Diatom stratigraphy of ODP Leg 150 holes

Diatoms are present in middle to lower upper Miocene sections of all holes examined during Leg 150, but are generally absent or in low abundance in Pleistocene to middle upper Miocene sediments. An exception is the alternating diatom-rich, diatom-poor intervals in upper Quaternary sediments. Five new diatom zones, covering an interval from near the lower/middle Miocene boundary to the lower upper Miocene, are proposed. Some of the taxon used to define these zones are also used in zonal schemes for the East Coast of the United States, and allow for correlations to be drawn between this region and Leg 150 sites. Lower Miocene and older levels are not included in this study. Although older Tertiary diatoms are present at some of the sites, dissolution has largely compromised their usefulness as zonal markers.

Benthic foraminifera across the Cretaceous/Paleogene boundary in the Southern Ocean

The impact of an asteroid at the Cretaceous/Paleogene (K/Pg) boundary triggered dramatic biotic, biogeochemical and sedimentological changes in the oceans that have been intensively studied. Paleo-biogeographical differences in the biotic response to the impact and its environmental consequences, however, have been less well documented. We present a high-resolution analysis of benthic foraminiferal assemblages at Southern Ocean ODP Site 690 (Maud Rise, Weddell Sea, Antarctica). At this high latitude site, late Maastrichtian environmental variability was high, but benthic foraminiferal assemblages were not less diverse than at lower latitudes, in contrast to those of planktic calcifiers. Also in contrast to planktic calcifiers, benthic foraminifera did not suffer significant extinction at the K/Pg boundary, but show transient assemblage changes and decreased diversity. At Site 690, the extinction rate was even lower (~3%) than at other sites. The benthic foraminiferal accumulation rate varied little across the K/Pg boundary, indicating that food supply to the sea floor was affected to a lesser extent than at lower latitude sites. Compared to Maastrichtian assemblages, Danian assemblages have a lower diversity and greater relative abundance of heavily calcified taxa such as Stensioeina beccariiformis and Paralabamina lunata. This change in benthic foraminiferal assemblages could reflect post-extinction proliferation of different photosynthesizers (thus food for the benthos) than those dominant during the Late Cretaceous, therefore changes in the nature rather than in the amount of the organic matter supplied to the seafloor. However, severe extinction of pelagic calcifiers caused carbonate supersaturation in the oceans, thus might have given competitive advantage to species with large, heavily calcified tests. This indirect effect of the K/Pg impact thus may have influenced the deep-sea dwellers, documenting the complexity of the effects of major environmental disturbance.

