem várias abordagens que podem ser utilizadas para o desenvolvimento desse módulo, dentre elas se destacam aquelas que utilizam microcontroladores de baixo custo e/ou FPGA. Este trabalho aborda o desenvolvimento de uma arquitetura hardware/software para um módulo NCAP segundo o padrão IEEE 1451.1. A infra-estrutura de hardware é composta por um driver de interface RS-232, uma memória RAM de 512kB, uma interface TII, o processador embarcado NIOS II e um simulador do módulo TIM. Para integração dos componentes de hardware é utilizada ferramenta de integração automática SOPC Builder. A infra-estrutura de software é composta pelo padrão IEEE 1451.1 e pela aplicação especí ca do NCAP que simula o monitoramento de pressão e temperatura em poços de petróleo com o objetivo de detectar vazamento. O módulo proposto é embarcado em uma FPGA e para a sua prototipação é usada a placa DE2 da Altera que contém a FPGA Cyclone II EP2C35F672C6. O processador embarcado NIOS II é utilizado para dar suporte à infra-estrutura de software do NCAP que é desenvolvido na linguagem C e se baseia no padrão IEEE 1451.1. A descrição do comportamento da infra-estrutura de hardware é feita utilizando a linguagem VHDL

Metodologia para caracterização metalográfica de um aço TRIP por microscopia óptica

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Análise do comportamento dinâmico de um rotor vertical através do método dos elementos finitos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Caracterização mecânica e microestrutural de um aço de baixo carbono

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Caracterização mecânica e microestrutural de um aço 300M com microestrutura multifásica

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Uma arquitetura multiagente para sistemas de supervisão e controle de processos

Pós-graduação em Ciência da Computação - IBILCE

Determinação experimental da tenacidade à fratura em baixas temperaturas de tubos de aço API 5L X70

Because of the great metallurgical advances, the welded tubes by HF / ERW (High Frequency / Electrical Resistance Welding) have played a more active role in the oil and gas, gradually replacing tubes produced by other processes (UOE, SAW, and others) to deep water applications, in high and extremely low temperatures, highpressure conditions and in highly corrosive environments. However, studies have revealed that defects in the welded joints are in one of main causes of failures in pipelines. Associated with damage external and the stringent requirements of this sector, the welded joints become particularly critical for his toughness and the determination of this particular property is fundamental. This study aims to evaluate the toughness of the HF / ERW pipes in HSLA steel API X70 class, used in pipelines transport systems of gas and oil from data obtained with CTOD tests (Crack Tip Opening Displacement). The main objectives of this project are: mechanical and microstructural characterization of steels API X70 manufactured in Brazil; and evaluation of the toughness of weld process by HF / ERW steel API X70 national. After having the tests done, mechanical, chemical and metallurgical, we have the conclusion that those pipe are in agreement to API 5L 42ª edition for X70MO and the toughness behaves like the expected