Properties of a nanocomposite polymer electrolyte from an amorphous comb-branch polymer and nanoparticles

Three fully amorphous comb-branch polymers based on poly(styrene-co-maleic anhydride) as a backbone and poly(ethylene glycol) methyl ether of different molecular weights as side chains were synthesized. SiO2 nanoparticles of various contents and the salt LiCF3SO3 were added to these comb-branch polymers to obtain nanocomposite polymer electrolytes. The thermal and transport properties of the samples have been characterized. The maximum conductivity of 2.8x10(-4) S cm(-1) is obtained at 28 degreesC. In the system the longer side chain of the comb-branch polymer electrolyte increases in ionic conductivity after the addition of nanoparticles. To account for the role of the ceramic fillers in the nanocomposite polymer electrolyte, a model based on a fully amorphous comb-branch polymer matrix in enhancing transport properties of Li+ ions is proposed.

Study of the conductivity and side chain mobility of a comb-like polymer electrolyte using the dynamic mechanical method

Using poly(styrene-co-maleic anhydride) as a backbone and poly(ethylene glycol) methyl ether (PEGME) with different molecular weights as side chains, three comb-like polymers and their Li salt complexes were synthesized. The dynamic mechanical properties and conductivities were investigated. Results showed that the polymer electrolytes possess two glass transitions: alpha -transition and beta -transition, and the temperature dependence of the ionic conductivity shows WLF (Williams-Landel-Ferry) behavior. Based on the time-temperature equivalence principle, a master curve was constructed by selecting T-beta as reference temperature. The values of the WLF parameters (C-1 and C-2) were obtained and were found to be almost independent of the length of the PEGME side chain and the content of Li salt. By reference to T-0 = 50 degreesC. the relation between log tau (c) and c was found to be linear. The master curves are displaced progressively to higher frequencies as the molecular weight of the side chain is increased. The relation between log tau (n) and the molecular weight of the side chain is also linear. (C) 2001 Elsevier Science B.V. All rights reserved.

Study on a comb-like polymer electrolyte based on the backbone of ethylene-maleic anhydride copolymer

A comb-like polymer host(CBPE) as polymer electrolyte was synthesized by reacting poly(ethylene glycol) monomethyl ether (PEGME) with ethylene-maleic anhydride copolymer(EMAC) and endcapping the residual carboxylic acid with methanol. The synthetic process was followed by IR and the amorphous product characterized by IR and elemental analysis. There were two peaks in the plot of the ionic conductivity against Li salt concentration. The plot of log sigma vs. 1/(T - T-0) may exhibit dual VTF behavior when using the glass transition temperature of PEO of side chain as T-0. The comb-like polymer is a white rubbery solid which dissolves in acetone. (C) 1998 Elsevier Science B.V. All rights reserved.

Study on the two class glass transition and ion transport of a comb polymer electrolyte

The thermal behaviour and ion-transport properties of a comb polymer electrolyte CP350/LiSCN based on methyl vinyl ether/maleic anhydride copolymer with oligo-oxyethylene side chains were studied by means of DSC and ac impedance method. The two glass transition temperatures which can be attributed to side chains and main chains respectively were found to increase with increasing salt concentration. Conductivities which displayed non-Arrhenius behaviour were analyzed by using Vogel-Tammann-Fulcher equation and interpreted on the basis of the configurational entropy model derived by Gibbs and coworkers. The optimum ionic conductivity at 25 degrees C achieved was 2.19x10(-5)S/cm.

Studies on the two class glass transition and the typical VTF behaviour of an amorphous comb polymer electrolyte

A comb polymer (CP350) with oligo-oxyethylene side chains of the type -(CH2CH2O)(7)CH3 was prepared from methyl vinyl ether/maleic anhydride copolymer and poly(ethylene glycol) methyl ether. The polymer can dissolve LiNO3 salt to form homogeneous amorphous polymer electrolyte. This electrolyte system was first found to have two class glass transitions, and the two T(g)s were observed to increase with increasing salt content. The ionic conduction was measured by using the complex impedance method, and conductivities were investigated as functions of temperature and salt concentration. At 25 degrees C, the ionic conductivity maximum of this system can get to 3.72 X 10(-5) S/cm at the [Li]/ [EO] ratio of 0.057. The appearance of the conductivity maximum has been interpreted as being due to the effect of T-g and the so called physical crosslinks. The temperature dependence of the ionic conductivity displaying non-Arrhenius behaviour can be analyzed using the Vogel-Tammann-Fulcher equation and interpreted on the basis of the configurational entropy model.

