984 resultados para intercalated clays


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The combination of rainy climate, glaciolacustrine clays, and steep topography of the Puget Lowland creates slope stability issues for the regional population. Several glaciolacustrine deposits of laminated silt and clay of different ages contribute to the likelihood of slope failure. The glaciolacustrine deposits are generally wet, range in thickness from absent to >30m, and consist of laminated silt and clay with sand interbeds at the tops and bottoms, sandy laminae throughout the deposits, occasional dropstones and shear zones. The glaciolacustrine deposits destabilize slopes by 1) impeding groundwater flow percolating through overlying glacial outwash sediments, 2) having sandy laminae that lower strength by increasing pore pressure during wet seasons, and 3) increasing the potential for block-style failure because of secondary groundwater pathways such as laminae and vertical fractures. Eight clay samples from six known landslide deposits were analyzed in this study for their mineralogy, clay fraction and strength characteristics. The mineralogy was determined using X-ray Diffractometry (XRD) which revealed an identical mineralogic suite among all eight samples consisting of chlorite, illite and smectite. Nonclay minerals appearing in the X-ray diffractogram include amphibole and plagioclase after removal of abundant quartz grains. Hydrometer tests yielded clay-size fraction percentages of the samples ranging from 10% to 90%, and ring shear tests showed that the angle of residual shear resistance (phi_r) ranged from 11° to 31°. Atterberg limits of the samples were found to have liquid limits ranging from 33 to 83, with plastic limits ranging from 25 to 35 and plasticity indices ranging from 6 to 48. The results of the hydrometer and residual shear strength tests suggest that phi_r varies inversely with the clay-size fraction, but that this relationship was not consistent among all eight samples. The nature of the XRD analysis only revealed the identity of the clay minerals present in the samples, and provided no quantitative information. Thus, the extent to which the mineralogy influenced the strength variability among the samples cannot be determined given that the mineral assemblages are identical. Additional samples from different locations within each deposit along with quantitative compositional analyses would be necessary to properly account for the observed strength variability.

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The yield behaviour of a series of melt-mixed polyethylene-modified montmorillonite nanocomposites has been studied as a function of temperature and strain rate and compared to the behaviour of the base polymer. The processing conditions used gave an intercalated structure as assessed by X-ray diffraction. Although there was a modest improvement in stiffness with clay content, the yield behaviour was insensitive to the addition of the clay. Both the base polymer and the nanocomposites showed double yield points. These were analysed as activated rate processes, with the activation energies consistent with the low strain yield point being associated with the alpha(2) molecular relaxation and the higher strain yield point with W axis slip. (C) 2003 Society of Chemical Industry.

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The structural and dynamic properties of dioctadecyldimethylammoniums (DODDMA) intercalated into 2:1 layered clays are investigated using isothermal-isobaric (NPT) molecular dynamics (MD) simulation. The simulated results are in reasonably good agreement with the available experimental measurements, such as X-ray diffraction (XRD), atom force microscopy (AFM), Fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR) spectroscopies. The nitrogen atoms are found to be located mainly within two layers close to the clay surface whereas methylene groups form a pseudoquadrilayer structure. The results of tilt angle and order parameter show that interior two-bond segments of alkyl chains prefer an arrangement parallel to the clay surface, whereas the segments toward end groups adopt a random orientation. In addition, the alkyl chains within the layer structure lie almost parallel to the clay surface whereas those out of the layer structure are essentially perpendicular to the surface. The trans conformations are predominant in all cases although extensive gauche conformations are observed, which is in agreement with previous simulations on n-butane. Moreover, an odd-even effect in conformation distributions is observed mainly along the chains close to the head and tail groups. The diffusion constants of both nitrogen atoms and methylene groups in these nanoconfined alkyl chains increase with the temperature and methelene position toward the tail groups.

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Understanding the interfacial interactions between the nanofiller and polymer matrix is important to improve the design and manufacture of polymer nanocomposites. This paper reports a molecular dynamic Study on the interfacial interactions and structure of a clay-based polyurethane intercalated nanocomposite. The results show that the intercalation of surfactant (i.e. dioctadecyldlmethyl ammonium) and polyurethane (PU) into the nanoconfined gallery of clay leads to the multilayer structure for both surfactant and PU, and the absence of phase separation for PU chains. Such structural characteristics are attributed to the result of competitive interactions among the surfactant, PU and the clay surface, including van der Waals, electrostatic and hydrogen bonding.

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The nanocomposites of general layered clays and metal sulfides could be produced from reactions of the layered clay aqueous suspensions and water-soluble metal-thiourea complexes. The clay could be saponite, montmorillonite, hectorite and laponite, while the metal sulfide could be cobalt sulfide, nickel sulfide, zinc sulfide, cadmium sulfide, and lead sulfide. In the nanocomposites, the clay could be incorporated with the metal sulfide pillars and metal sulfide nanoparticles. (c) 2006 Elsevier B.V. All rights reserved.