968 resultados para RIFAMPICIN. 3-FORMYLRIFAMYCIN. RIFAMPICIN QUINONE.RIFAMPICIN N-OXIDE. THERMAL ANALYSIS


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Bedding dips in the CRP-3 drillhole were determined in three ways: (1) analysis of a dipmeter log, (2) identification of bed boundaries on borehole televiewer log images, and (3) identification of bed boundaries on digital images of the outer surfaces of oriented cores. All three methods determine both dip magnitude and downdip azimuth of bedding. Dipmeter results document variations in bedding dip throughout the logged interval (20-902 mbsf), whereas core and televiewer results are available at present only for selected depth intervals. Dipmeter data indicate that structural dip is remarkably constant, at 21° dip to azimuth 65°, throughout the Tertiary shelf section, except for the top 100 m where dips appear to be 5-10° shallower. This pattern, in conjunction with the systematically increasing dips throughout CRP-2A, suggests that the growth faulting active during CRP-2A deposition began during the final period of deposition at CRP-3. Normal faults at 260 and 539 mbsf in CRP-3 exhibit neither drag (localized dip steepening) nor significant changes in structural dip across them. Oriented core and televiewer analyses, covering a total of 200 m in the interval 400-900 mbsf, indicate bedding patterns that confirm the dipmeter results. The doleritic breccia at the base of the Tertiary section has steeper dips than overlying structural dips, possibly indicating a sedimentary dip to ENE in these fan sediments. Dip directions in the underlying Devonian Beacon sandstone are surprisingly similar to those in the overlying Tertiary section. Superimposed on the average Beacon dip of 22° to the ENE are localized tilts of up to 20°, probably caused by Tertiary fracturing and brecciation rather than original sedimentary dip variations.

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Alteration of sheeted dikes exposed along submarine escarpments at the Pito Deep Rift (NE edge of the Easter microplate) provides constraints on the crustal component of axial hydrothermal systems at fast spreading mid-ocean ridges. Samples from vertical transects through the upper crust constrain the temporal and spatial scales of hydrothermal fluid flow and fluid-rock reaction. The dikes are relatively fresh (average extent of alteration is 27%), with the extent of alteration ranging from 0 to >80%. Alteration is heterogeneous on scales of tens to hundreds of meters and displays few systematic spatial trends. Background alteration is amphibole-dominated, with chlorite-rich dikes sporadically distributed throughout the dike complex, indicating that peak temperatures ranged from <300°C to >450°C and did not vary systematically with depth. Dikes locally show substantial metal mobility, with Zn and Cu depletion and Mn enrichment. Amphibole and chlorite fill fractures throughout the dike complex, whereas quartz-filled fractures and faults are only locally present. Regional variability in alteration characteristics is found on a scale of <1-2 km, illustrating the diversity of fluid-rock interaction that can be expected in fast spreading crust. We propose that much of the alteration in sheeted dike complexes develops within broad, hot upwelling zones, as the inferred conditions of alteration cannot be achieved in downwelling zones, particularly in the shallow dikes. Migration of circulating cells along rides axes and local evolution of fluid compositions produce sections of the upper crust with a distinctive character of alteration, on a scale of <1-2 km and <5-20 ka.

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The Toba lake event, the Australasian microtektite event, and the Cretaceous/Paleogene boundary were analyzed on the basis of foraminifers, carbonate content, trace elements, and spherules (microtektites). The Toba ash event, recovered in Hole 758C, may have had minor influences on the foraminiferal populations. The Australasian tektite event has probably some influence on foraminiferal ecology, because the larger specimens become scarce just above the microtektite layer. Microtektites recovered from Hole 758B closely resemble spherules recovered from several Cretaceous/Paleogene boundary localities in North America. The Cretaceous/Paleogene spherules, however, are usually larger and are completely altered to goyazite in the terrestrial environment and to smectite in a marine environment. The Cretaceous/Paleogene boundary of Hole 752B does not show obvious anomalous trace-element concentrations, and iridium concentrations are below our detection limits. The trace-element pattern is dominated by the alternation of chalk with volcanic ash layers above the Cretaceous/Paleogene boundary.

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Geological features of some areas of the Tropical Atlantic (stratigraphy, tectonic structure, lithology, distribution of ore components in bottom sediments, petrography of bedrocks, etc.) are under consideration in the book. Regularities of concentration of trace elements in iron-manganese nodules, features of these nodules in bottom sediments, distribution of phosphorite nodules and other phosphorites have been studied. Much attention is paid to rocks of the ocean crust. A wide range of mineralization represented by magnetite, chromite, chalcopyrite, pyrite, pentlandite, and other minerals has been found.

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Manganese nodules from Stations 252 and 281 of the Challenger Expedition, collected in 1875, have recently been discovered in the Redpath Museum. The nodules have been found to be quite typical specimens of two areas in the Central Pacific Ocean except for dehydration and other changes that have taken place during storage. The principal resolvable manganese mineral in nodules from Station 252 proved to be 10 A manganite; there was a very thin surface coating of birnessite. Delta manganite was the only manganese mineral found in nodules from Station 281. Through electron microprobe studies, findings from chemical, optical and x-ray crystallographic work were correlated with the detailed picture of the occurrence and quantities of the different elements within the nodules. In all cases it was found that the iron and manganese had an antithetical relationship, and that nickel and copper were associated with the manganese. Special study was given to a 300-micron-square area in a nodule from Station 252 which included a segregation of 49.39% Mn, 5.31 % Ni, and 1.64% Cu. Crystallization of the manganese phases is thought to have provided a mech¨anism for formation of segregations which were further enriched through chemical scavenger action as long as ocean floor conditions permitted.

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