Comb polymer electrolytes - Ionic conductivity and cation-polymer interaction

Three comb polymers(CP) with oligo-oxyethylene side chains of the type -O(CH2CH2O)(n)CH3 were prepared from methyl vinyl ether/maleic anhydride alternating copolymer. Homogeneous amorphous polymer electrolytes were made from CP and LiCF3SO3 or LiClO4 by solvent-casting method, and their conductivities were measured as a function of temperature and salt concentration. The conductivity which displayed non-Arrhenius behaviour was analyzed using the Vogel-Tammann-Fulcher equation. The conductivity maximum appears at lower salt concentration when CP has longer side chains. XPS was used to study the cation-polymer interaction.

SYNTHESIS AND CHARACTERIZATION OF A NEW COMB-LIKE POLYMER-BASED ON POLY(VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE

A new comblike polymer host for polymer electrolyte was synthesized by reacting monomethyl ether of poly(ethylene glycol) with poly(vinyl methyl ether-alt-maleic anhydride) and endcapping the residual carboxylic acid with methanol. Butanone was selected as a solvent for the esterification in order to obtain a completely soluble product. The synthesis process was traced through by LR. Compared with the model compounds, the presumed structure of this comblike polymer has been proved to be valid by C-13 NMR The comb polymer is a white rubbery solid. It can be dissolved in butanone and THF, and manifests good film forming ability.

IONIC-CONDUCTION OF A NOVEL COMB POLYMER ELECTROLYTE BASED ON MALEIC-ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE-CHAINS

A comb-shaped polymer (BM350) with oligo-oxyethylene side chains of the type -O(CH2CH2O)(7)CH3 was prepared from methyl vinyl ether/maleic anhydride copolymer. Homogeneous amorphous polymer electrolyte complexes were made from the comb polymer and LICF(3)SO(3) by solvent casting from acetone, and their conductivities were measured as a function of temperature and salt concentration. Maximum conductivity close to 5.08 X 10(-5) Scm(-1) was obtained at room temperature and at a [Li]/[EO] ratio of about 0.12. The conductivity which displayed non-Arrhenius behaviour was analyzed using the Vogel-Tammann-Fulcher equation and interpreted on the basis of the configurational entropy model. The results of mid-IR showed that the coordination of Li+ to side chains made the C-O-C band become broader and shift slightly. X-ray photoelectron spectroscopy analysis indicated that the oxygen atoms in the two situations could coordinate to Li+ and this coordination resulted in the reduction of the electron orbit binding energy of F and S.

Study on new comb polymer electrolyte(III)

A new solid polymer electrolyte has been prepared using NaClO4 and a comb-branch polymer with oligo(ethylene oxide) side chains. The thermal and ionic conductive properties of the electrolytes were investigated. The profile of conductivity at various temperatures follows the VTF plots.

Study on a new comb polymer electrolyte(II)

A comb polymer(CP350) with oligo-oxyethlene side chains was prepared from methyl vinyl ether/maleic anhydride copolymer. Homogeneous amorphous polymer electrolyte were made from the comb polymer and LiCF3SO3 by solvent casting from acetone, and their conductivities were measured as a function of temperature and salt concentration. Maximum conductivity close I to 5.08 x 10(-5)S/cm was achieved at room temperature at [Li]/[EO] ratio of about 0.12.

WATER-SOLUBLE AND AMPHIPHILIC POLYMERS .7. SYNTHESIS AND CHARACTERIZATION OF A NOVEL COMB-TYPE AMPHIPHILIC POLYMER PAMC16S

A novel comb-like amphiphilic polymer, poly (2-acrylamidohexadecylsulfonic acid) (PAMC16S), was synthesized by free radical polymerization of the corresponding amphiphilic monomer in 1,4-dioxane-water mixed solvents. Depending on the ratio of water/dioxane in the solvent, the reaction proceeded by either precipitation polymerization or micellar polymerization. The molecular weight of the polymer obtained under similar conditions decreased and subsequently increased with the increase of water content in the mixed solvent. The polyion nature of PAMC16S was confirmed by viscosity data of ethanolic solutions. In addition, the polymer was characterized by solubility, IR, TG and wide angle X-ray diffraction methods.