Oxygen and carbon isotope stratigraphy of ODP Holes 107-653A and 107-654A

Stable isotope analysis of two species (or groups of species) of planktonic foraminifers: Globigerinoides ruber (or G. obliquus and G. obliquus extremus) and Globigerina bulloides (or G. falconensis and G. obesa) from ODP Hole 653A and Site 654 in the Tyrrhenian basin, records the Pliocene-Pleistocene glacial history of the Northern Hemisphere. The overall increase in mean d18O values through the interval 4.6-0.08 Ma is 1.7 per mil for G. bulloides and 1.5 per mil for G. ruber. The time interval 3.1-2.5 Ma corresponds to an important phase of 18O enrichment for planktonic foraminifers. In this interval, glacial d18O values of both species G. bulloides and G. ruber increase by about l per mil, this increase being more progressive for G. ruber than for G. bulloides. The increase of interglacial d18O values is higher for G. bulloides (1.5 per mil) than for the Gruber group (1 per mil). These data suggest a more pronounced seasonal stratification of the water masses during interglacial phases. Large positive d18O fluctuations of increasing magnitude are also recorded at 2.25 and 2.15 Ma by G bulloides and appear to be diachronous with those of Site 606 in the Atlantic Ocean. Other events of increasing d18O values are recorded between 1.55 and 1.3 Ma, at 0.9 Ma, 0.8 Ma, and near 0.34 Ma. In the early Pliocene the d18O variability recorded by the planktonic species G. bulloides was higher in the Mediterranean than in the Atlantic at the same latitude. This suggests that important cyclic variations in the water budget of the Mediterranean occurred since that time. Step increases in the d18O variability are synchronous with those of the open ocean at 0.9 and 0.34 Ma. The higher variability as well as the higher amplitude of the peaks of 18O enrichment may be partly accounted for by increase of dryness over the Mediterranean area. In particular the high amplitude d18O fluctuations recorded between 3.1 and 2.1 Ma are correlated with the onset of a marked seasonal contrast and a summer dryness, revealed by pollen analyses. Strong fluctuations towards d13C values higher than modern ones are recorded by the G. ruber group species before 1.7 Ma and suggest a high production of phytoplankton. When such episodes of high primary production are correlated with episodes of decreasing 13C content of G. bulloides, they are interpreted as the consequence of a higher stratification of the upper water masses resulting itself from a marked seasonality. Such episodes occur between 4.6 and 4.05 Ma, 3.9 and 3.6 Ma, and 3.25 and 2.66 Ma. The interval 2.66-1.65 Ma corresponds to a weakening of the stratification of the upper water layers. This may be related to episodes of cooling and increasing dryness induced by the Northern Hemisphere Glaciations. The Pleistocene may have been a less productive period. The transition from highly productive to less productive surface waters also coincides with a new step increase in dryness and cooling, between 1.5 and 1.3 Ma. The comparison of the 13C records of G ruber and G. bulloides in fact suggests that a high vertical convection became a dominant feature after 2.6 Ma. Increases in the nutrient input and the stratification of the upper water masses may be suspected, however, during short episodes near 0.86 Ma (isotopic stage 25), 0.57-0.59 Ma (isotopic stage 16), 0.49 Ma (isotopic stage 13), 0.4-0.43 Ma (isotopic stage 11), and 0.22 and 0.26 Ma (part of isotopic stage 7 and transition 7/8). In fact, changes in the C02 balance within the different water masses of the Tyrrhenian basin as well as in the local primary production did not follow the general patterns of the open ocean.

Late Quaternary carbonate and isotope stratigraphy of DSDP Site 90-594 east of South Island, New Zealand

The late Quaternary sequence off eastern South Island, New Zealand, consists of ~100 m of alternating bluish gray pelagic oozes and greenish gray hemipelagic oozes that extend uninterruptedly back to the Brunhes/Matuyama boundary (0.73 m.y.). A very high resolution (~2400 yr.) record of sediment texture, calcium carbonate content, and planktonic and benthic foraminiferal oxygen and carbon isotope composition demonstrates an in-phase cyclical fluctuation between the sedimentary parameters that closely correspond to the pelagic-hemipelagic sedimentation cycles and the isotope composition. Pelagic oozes, formed during interglacial periods of high eustatic sea level, are characterized by calcareous microfossils, relative enrichment in sand and clay sizes, high carbonate contents, reduced delta18O values, and increased delta13C values. Hemipelagic oozes, associated with glacial episodes and lowered eustatic sea level, include common terrigenous material and siliceous microfossils, are enriched in silt sizes, have low carbonate contents, high delta18O values, and low delta13C values. The history of alpine glaciations and associated erosion of the South Island of New Zealand, as expressed by the appearance of hemipelagic oozes, can be correlated directly with the major fluctuations of Northern Hemisphere ice sheets as expressed by the influence of eustatic sea-level changes on the oxygen isotope composition of both planktonic and benthic foraminifers. This high-accumulation-rate record contains conspicuous intervals of highfrequency, high-amplitude isotope variability including the presence of multiple glacial/interglacial intervals within single isotope stages, and offers one of the best sections cored to date for detailed study of the evolution and history of climate change over the last 0.75 m.y.

Radiolarian Paleogene biostratigraphy in the southern Indian Ocean, ODP Leg 120

During Ocean Drilling Program Leg 120, an almost complete Paleogene sediment section on the Kerguelen Plateau in the southern Indian Ocean was recovered. The biostratigraphy of radiolarians from these sediments at Sites 748 and 749 is studied. A biostratigraphic framework established in low and middle latitudes is not applicable because of the absence of most zonal marker species. Biogenic opal is present only in middle Eocene to Oligocene sediments, and three new zones-Lychnocanoma conica, Axoprunum (?) irregularis, and Eucyrtidium spinosum zones-are proposed. The Paleogene antarctic radiolarian fauna is different from that in low and middle latitudes. Three new species, Axoprunum (?) irregularis, Eucyrtidium cheni, and Eucyrtidium spinosum, are described.

