Kinetics of autocatalytic acid hydrolysis of cellulose with crystalline and amorphous fractions

The acid hydrolysis of cellulose with crystalline and amorphous fractions is analyzed on the basis of autocatalytic model with a positive feedback of acid production from the degraded biopolymer. In the condition of low acid rate production compared with hydrolysis rate, both fraction of cellulose decrease exponentially with linear and cubic time dependence, and the normalized number of scissions per cellulose chain follows a sigmoid behavior with reaction time. The model predicts that self generated acidic compounds from cellulose accelerate the degradation of the biopolymer. However, if the acidic compounds produced are volatile species, then their release under low pressure will reduce the global rate of degradation of cellulose toward its intrinsic rate value determined by the residual acid catalyst present in the starting material.

Análise não linear física e geométrica de pórticos espaciais

Apresenta-se uma formulação do tipo incrementaliterativa destinada a análise não linear de pórticos espaciais. Considera-se os efeitos não lineares introduzidos pelas mudanças de configuração geométrica da estrutura e também pela combinação destes efeitos com aqueles inerentes ao comportamento plástico exibido pelo material. As relações cinemáticas empregadas permitem a consideração de deslocamentos arbitrariamente grandes, acompanhadas de pequenas deformações . A modelagem do comportamento plástico do material é efetuada através do conceito de rótula plástica, estabelecido a partir de um critério de plastificação generalizado. Adota-se uma matriz de rigidez geométrica de barra baseada em momentos semitangenciais. Para elementos com extremos plastificados, é deduzida uma matriz de rigidez elasto-plástica. Emprega-se um método numérico do tipo incremental-iterativo, que utiliza como condição básica de controle da análise a constância do trabalho realizado pelos incrementos de cargas, em cada passo incremental (Método de Controle por Trabalho).A formulação permite uma descricão completa do desempenho mecânico da estrutura, inclusive em estágio de deformação pós-crítico em que ocorre regressão do carregamento com aumento de deslocamentos, ou vice-versa. A formulação foi implementada em um programa computacional elaborado em linguagem FORTRAN. Vários exemplos numéricos são apresentados para mostrar a eficiência das procedimentos propostos.

Criação da matéria em cosmologias com velocidade da luz variável e eletrônico não-linear

In this work we obtain the cosmological solutions and investigate the thermodynamics of matter creation in two diferent contexts. In the first we propose a cosmological model with a time varying speed of light c. We consider two diferent time dependence of c for a at Friedmann-Robertson- Walker (FRW) universe. We write the energy conservation law arising from Einstein equations and study how particles are created as c decreases with cosmic epoch. The variation of c is coupled to a cosmological Λ term and both singular and non-singular solutions are possible. We calculate the "adiabatic" particle creation rate and the total number of particles as a function of time and find the constrains imposed by the second law of thermodynamics upon the models. In the second scenario, we study the nonlinearity of the electrodynamics as a source of matter creation in the cosmological models with at FRW geometry. We write the energy conservation law arising from Einstein field equations with cosmological term Λ, solve the field equations and study how particles are created as the magnetic field B changes with cosmic epoch. We obtain solutions for the adiabatic particle creation rate, the total number of particles and the scale factor as a function of time in three cases: Λ = 0, Λ = constant and Λ α H2 (cosmological term proportional to the Hubble parameter). In all cases, the second law of thermodynamics demands that the universe is not contracting (H ≥ 0). The first two solutions are non-singular and exhibit in ationary periods. The third case studied allows an always in ationary universe for a suficiently large cosmological term

The peremptory influence of a uniform background for trapping neutral fermions with an inversely linear potential

The problem of neutral fermions subject to an inversely linear potential is revisited. It is shown that an infinite set of bound-state solutions can be found on the condition that the fermion is embedded in an additional uniform background potential. An apparent paradox concerning the uncertainty principle is solved by introducing the concept of effective Compton wavelength.

Mitigation of symmetry condition in positive realness for adaptive control

Feasibility of nonlinear and adaptive control methodologies in multivariable linear time-invariant systems with state-space realization (A, B, C) is apparently limited by the standard strictly positive realness conditions that imply that the product CB must be positive definite symmetric. This paper expands the applicability of the strictly positive realness conditions used for the proofs of stability of adaptive control or control with uncertainty by showing that the not necessarily symmetric CB is only required to have a diagonal Jordan form and positive eigenvalues. The paper also shows that under the new condition any minimum-phase systems can be made strictly positive real via constant output feedback. The paper illustrates the usefulness of these extended properties with an adaptive control example. (C) 2006 Elsevier Ltd. All rights reserved.

Correlação linear e espacial dos componentes de produção e produtividade da soja

The soybean is the crop most cultivated in Brazil, with great socioeconomic importance. In the agriculture year 2008/09 in Selviria County, Mato Grosso do Sul State, in the Brazilian Savannah, was analyzed the production components and the soybean yield cultivated in a Typic Acrustox on no-tillage. The main purpose objective was select among the production components number of pods per plant, number of grains per pod, number of grains per plant, mass of a thousand grains, mass of grains per plant and population of plants, which of the best linear and spatial correlation aiming explain the soybean yield variability. The irregular geostatistical grid was installed to collect of data, with 120 sampling points, in an area of 8.34 ha. The values of spatial dependence range to be utilized should be among 38.1 and 114.7 meters. The model of the adjusted semivariograma was predominantly the spherical. of the lineal and spatial point of view, the number of pods per plant and the mass of grains per plant they were correlated in a direct way with the soybean yield, demonstrating be the best components to esteem her.

