[Ni(Phen)_3][Pd(mnt)_2]·1.25 DMF的合成与晶体结构

报道标题化合物的合成、鉴定和单晶结构.晶体中含有数量相同的两种独立的阳离子,互为对映异构体,而且这两种八面体构型阳离子的畸变程度各不相同.晶胞中还存在三种独立的阴离子.不同阳离子中的四个平面型 Phen 配体之间通过π-π相互作用发生联系,形成四聚单元,每两个四聚单元又通过与平面共轭型的阴离子之间的π-π相互作用而相连,形成一种特殊的、准一维的链状结构.

n—C_(12)H_(25)NH_3Br固态相性质的DSC和拉曼光谱研究

用差示扫描量热(DSC)和拉曼光谱方法考察了n-C_(12)H_(25)NH_3Br(DoAB)的固相性质,确定了DoAB固-固结构相变的温度及其焓变,通过6种状态下所对应的拉曼光谱讨论了相变过程中分子构象的变化。

[n-C_(12)H_(25)NH_3]_2ZnCl_4配合物相变拉曼光谱研究

通式为[C_nH_(2n+1)NH_3]_2MX_4(M=Cu,Mn,Zn…、X=Cl,Br)(简写C_nM)四卤合金属酸二烷基铵系列化合物一般具有二维层结构。它是由薄的无机层阴离子MX_4~(2-)和厚的烷基铵阳离子[R-NH_3]~+组成的碳氢层规则交替构成的“夹心面包”型体系。这类化合物常存在固-固相变,并且有较大的相变潜热,有可能成为很有应用前景的一类新的低温储能材

Study on growth factors of intermetallic layer within hot-dipped 25% Al-Zn alloy coating on steel

25%Al-Zn alloy coating performs better than hot dip galvanized coating and 55%Al-Zn-Si coating with regard to general seawater corrosion protection. This study deals with the interfacial intermetallic layer's growth, which affects considerably the corrosion resistance and mechanical properties of 25%Al-Zn alloy coatings, by means of three-factor quadratic regressive orthogonal experiments, The regression equation shows that the intermetallic layer thickness decreases rapidly with increasing content of Si added to the Zn-Al alloy bath, increases with rise in bath temperature and prolonging dip time. The most effective factor that determined the thickness of intermetallic layer was the amount of Si added to Zn-Al alloy bath, while the effect of bath temperature and dip time on the thickness of intermetallic layer were not very obvious.

Effect of nano-TiO(2)on MP-25 resin

MP-25 resin is a chlorine-containing polymer widely used in coatings. The effects of two types of nano-TiO2 (P-25 and RM301 LP) on MP-25 were studied with saline immersion, UV irradiation, and electrochemical impedance spectroscopy. UV irradiation was evaluated in terms of gloss change and X-ray photoelectron spectroscopy (XPS). The results indicate that, compared to pigment R-930 TiO2, P-25 reduced the immersion resistance and accelerated UV aging of the MP-25 coating, whereas RM301 LP showed the opposite effects. XPS analysis showed that MP-25 resin degraded under UV irradiation via dechlorination and C-C bond breakage, similarly to poly(vinyl chloride), but RM301 LP could inhibit the aging of MP-25 to a certain extent. A skin effect of oxygen and chlorine was identified in MP-25 resin by XPS. RM301 LP could improve the impedance of the MP-25 coating because of its excellent fill capacity. Hence, rutile nano-TiO2 RM301 LP represents an excellent additive for MP-25 resin. (c) 2007 Wiley Periodicals, Inc.

压力和铁含量对铁方镁石(Mg1-xFex)O(x<=0.25)弹性常数影响的第一性原理研究

By first principle methods based on density functional theory (DFT),the equation of state(EOS) and elastic constants of both periclase and ferropericlase are calculated. The pressure and iron doping effects on the elastic constants of ferropericlase are investigated systematically. Firstly, we calculate the elastic constants of periclase and compare the obtained results with experimental data and other theoretical calculations, which shows a encouraging consistence and demonstrates the practicability of first-principle methods. Secondly, by adding iron into periclase crystal model, we build up ferropericlase with iron contents ranging from 0% to 25% mole percent. The corresponding elastic constants are calculated in a large pressure range(0~120GPa). Emphatically, the strong correlation of 3d electrons in transitional elements, such as iron, is difficult to treat in first-principle methods for a long time. The current solution is to make additional correction. During the initial stage of this study, the strong correlation of 3d electrons in iron is not considered, and we observed that addition of iron decreases the volume of ferropericlase, which is totally contradictory to the experimental data. By applying LDA+U approximation in order to solve the strongly correlated 3d electron of iron, we observed the expansion of volume by iron as expected. On the basis of the LDA+U approximation, the elastic constants of ferropericlase are calculated. After a detailed analysis of data obtained from theoretical calculations, we have reached the following conclusions:(1)pressure imposes positive effects on all elastic constants, and the degree of effects is C11>C12>C44. (2) Iron has no distinctive effects on C11 and C12, although some fluctuations are observed around 60GPa. However, iron has obvious softening effects on C44 The softening effects on C44 are intensified as pressure increases. Above the 100GPa, the effects increase greatly, even surpasses the pressure's positive effects in ferropericlase crystal models with iron mole percent of having 12.5%, 18.75% and 25% iron content. (3)As to the modulus deprived from elastic constants, iron has no effect on the adiabatic bulk module BS, only a little fluctuation around 60GPa. We find iron's softening effects on shear modulus G. (4)We find out that, compared with low iron content, elastic constants with iron content approaching 25mole% is consistently fluctuated，which may be caused by the limitations of the LDA+U approximation method itself. (5)We investigate the pressure and Fe doping effects on elastic anisotropy factor（A=(2C44+C12-C11)/C11） of ferropericlase and find out that iron contents will lower the critical isotropic pressure. At the same pressure, when the pressure is below the isotropic pressure, iron softens the anisotropy factor ; when pressure surpasses the isotropic pressure, iron increases the anisotropy factor.