Benthic foraminifera across the Cretaceous/Paleogene boundary in ODP Hole 198-1210A

Deep-sea benthic foraminifera show important but transient assemblage changes at the Cretaceous/Paleogene (K/Pg) boundary, when many biota suffered severe extinction. We quantitatively analyzed benthic foraminiferal assemblages from lower bathyal-upper abyssal (1500-2000 m) northwest Pacific ODP Site 1210 (Shatsky Rise) and compared the results with published data on assemblages at lower bathyal (~ 1500 m) Pacific DSDP Site 465 (Hess Rise) to gain insight in paleoecological and paleoenvironmental changes at that time. At both sites, diversity and heterogeneity rapidly decreased across the K/Pg boundary, then recovered. Species assemblages at both sites show a similar pattern of turnover from the uppermost Maastrichtian into the lowermost Danian: 1) The relative abundance of buliminids (indicative of a generally high food supply) increases towards the uppermost Cretaceous, and peaks rapidly just above the K/Pg boundary, coeval with a peak in benthic foraminiferal accumulation rate (BFAR), a proxy for food supply. 2) A peak in relative abundance of Stensioeina beccariiformis, a cosmopolitan form generally more common at the middle than at the lower bathyal sites, occurs just above the buliminid peak. 3) The relative abundance of Nuttallides truempyi, a more oligotrophic form, decreases at the boundary, then increases above the peak in Stensioeina beccariiformis. The food supply to the deep sea in the Pacific Ocean thus apparently increased rather than decreased in the earliest Danian. The low benthic diversity during a time of high food supply indicates a stressed environment. This stress might have been caused by reorganization of the planktic ecosystem: primary producer niches vacated by the mass extinction of calcifying nannoplankton may have been rapidly (<10 kyr) filled by other, possibly opportunistic, primary producers, leading to delivery of another type of food, and/or irregular food delivery through a succession of opportunistic blooms. The deep-sea benthic foraminiferal data thus are in strong disagreement with the widely accepted hypothesis that the global deep-sea floor became severely food-depleted following the K/Pg extinction due to the mass extinction of primary producers ("Strangelove Ocean Model") or to the collapse of the biotic pump ("Living Ocean Model").

Magnetic susceptibility stratigraphy for Pleistocene and Pliocene sediments of ODP Leg 110 samples

Whole-core magnetic susceptibility measurements define a detailed stratigraphy that enables correlation between the various Pleistocene, Pliocene, and upper Miocene sections cored on ODP Leg 110, near the Tiburon Rise. The magnetic susceptibility in these sections is primarily related to the content of volcanic ash, rich in titanomagnetite, and also inversely related to calcium carbonate content. The high resolution of the susceptibility record enables correlations with a resolution of about 0.3 m of sediment thickness, and the identification of minor faults not definable by biostratigraphic means. Reverse and normal faults identified in Hole 672A are probably a result of normal oceanic sediment dewatering and compaction processes. This work indicates some of the problems of using visible ash layers as time-stratigraphic markers.

Core alignment and composite depth scale of DSDP Site 86-577

Deep Sea Drilling Project Site 577 on Shatsky Rise (North Pacific Ocean) recovered a series of cores at three holes that contain calcareous nannofossil ooze of latest Cretaceous (late Maastrichtian) through early Eocene age. Several important records have been generated using samples from these cores, but the stratigraphy has remained outdated and confusing. Here we revise the stratigraphy at Site 577. This includes refining several age datums, realigning cores in the depth domain, and placing all stratigraphic markers on a current time scale. The work provides a template for appropriately bringing latest Cretaceous and Paleogene data sets at old drill sites into current paleoceanographic literature for this time interval. While the Paleocene Eocene Thermal Maximum (PETM) lies within core gaps at Holes 577* and 577A, the sedimentary record at the site holds other important events and remains crucially relevant to understanding changes in oceanographic conditions from the latest Cretaceous through early Paleogene.