Correlação linear entre componentes da produção e produtividade do arroz de terras altas em sistema plantio direto

The rice is one of the main sources of the humanity's feeding. During the agricultural year 2009/2010, in Selviria County, Mato Grosso do Sul State, in the Brazilian Savannah, an experiment was installed with rice upland in a Dystropherric Red Latosol (Typic Acrustox) under no-tillage, irrigated by central pivot, with the purpose of selecting the best components production to explain the variability the irrigated rice yield upland. The geostatistical grid was installed, to collect the data, with 120 sampling points, in an area of 3.0 ha and and homogeneous slope of 0.055 m m(-1). The medium rice yield was of the 5980 kg ha(-1). For the simple lineal regressions, the number of spikelets grenades for panicle presented the best direct potential correlation with the yield rice, given for: PGO = 115,5.NEG(0,770). However, for the multiple lineal regressions, the equation equacao PGO = 2754,30-411,55.NEG-461,07. NEC+436,59. NET it was the one that better she came to esteem the yield rice. However, spatial, it was not possible to establish correlation between the yield rice and the components production, once none of those it presented spatial dependence in their data.

Thermodynamic analysis of a non linear lattice

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Dependence of anuran diversity on environmental descriptors in farmland ponds

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Frame dependence of the pair contribution to the pion electromagnetic form factor in a light-front approach

The frame dependence of the pair-term contribution to the electromagnetic form factor of the pion is studied within the Light Front approach. A symmetric ansatz for the pion Bethe-Salpeter amplitude with a pseudo scalar coupling of the constituent to the pion field is used. In this model, the pair term vanishes for the Drell-Yan condition, while it is dominant for momentum transfer along the light-front direction.

Correlação linear e espacial entre o rendimento de grãos do feijoeiro e a resistência mecânica à penetração em um Latossolo Vermelho distrófico

A resistência mecânica à penetração apresentada pelo solo exerce grande influência sobre o desenvolvimento vegetal, uma vez que o crescimento das raízes, assim como o rendimento das culturas, varia de forma inversamente proporcional ao seu valor. No ano agrícola de 2001/2002, na Fazenda Experimental de Ensino e Pesquisa da Faculdade de Engenharia/UNESP - Campus de Ilha Solteira, foram analisados o rendimento de grãos do feijoeiro (PG) e a resistência mecânica à penetração (R), de um Latossolo Vermelho distrófico. O objetivo foi apurar diretrizes relacionadas com o aumento da produtividade agrícola em questão, estudando a correlação linear e a espacial entre a PG e a R. Foi instalada uma rede geoestatística para a coleta dos dados do solo e da planta, estabelecida com espaçamentos de 5 x 5 m e 2,5 x 2,5 m, que continham 120 pontos amostrais distribuídos numa área de 1.875 m². A correlação linear entre a PG e a R foi praticamente nula, uma vez que, dependendo das profundidades estudadas do solo, apresentou coeficientes de correlação (r) menores do que 0,20. A análise geoestatística apresentou boa estrutura de dependência espacial, tanto para a PG quanto para a R, quando analisadas isoladamente. Entretanto, a análise espacial conjunta de tais atributos apresentou-se inconsistente. Assim, com o aumento da resistência mecânica à penetração, em determinada região do solo ocorreu ora aumento, ora diminuição do rendimento de grãos do feijoeiro.

Hq(4) symmetry: the linear q-harmonic oscillator based on generalized irreps of the q-deformed Heisenberg algebra

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Classes of exact Klein-Gordon equations with spatially dependent masses: Regularizing the one-dimensional inversely linear potential

In this work we consider the effect of a spatially dependent mass over the solution of the Klein-Gordon equation in 1 + 1 dimensions, particularly the case of inversely linear scalar potential, which usually presents problems of divergence of the ground-state wave function at the origin, and possible nonexistence of the even-parity wave functions. Here we study this problem, showing that for a certain dependence of the mass with respect to the coordinate, this problem disappears. (c) 2006 Elsevier B.V. All rights reserved.

Giant non-linear absorption in Er3+-doped fluoroindate glass

Non-linear absorption is observed in Er3+-doped fluoroindate glass (in mol% 37InF2:20ZnF2:20SrF2:16BaF2:2GdF2: 2NaF:1GaF3:2ErF3) when the sample is irradiated with a CW laser emitting at 650 nm. An intensity dependence of the optical transmittance is detected. Saturation and sequential absorption of two photons are responsible for the decrease of 50% in the transmittance. The results are explained by simple models which are solved based on rate-equations for the populations of energy levels.

Design of microirrigation systems in sloping lands using linear programming

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)