Conceções sobre avaliação formativa de professores do 2.ºCEB: um estudo comparativo

Relatório de estágio apresentado à Escola Superior de Educação de Lisboa para obtenção de grau de mestre em Ensino do 1.º e do 2.º Ciclo do Ensino Básico

Professor de dupla habilitação: (des)continuidades entre o 1º e 2ºciclos do ensino básico

Relatório de estágio apresentado à Escola Superior de Educação de Paula Frassinetti para a obtenção do grau de Mestre em Ensino do 1.º e 2.º Ciclo do Ensino Básico

A promoção do pensamento crítico e as atividades experimentais nas aulas de Ciências naturais do 2º CEB

Relatório de estágio apresentado para obtenção do grau de mestre em Ensino do 1º e do 2º ciclos do ensino básico

Prática de ensino supervisionada em educação pré-escolar e 1º ciclo do ensino básico: ensinar para aprender - gerindo a heterogeneidade, o currículo e rumando à diferenciação pedagógica

O presente relatório surge no âmbito do Mestrado em Educação Pré-escolar e Ensino do 1º Ciclo do Ensino Básico e visa a obtenção do grau de mestre nos níveis de escolaridade referidos. Neste descrevo o projeto de investigação-ação desenvolvido nos contextos da Prática de Ensino Supervisionado (PES) em Educação Pré-escolar e 1º Ciclo do Ensino Básico (CEB). A investigação-ação realizada visava, sobretudo, ajudar-me a compreender quais as condições que deveria reunir de modo a responder de forma adequada às necessidades das crianças e a perceber como poderia melhorar a minha ação e intervenção promovendo aprendizagens significativas e de qualidade, salientando que o propósito não era fornecer o mesmo a todas as crianças, mas sim, a cada uma aquilo de que necessitava. A minha aposta na Diferenciação Pedagógica e numa gestão flexível do currículo surge orientada pelo princípio do direito de todos à aprendizagem e como resposta intencional à heterogeneidade dos grupos de crianças que frequentam atualmente as instituições. Assim, de modo a atingir os objetivos propostos, planeei algumas sugestões de interação que permitiam a utilização de estratégias diversificadas e a observação das crianças durante a utilização das mesmas. A metodologia utilizada contemplou uma pesquisa bibliográfica com base em vários referenciais teóricos e a recolha e análise de dados. Esta investigação possibilitou constatar que a Diferenciação Pedagógica subjacente às propostas apresentadas proporciona o desenvolvimento das crianças tanto a nível social como cognitivo; ABSTRACT: The present report reflects the research develop in the context of the Master Degree in Preschool Education and Teaching of the Primary School at University of Évora, and aims to obtain the degree of master in the levels mention above. This research was held in two different contexts, the first one in a pre-school classroom, and later in a classroom of fourth year of Primary School. The research performed aimed mainly to help me to understand what conditions must be gathered in order to respond appropriately to children's needs and to see how it could improve my actions and intervention by promoting meaningful and quality learnings, stressing that the purpose was not to provide the same for all children, but to each one what they needed. My bet on Pedagogical Differentiation and a flexible management of the curriculum comes to the principle of the right of all to learning and as an intentional response to the heterogeneity of the groups of children who currently attend institutions. Thus, in order to achieve the proposed objectives, I planned some suggestions for interacting with groups of children’s which allowed me to use multiple strategies and to do observation of the individuals while they were being applied. The methodology included a literature search based on various theoretical frameworks and data collection and the respective analysis. This research led us to confirm that the proposals based on pedagogical differentiation provide children's development both socially and cognitive and it is essential to ensure it since the earliest years of school, in order to build a rich differentiated pedagogical action and to promote learning for all students in pre-school and 1st cycle contexts by using diverse strategies.

Vibrational spectroscopy of phthalocyanine and naphthalocyanine in sandwich-type (na)phthalocyaninato and porphyrinato rare earth complexes: Part 14. The infrared and Raman characteristics of phthalocyanine in “pinwheel-like” homoleptic bis[1,8,15,22-tetrakis(3-pentyloxy)phthalocyaninato] rare earth(III) double-decker complexes

The infrared (IR) spectroscopic data and Raman spectroscopic properties for a series of 13 “pinwheel-like” homoleptic bis(phthalocyaninato) rare earth complexes M[Pc(α-OC5H11)4]2 [M = Y and Pr–Lu except Pm; H2Pc(α-OC5H11)4 = 1,8,15,22-tetrakis(3-pentyloxy)phthalocyanine] have been collected and comparatively studied. Both the IR and Raman spectra for M[Pc(α-OC5H11)4]2 are more complicated than those of homoleptic bis(phthalocyaninato) rare earth analogues, namely M(Pc)2 and M[Pc(OC8H17)8]2, but resemble (for IR) or are a bit more complicated (for Raman) than those of heteroleptic counterparts M(Pc)[Pc(α-OC5H11)4], revealing the decreased molecular symmetry of these double-decker compounds, namely S8. Except for the obvious splitting of the isoindole breathing band at 1110–1123 cm−1, the IR spectra of M[Pc(α-OC5H11)4]2 are quite similar to those of corresponding M(Pc)[Pc(α-OC5H11)4] and therefore are similarly assigned. With laser excitation at 633 nm, Raman bands derived from isoindole ring and aza stretchings in the range of 1300–1600 cm−1 are selectively intensified. The IR spectra reveal that the frequencies of pyrrole stretching and pyrrole stretching coupled with the symmetrical CH bending of –CH3 groups are sensitive to the rare earth ionic size, while the Raman technique shows that the bands due to the isoindole stretchings and the coupled pyrrole and aza stretchings are similarly affected. Nevertheless, the phthalocyanine monoanion radical Pc′− IR marker band of bis(phthalocyaninato) complexes involving the same rare earth ion is found to shift to lower energy in the order M(Pc)2 > M(Pc)[Pc(α-OC5H11)4] > M[Pc(α-OC5H11)4]2, revealing the weakened π–π interaction between the two phthalocyanine rings in the same order.

Peripherally η1-Platinated Organometallic Porphyrins as Building Blocks for Multiporphyrin Arrays

The modification of peripherally metalated meso-η1-platiniometalloporphyrins, such as trans-[PtBr(NiDAPP)(PPh3)2] (H2DAPP = 5-phenyl-10,20-bis(3‘,5‘-di-tert-butylphenyl)porphyrin), leads to the analogous platinum(II) nitrato and triflato electrophiles in almost quantitative yields. Self-assembly reactions of these meso-platinioporphyrin tectons with pyridine, 4,4‘-bipyridine, or various meso-4-pyridylporphyrins in chloroform generate new multicomponent organometallic porphyrin arrays containing up to five porphyrin units. These new types of supramolecular arrays are formed exclusively in high yields and are stable in solution or in the solid state for extended periods. They were characterized by multinuclear NMR and UV−visible spectroscopy as well as high-resolution electrospray ionization mass spectrometry.