Spring Diatom Blooming Phases in a Representative Eutrophic Bay of the Three-Gorges Reservoir, China

We investigated dynamics of the phytoplankton community and abiotic factors in Xiangxi Bay of the Three-Gorge Reservoir, China, by daily sampling, a specific site during a spring algal bloom (February 23-April 28, 2005). Among the 76 taxa observed, Asterionella formosa and Cyclotella spp. were the dominants, accounting for 47.2% and 29.9% of the total abundance, respectively. We determined the five distinct developing phases of the bloom by analyzing the dissimilarity of physicochemical parameters. Simultaneously, six phytoplankton community groups were distinguished by TWINSPAN classifications. The pattern for algal community succession was similar to that for the bloom phase shift, and the structural complexity of communities significantly decreased over time. Water temperature and silicate were the main factors that related to the development of the bloom and the shifts of the phytoplankton community.

Monitoring organochlorine pesticides and polychlorinated biphenyls in Baiyangdian Lake using microbial communities

We used polyurethane foam units (PFUs) to collect persistent organic pollutants (POPs) from four sites in Baiyangdian Lake in July 2003. Following extraction from the PFUs, relative concentrations of seven organochlorine pesticides (OCPs) and ten polychlorinated biphenyls (PCBs) were determined by gas chromatography. OCPs and PCBs were detected in the microbial communities from all the four sampling stations. In terms of the total concentration of POPs (OCPs+ PCBs), two river estuary stations had more POP (18.45 mu g/L and 9.77 mu g/L) than the two mid-lake stations (4.75 mu g/L and 5.21 mu g/L), indicating that Baiyangdian Lake was significantly impacted by inflow from the Fu River and Baigou River.