Tab. 1: Meerfelder Maar Drilling B4, stratigraphy and sequence of the lake sediments (pdf 215 kB)

A core from Meerfelder Maar, with a basal age of 29,000 years, provides a continuous sedimentary sequence from Late-Glacial times to the present. It includes the stratigraphical marker of the Laach Pumice Tuff. Sedimentological, geochemical, palynological, palaeobiological, palaeomagnetic and palaeontological analyses permit reconstructions of the history of the lake and its catchment area, and hence of the climate of the region, to be made. The discovery of Middle Oligocene marine, detrital fossils in the maar sediments provides insights into the palaeogeography of the Eifel region during Tertiary times.

XRF iron (Fe) counts of ODP Hole 171-1050A and 171-1051A

Upper Paleocene to lower Eocene sediments drilled at Ocean Drilling Program (ODP) Site 1051 (Blake Nose, off Florida) display well-defined orbital cycles, a detailed magnetic stratigraphy, and a suite of planktonic foraminiferal datums. We derived a cyclostratigraphy by using spectral analysis of high-resolution records of elemental concentrations obtained by an X-ray fluorescence (XRF) Core Scanner. XRF counts of iron serve as a proxy for the relative amount of terrestrial material. Sliding-window spectral analysis, bandpass filtering, and direct counting of precession and obliquity cycles yield minimum durations for magnetic polarity chrons C22 to C26 (~49 to ~61 Ma), calculations of sediment accumulation rates, as well as constraints on the timing of biostratigraphic and climatological events in the vicinity of the Initial Eocene Thermal Maximum (IETM). Durations of polarity chrons as represented in sediments drilled at Site 1051 were estimated using a conservative assignment of 41 k.y. for obliquity cycles and 21 k.y. for precession cycles. Combined polarity chrons C26r and C26n span 3.61 m.y., and chron C25r spans 1.07 m.y. Polarity chron C24r is estimated as 2.877 m.y. The interpretation of polarity chron C24n is ambiguous, but its duration is probably <1.23 m.y. Polarity chron C23r spans 0.53 m.y., chron C23n is 0.74 m.y., and chron C22r is 0.9 m.y. Spectral analysis through this interval indicates that spectral peaks shift through time and are related to changes in sedimentation rate in Site 1051. The sedimentation rates dramatically increased ~200 k.y. after the IETM and remained high for most of chron C24r.

Strontium-isotope stratigraphy and oxygen- and carbon-isotope record of Middle Jurassic to Early Cretaceous belemnites in the South Atlantic

87Sr/86Sr data of belemnites are presented from a Middle Jurassic-Early Cretaceous succession from the Falkland Plateau (Deep Sea Drilling Project Sites 511 and 330) that was deposited in a periodically anoxic, semi-enclosed shallow water basin. Diagenetically screened strontium-isotope values of 0.706789 rise to 0.707044 before increasing sharply to 0.707428 in the uppermost part of the sampled succession. Comparison with published strontium calibration curves suggests that the oldest samples were Callovian to Oxfordian in age, whilst the remainder of the Jurassic part of the succession consisted of Kimmeridgian and Early Tithonian age sediments. The nannofossil, dinoflagellate and molluscan assemblages provide comparable age determinations. The strontium-isotope analysis of the youngest belemnites points to a Hauterivian-Barremian age, whilst age interpretations based upon the fauna provide a wide age range from the Barremian to early Albian. Strontium-isotope stratigraphy of this succession hence offers increased age resolution providing data regarding the timing of episodes of bottom water anoxia which have been recorded throughout the South Atlantic Basin. Well-preserved belemnite specimens display an oxygen-isotope range between +0.08 and -2.22? (PDB, Peedee belemnite international standard) and a carbon-isotope range from +2.35 to -1.33? (PDB). Delta13C values become increasingly negative through the Late Jurassic-Early Cretaceous and in concert with the 87Sr/86Sr data reveal a trend that could be accounted for by increasing levels of weathering and erosion. The oxygen-isotope data if interpreted in terms of palaeotemperature are consistent with warm palaeotemperatures in the Kimmeridgian and slightly cooler temperatures for the Tithonian and Early Cretaceous parts of the succession. The proposed relative Kimmeridgian warmth (based upon strontium-isotope age assignments) is thus in good agreement with other published palaeotemperature records.