Wangia profunda gen. nov., sp nov., a novel marine bacterium of the family Flavobacteriaceae isolated from southern Okinawa Trough deep-sea sediment

An orange-pigmented, Gram-negative, nonmotile, strictly aerobic and oxidase- and catalase-positive bacterium (SM-A87(T)) was isolated from the deep-sea sediment of the southern Okinawa Trough area. The main fatty acids were i15 : 0, i17 : 0 3OH, i15 : 1 G, i17 : 1 omega 9c, 15 : 0, i15 : 0 3OH and summed feature 3 (comprising i-15 : 0 2OH and/or 16 : 1 omega 7c). MK-6 was the predominant respiratory quinone. DNA G+C content was 35.8 mol%. Flexirubin-type pigments were absent. Phylogenetic analyses based on 16S rRNA gene sequences revealed that strain SM-A87(T) formed a distinct lineage within the family Flavobacteriaceae, with < 93% sequence similarity to the nearest strain of genus Salegentibacter. Moreover, strain SM-A87(T) could be distinguished from the nearest phylogenetic neighbors by a number of chemotaxonomic and phenotypic properties. On the basis of polyphasic analyses, it is proposed that strain SM-A87(T) be classified in a novel genus and a new species in the family Flavobacteriaceae, designated Wangia profunda gen. nov., sp. nov. The type strain is SM-A87(T) (CCTCC AB 206139(T)=DSM 18752).

Myroides profundi sp nov., isolated from deep-sea sediment of the southern Okinawa Trough

A Gram-negative, nonmotile, aerobic and oxidase- and catalase-positive bacterium,, designated D25(T), was isolated from the deep-sea sediments of the southern Okinawa Trough area. Phylogenetic analyses of 16S rRNA gene sequences showed that strain D25(T), fell within the genus Myroides, with 99.2%, 96.0% and 93.4% sequence similarities to the only three recognized species of Myroides. However, the DNA-DNA similarity Value between strain D25(T) and its nearest neighbour Myroides odoratimimus JCM 7460(T) was only 49.9% ( < 70%). Several phenotypic properties could be used to distinguish strain D25(T) from other Myroides species. The main cellular fatty acids of strain D25(T) were iso-C-15:0, iso-C-17:1 omega 9C, iso-C(17:0)3-OH and Summed Feature 3 (comprising C-16:1 omega 7c and/or iso-C(15:0)2-OH). The major respiratory quinone was MK-6. The DNA G+C content was 33.0 mol%. The results of the polyphasic taxonomy analysis suggested that strain D251(T) represents a novel species of the genus Myroides, for which the name Myroides profundi sp. nov. is proposed. The type strain is D25(T) (=CCTCC M 208030(T) = DSM 19823(T)).

Laurencia nanhaiense sp nov., a new species of the genus Laurencia(Rhodomelaceae, Rhodophyta) from China

Laurencia nanhaiense sp. nov. (Rhodomelaceae, Rhodophyta) is described from Hainan and Guangdong Provinces, China. The new species clearly displays one of the defining features of the genus, viz. four periaxial cells per vegetative axial segment. It differs from other closely related species in having a combination of features such as terete axes from a basal system composed of a primary, discoid holdfast and a secondary attachment to give rise to many short rhizoids, branching oppositely and alternately, irregularly tristichous or subverticillately polystichous, having more curve branches with very sparse, adventitious ultimate branchlets, non-projecting superficial cortical cells at the apices of ultimate branchlets, presence of longitudinally oriented secondary pit-connections between contiguous superficial cortical cells, absence of lenticular thickenings in the walls of medullary cells, parallel arrangement of tetrasporangia along the axis of stichidia, and presence of intercellular spaces between medullary cells.

Letter to Daniel Avery Whedon. Brooklyn, NY. Nov. 22, 1865.

Handwritten 1865 handwritten letter from Daniel D. Whedon to Daniel A. Whedon, his nephew, regarding slavery in relation to the Church as well as the Christian Union.