牦牛粪便对青藏高原东部高寒草甸土壤养分系统的影响

川西北高寒草甸位于青藏高原东部地区，是我国四大牧区之一，也是长江和黄河等江河源区的重要水源涵养功能区。近几十年来，大量牦牛粪便被牧民作为生物能源、肥料或者食用菌产业的原料而利用，为草原生态系统的养分平衡增加了生态风险。鉴于在青藏高原地区针对牦牛粪便的相关研究尚未见报道，本文从粪便和土壤养分相互变化趋势的角度出发，研究了粪便在夏秋两季的分解状况和粪便其下及其周围土壤的养分变化。通过此研究，将有助于了解牦牛粪便在自然状态下的分解速率以及粪便对土壤养分及土壤微生物生物量的影响，为粪便对草地土壤生态系统的贡献提供概念性认识，同时也为高寒草甸草地这种脆弱生态系统的可持续管理提供理论依据。 针对牦牛粪便自身养分释放及其对土壤在时间和空间尺度上的影响，本文通过模拟牛粪堆积，在不同时间和固定区域内对牛粪和土壤进行了夏秋两季的采样测定，分析了牛粪及土壤NO3--N、NH4+-N、速效K、无机P、有机C、全N 和全P 含量随时间的变化趋势。得到如下结果： 1. 在研究区域内，牛粪对草地生态系统具有较强的养分（N、P）贡献能力。据初步统计，其估值大致为氮素699~932 kg ha-1，P 素为110~147 kg ha-1。牛粪（湿重、干重）在夏秋季节的分解速率具有较大差异，夏季显著快于秋季。夏季牛粪湿重、干重在2 个月左右之后分别降为初期的14%和24%，而秋季同期分别降为35%和52%。牛粪养分（NO3--N、NH4+-N、速效K、无机P、有机C、全N 和全P）的分解速率在夏季也要显著快于秋季。秋季经过2 个月左右的分解之后，牛粪以上含量分别降至初始态的32%、60%、36%、64%、58%、63%和43%，远高于夏季的同期水平。 2. 在不同季节，牛粪周围的土壤养分（NO3--N、NH4+-N、速效K 和无机P）含量变化随时间改变呈现相同的趋势。但是，牛粪周围不同远近下土壤养分随时间的动态变化幅度略有不同。粪下土壤养分含量随时间变化波动较大，距粪便越远，随时间变化的变幅越为平缓。总体来说，在夏季由于粪便分解较快，对土壤养分的持续作用时间不及秋季，秋季粪便分解变慢，表现出养分的缓释特征。其次，牛粪对粪下土壤影响的持续时间也长于对周围土壤的作用时间。 3. 粪便对土壤养分（NO3--N、NH4+-N、速效K、无机P）影响的范围在不同季节具有差异。夏季要高于秋季，但对周围土壤养分影响的持续时间低于秋季。在夏季短期内，牛粪对土壤NO3--N 和速效K 含量的影响范围能够超过30cm，而对NH4+-N 和无机P 的影响范围则介于10cm 和30cm 之间。在2 个月左右之后，牛粪对周围土壤养分的影响能力基本消失。在秋季，牛粪对周围土壤养分影响范围难以达到30cm 处。粪便在夏季对其下土壤和周围土壤的有机C、全N 和全P 含量并无显著影响，但在秋季能显著增加其下土壤有机C、全N 和全P 含量。 4. 牛粪在秋季对土壤SMB-C、SMB-N 和SMB-P 含量的影响能够持续2 个月以上，由于秋冬季节牛粪分解缓慢，因此推断这种效应持续时间至少能够1 年左右。另一方面，牛粪在秋季对土壤SMB-C、SMB-N 和SMB-P 含量的影响范围主要集中在其下土壤，而周围的影响效应并不明显。 The grassland on the eastern fringe of Qinghai-Tibetan Plateau was one of the four greatest pasture zones in our country and the main water conservation function zones in the hesastream of Yangtse River and Huanghe river. Rencent years, lots of dung in this area was used as biological energy, fertilizer or material of fungoid growing, leading to high risk of nutrient banlance in grassland ecosystem. In view of the researches on the impact of yak dung in this area are relatively rare, the present study focused on the relationship of dung and soil nutrient transformation in sunmer and autumn, which could profoundly illuminate the mechanism of dung decomposition and the effect of dung on soil chemical properties and soil microbe biomass. The present study also contributed to a basic understand and provided scientific management in the high-frigid ecosystem. Decomposition of yak dung and its effect on soil chemical properties in eastern grassland of Qinghai-Tibetan Plateau were determined. The study simulated the real dung pats, took dung and soil samples at different time and fixed-point in summer and autumn. The samples were analysed for NO3--N, NH4+-N, available K, inorganic P, total organic C (TOC), total N (TN), total P (TP). It was concluded that: 1. In study area, the yak dung supplied to ecosystem substantial nutrient. It is estimated that the N contribution of dung was approximately 699~932 kg ha-1, P contribution was approximately 110~147 kg ha-1. The rate of yak decomposition was more rapid in summer than autumn, the wet and dry weight of yak decreased to 14% and 24% respectively after 2 months when dung excreted in summer, with 35% and 52% in autumn. The content of NO3--N、NH4+-N、available K、inorganic P、TOC、TN and TP in dung decomposed more rapid in summer too. After 2 months when dung excreted in autumn, the content of above nutrient decreased to 32%、60%、36%、64%、58%、63% and 43% respectively，which were significantly higher than summer. 2. The content of NO3--N、NH4+-N、available K and inorganic P in soil around dung had the same transformation trend in each season, whereas it was distinguishing at different gradient of distance from dung, the nutrient in soil below dung had the most significant change while the more far from dung, the less change in soil. It was concluded that the yak dung had prolong impacts on soil in autumn compared with summer, besides, it aslo showed that the yak dung had protract effect on soil below dung compared with soil around dung. 3. The yak dung had expansive impact on soil around dung in summer whereas had relatively short effect compared with autumn. In short-term at summer, there was a significant increase about the content of NO3--N and available K around 30cm radius from dung pat while the content of NH4+-N and inorganic P between 10cm to 30cm. After 2 months, the impact almost disappeared. In autumn, the effect was hard to reach 30cm. The yak dung had no significant effects on the content of TOC、TN and TP in soil below or around dung in summer whereas there was a obvious increase in soil below dung pat in autumn. 4. The duration of effect of yak dung on soil microbial biomass(SMB) C、N and P was at least 2 months, maybe even more than 1 year. On the other hand, the impact of dung on SMB-C、SMB-N and SMB-P mainly acted on soil below dung while no obious effect on soil around dung.