Stable isotope stratigraphy of ODP Site 167-1014

Late Quaternary oxygen (d18O) and carbon (d13C) isotopic records for the benthic foraminifer Uvigerina and the planktonic foraminifer Globigerina bulloides are presented for the upper 20 meters composite depth sediment sequence of Ocean Drilling Program Site 1014, Tanner Basin, in the outer California Borderland province. The benthic oxygen isotopic record documents a continuous >160-k.y. sequence from marine isotope Stage (MIS) 6 to the present day. The record closely resembles other late Quaternary North Pacific benthic isotope records, as well as the well-dated deep-sea sequence (SPECMAP), and thus provides a detailed chronologic framework. Site 1014 provides a useful record of the California response to climate change as it enters the southern California Border-land. Sedimentation rates are relatively constant and high (~11.5 cm/k.y. ). The planktonic foraminiferal record is well pre-served except during marine isotope Substages 5b and 5d, when normally high G. bulloides abundance is strongly diminished as a result of dissolution. The planktonic oxygen isotopic shift of ~3 per mil between the last glacial maximum and the Holocene suggests a surface water temperature shift of <7°C, similar to estimates from Hole 893A (Leg 146) to the north. Unlike Santa Barbara Basin, G. bulloides d18O values during the last interglacial (MIS 5) at Site 1014 were significantly higher than during the Holocene. In particular, marine isotope Substage 5e (Eemian) was ~0.8 per mil higher. This is unlikely to reflect a cooler Eemian but is instead the result of preferential dissolution of thin-shelled (low d18O) specimens during this interval. In this mid-depth basin, a large benthic d18O shift during Termination I suggests dramatic temperature and salinity changes in response to switches in the source of North Pacific Intermediate Water. Although d13C values of the planktonic foraminifer G. bulloides are in disequilibria with seawater and hence interpretations are limited, the G. bulloides record exhibits several negative d13C excursions found at other sites in the region (Sites 1017 and 893). This indicates a response of G. bulloides d13C to regional surface water processes along the southern California margin. A general increase in benthic carbon isotopic values (-1.75 per mil to -0.75 per mil) in Tanner Basin during the last 200 k.y. is overprinted with smaller fluctuations correlated with climate change. The coolest intervals during the last glacial maximum (MISs 2 and 4) exhibit lower benthic d13C values, which correlate with global 13C shifts. The opposite relationship is exhibited during the last interglacial before 85 ka, when lower benthic d13C values are associated with warmer intervals (marine isotope Substages 5c and 5e) of the last interglacial. These time intervals were also marked by decreased intermediate water ventilation. Increased dissolution and organic accumulation during Substages 5b and 5d are anticorrelated with the benthic d13C record. These results suggest that a delicate balance in intermediate water d13C has existed between the relative influences of global 13C and regional ventilation changes at the 1165-m water depth of Site 1014.

Pleistocene calcareous nannofossil stratigraphy for ODP Leg 177, Atlantic sector of the Southern Ocean

Seven Ocean Drilling Program (ODP) sites recovered during ODP Leg 177 in the Atlantic sector of the Southern Ocean were analyzed to study the Pleistocene calcareous nannofossil record. Calcareous nannofossil events previously described from intermediate and low latitudes were identified and calibrated with available geomagnetic and stable isotope stratigraphic data. In general, Pleistocene southern high latitude calcareous nannofossil events show synchronicity with those observed from warm and temperate latitudes. The first occurrence (FO) of Emiliania huxleyi and the last occurrence (LO) of Pseudoemiliania lacunosa are observed in marine isotope stages (MIS) 8 and 12, respectively. A reversal in abundance between Gephyrocapsa muellerae and E. huxleyi is observed at MIS 5. MIS 6 is characterized by an increase in G. muellerae and MIS 7 features a dramatic decrease in the proportion of Gephyrocapsa caribbeanica. This latter species began to increase its proportions from MIS 14 to 13. The LO of Reticulofenestra asanoi is observed within subchron C1r.1r and the FO of R. asanoi occurs at the top of C1r.2r. A reentry of medium-sized Gephyrocapsa can be identified in some cores during subchron C1r.1n. The LO of large morphotypes of Gephyrocapsa is well correlated through the studied area, and occurs during the middle-low part of subchron C1r.2r,synchronous with other oceanic regions. The FO of Calcidiscus macintyrei and FO of medium-sized Gephyrocapsa occur in the studied area close to 1.6 Ma.