Preparation of Y3Al5O12 : Eu phosphors by citric-gel method and their luminescent properties

By using metal nitrates as starting materials and citric acid as complexing agent, Y3Al5O12 (YAG) and Y3Al5O12:Eu (1 mol%) (YAG:Eu) powder phosphors were prepared by a citrate-gel method. The formation process of YAG and YAG:Eu were investigated by means of XRD, TG-DTA and FT-IR spectra. The purified crystalline phases of YAG and YAG:Eu were obtained at 800 degreesC. The crystalline YAG:Eu phosphors showed an orange-red emission with D-5(0)-F-7(1) (591 nm) as the most prominent group, whose intensity was dependent on the pH value of the starting solution, citric acid content and firing temperature. It has been found that the suitable pH and citric acid/metal ratio are 3 and 2 for obtaining the highest emission intensity, respectively. The emission intensity increases steadily with increasing the annealing temperature from 800 to 1200 degreesC, and nearly remains constant after 1200 degreesC. Furthermore, great differences were observed for the lifetimes and the charge transfer band of Eu3+ in crystalline and amorphous states of YAG.

Preparation of Pt/C catalyst with solid phase reaction method

The PVC catalyst was prepared with solid phase reaction method (Pt/C(S)) for the first time. Its performances were compared with that prepared by the traditional liquid phase reaction method. The results demonstrate that the electrocatalytic activity of PVC catalyst with solid phase reaction method for methanol oxidation is higher than that with liquid phase reaction method. XRD and TEM measurements indicate that the Pt/C(S) possesses low crystalline extent and small particle size.

Preparation of polymer/silica nanoscale hybrids through sol-gel method involving emulsion polymers (PMMA/SiO2)

The different poly (methyl methacrylate) (PMMA) /SiO2 hybrids were prepared through sol-gel method involving PMMA emulsion (emulsion method) and PMMA/THF solution (solution method). The samples were characterized by differential scanning calorimetry(DSC), thermogravimetry analysis(TGA), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results showed that PMMA/SiO2 composites in nanoscale were prepared by emulsion method, and its size of phase heterogeneity was less than that of solution method. Meanwhile, the polymer emulsion as the reactive medium was more suitable for the formation of SiO2 network.

A new preparation of zinc sulfide nanoparticles by solid-state method at low temperature

A novel solid-state method of the preparation of zinc sulfide nanoparticles is reported. By solid-state reaction of zinc acetate and thioacetamide at low temperature, zinc sulfide nanoparticles of different sizes were prepared. The temperature of preparation varied from room temperature to 300 degrees C. The particles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), differential thermal analysis (DTA), and photoluminescence spectrum. X-ray diffraction patterns revealed that the particles exhibited pure zinc-blende crystal structure and that particle size increased with increasing temperature. The TEM micrograph showed that the mean particle size was about 40 nm for the sample heated at 100 degrees C. A blue shift was observed in the photoluminescence emission spectrum. A possible mechanism of the reaction corresponding to our observation is proposed, (C) 2000 Elsevier Science Ltd. All rights reserved.

Preparation and luminescence properties of the ternary europium complex incorporated into an inorganic polymer matrix by a sol-gel method

Ternary europium complexes with thenoyltrifluoroacetone (TTA) and phenanthroline (phen) were incorporated into SiO2/polymer matrix by a sol-gel method. The gels exhibit the characteristic emission bands of europium ion. In addition, Eu3+ presents a longer fluorescence lifetime in gel than in the corresponding pure complex powder. Concentration effects on the luminescence intensity were investigated. The reasons that are responsible for above results are also discussed in the context.

Preparation of the phosphor BaMgAl10O17 : Eu2+ by the surface diffusion method

A surface diffusion method was proposed and applied to prepare blue phosphor BaMgAl10O17:Eu2+. The results show that, compared with the direct synthesis method by common high temperature solid state, the concentration of Eu2+ in the phosphor BaMgAl10O17:Eu2+ prepared by the surface diffusion method can be greatly reduced owing to the activator Eu2+ ions distributed mainly over the surface of the phosphor. It is possible to reduce the cost of this kind of the luminescent materials with the aid of the surface diffusion method.

A new method for the preparation of fullerol

Reaction of C-60 with excessive potassium in toluene at refluxing temperature results in black precipitate KaC60 with high conversion, which can completely be hydrolyzed to prepare the fullerol. Investigations including FT-IR. H-1 NMR C-13 NMR, UV-Vis and FABMS of the product were reported.

Preparation of lanthanide hydrides of nanometric size by the catalytic method

Rare-earth metals were hydrogenated in the presence of TiCl4 catalyst in tetrahydrofuran (THF) at 45 degreesC under normal pressure. Transmission electron micrographs showed that the re. sulting lanthanide hydrides were in the form of nanoparticles. The rate of hydrogenation decreased with increasing atomic number of the rare-earth elements.

Preparation of titania-based catalysts for formaldehyde photocatalytic oxidation from TiCl4 by the sol-gel method

Titania sols were prepared by acid hydrolysis of a TiCl4 precursor instead of titanium alkoxides. The effect of acid concentration on the particle size and stability of sol was investigated. Stable titania sols with mean particle size of 14 nm could be obtained when the H+/Ti molar ratio was 0.5. The titania sols were modified with Pt, SiO2, ZrO2, WO3 and MoO3 to prepare a series of modified catalysts, which were used for the photocatalytic oxidation of formaldehyde at 37 degreesC. They showed different photocatalytic activities due to the influence of the additives. Comparing with pure TiO2, the addition of silica or zirconia increased the photocatalytic activity, while the addition of Pt and MoO3 decreased the activity, and the addition Of WO3 had little effect on the activity. It is of great significance that the conversion of formaldehyde was increased up to 94% over the SiO2-TiO2 catalyst. The increased activity was partly due to higher surface area and porosity or smaller crystallite size. A comparison of our catalyst compositions with the literature in this field suggested that the difference in activity due to the addition of a second metal oxide maybe caused by the surface chemistry of the catalysts, particularly the acidity. (C) 2001 Elsevier Science B.V. All rights reserved.