PRINCIPAIS INDICADORES: AGRÍCOLAS, v. 3, n. 25, 2010.

2010

PRINCIPAIS INDICADORES: LEITE E DERIVADOS, v. 3, n. 25, 2010.

2010

PRINCIPAIS INDICADORES: MACROECONÔMICOS, v. 3, n. 25, 2010.

2010

Levantamento pedológico semidetalhado (1:25.000) da microbacia da Água Três Unidos, município de Vera Cruz (SP).

2002

Embrapa Acre: 25 anos.

Ao longo desses 25 anos, a Embrapa Acre, estrategicamente, efetuou mudanças nos rumos da pesquisa e desenvolvimento no Estado, procurando adequar-se às realidades das políticas vigentes e às tendências econômicas, sociais e ambientais locais e nacionais. Hoje, a imagem da Embrapa Acre é reconhecida pela qualidade técnica do seu trabalho e do seu comprometimento com o desenvolvimento sustentável da Amazônia. A dedicação de funcionários e a valiosa contribuição de parceiros das esferas públicas e privadas resultaram em informações e soluções tecnológicas para aumento da produtividade, melhoria da qualidade de vida e satisfação de clientes, usuá rios e beneficiários de nossos produtos, serviços e tecnologias. Nesta publicação, procuramos sintetizar todo o esforço desta caminhada, cujos resultados permitem contemplar a missão deste Centro de Pesquisa que é "viabilizar soluções tecnológicas para o desenvolvimento sustentável do agronegócio da Amazônia, com foco no Estado do Acre, por meio da geração, adaptação e transferência de conhecimentos e tecnologias, em benefício da sociedade."

The evolutionary history of ferns inferred from 25 low-copy nuclear genes.

UNLABELLED: • PREMISE OF THE STUDY: Understanding fern (monilophyte) phylogeny and its evolutionary timescale is critical for broad investigations of the evolution of land plants, and for providing the point of comparison necessary for studying the evolution of the fern sister group, seed plants. Molecular phylogenetic investigations have revolutionized our understanding of fern phylogeny, however, to date, these studies have relied almost exclusively on plastid data.• METHODS: Here we take a curated phylogenomics approach to infer the first broad fern phylogeny from multiple nuclear loci, by combining broad taxon sampling (73 ferns and 12 outgroup species) with focused character sampling (25 loci comprising 35877 bp), along with rigorous alignment, orthology inference and model selection.• KEY RESULTS: Our phylogeny corroborates some earlier inferences and provides novel insights; in particular, we find strong support for Equisetales as sister to the rest of ferns, Marattiales as sister to leptosporangiate ferns, and Dennstaedtiaceae as sister to the eupolypods. Our divergence-time analyses reveal that divergences among the extant fern orders all occurred prior to ∼200 MYA. Finally, our species-tree inferences are congruent with analyses of concatenated data, but generally with lower support. Those cases where species-tree support values are higher than expected involve relationships that have been supported by smaller plastid datasets, suggesting that deep coalescence may be reducing support from the concatenated nuclear data.• CONCLUSIONS: Our study demonstrates the utility of a curated phylogenomics approach to inferring fern phylogeny, and highlights the need to consider underlying data characteristics, along with data quantity, in phylogenetic studies.

25 años de labor agrometeorológica en la estación experimental agroindustrial Obispo Colombres, Tucumán Argentina

p.81-136

Imátgenes 25, 26, 27 y última imatgen

Su mirada recorrió los lomos del estante inferior y se detuvo en un título que le llamó la atención. Lo liberó de la hilera que lo aprisionaba y lo abrió al azar. Al menos eso era lo que pretendía, aunque el libro se abrió por una página señalada con un pliegue en la esquina superior. Quien lo practicó quería señalar un punto con una indicación perenne. Seguro que era cosa de su abuelo, fallecido hacía ya unos cuantos años. Fue precisamente el recuerdo de su muerte lo que le animó a entrar en la biblioteca. No sabía porqué, pero de repente le había venido a la mente la imagen del anciano leyendo ensimismado en aquel sillón antiguo, rodeado de incontables volúmenes, páginas, frases, palabras, letras.