Iron and inorganic carbon in Liaodong Gulf sediments of Bohai Sea in China

Iron in seawater is an essential trace metal for phytoplankton that plays an important role in the marine carbon cycle. But most studies focused on oceanic iron fertilization in high nutrient low chlorophyll (HNLC) seawaters. A study of inorganic carbon (IC) forms and its influencing factors was presented in Liaodong Gulf sediments, and especially the influence of iron was discussed in detail. Inorganic carbon in Liaodong Gulf sediments was divided into five forms: NaCl, NH3·H2O, NaOH, NH2OH·HCl and HCl. The concentration of NaCl and NaOH forms were similar and they only occupied the minority of total inorganic carbon (TIC). However, NH3·H2O, NH2OH·HCl and HCl forms were the principal forms of TIC and accounted for more than 80% of TIC. Especially, the percentage of NH3·H2O form was much higher than that in the Changjiang River Estuary and Jiaozhou Bay sediments. All forms of inorganic carbon were influenced by organic carbon,pore water, iron, pH, redox potential(Eh) and sulfur potential(Es) in sediments, moreover, the influences had different characteristics for different IC forms. However, the redox reactions of iron affected mainly active IC forms. Iron had little effect on NH2OH·HCl and HCl forms of IC which were influenced mainly by pH. Iron had a stronger influence on NaCl, NaOH and NH3·H2O forms of IC; the influence of Fe2+ was higher than Fe3+ and its effect on NH3·H2O form was stronger than on NaCl and NaOH forms.

Clay mineral distributions in the southern Yellow Sea and their significance

To better understand the characteristics of the clay minerals in the southern Yellow Sea, the X-ray quantitative determinations have been carried out for the surface samples obtained from the Yellow Sea. With newly compiled clay mineral synoptic maps, the depositional processes were described for four main clay minerals (illite, chlorite, kaolinite and smectite). The analysis shows that most clay minerals are of terrigenous source with the Huanghe River acting as the major sediment supplier. Besides, the source of muddy sediments in the Yellow Sea was also discussed. As for the central Yellow Sea mud (CYSM), the sediments in its northern part mainly come from the Huanghe River, and those in the rest are of multi-origin. Very similarly, a large amount of sediments in the northern part of the southeastern Yellow Sea Mud (SEYSM) derive from the Keum River and Yeong-san River, while those in the southern part are of multi-origin.

Preservation of black carbon in the shelf sediments of the East China Sea

Concentrations and carbon isotopic (C-14, C-13) compositions of black carbon (BC) were measured for three sediment cores collected from the Changjiang River estuary and the shelf of the East China Sea. BC concentrations ranged from 0.02 to 0.14 mg/g (dry weight), and accounted for 5% to 26% of the sedimentary total organic carbon (TOC) pool. Among the three sediment cores collected at each site, sediment from the Changjiang River estuary had relatively high BC contents compared with the sediments from the East China Sea shelf, suggesting that the Changjiang River discharge played an important role in the delivery of BC to the coastal region. Radiocarbon measurements indicate that the ages of BC are in the range of 6910 to 12250 years old B. P. (before present), that is in general, 3700 to 9000 years older than the C-14 ages of TOC in the sediments. These variable radiocarbon ages suggest that the BC preserved in the sediments was derived from the products of both biomass fire and fossil fuel combustion, as well as from ancient rock weathering. Based on an isotopic mass balance model, we calculated that fossil fuel combustion contributed most (60%. 80%) of the BC preserved in these sediments and varied with depth and locations. The deposition and burial of this "slow-cycling" BC in the sediments of the East China Sea shelf represent a significant pool of carbon sink and could greatly influence carbon cycling in the region.

Warming trend in northern East China Sea in recent four decades

Global warming has become a notable trend especially since an abrupt climate change in 1976. Response of the East China Sea (ECS) to the global warming trend, however, is not well understood because of sparse long-term observation. In this paper, hydrographic observation data of 1957-1996 are collected and reviewed to study climatological variability in northern ECS. Significant warming trends are found in both summer and winter. In summer, the average SST is about 0.46A degrees C higher during the period of 1977-1996 than that of 1957-1976, and the Taiwan Warm Current Water (TWCW) was strengthened. In winter, despite of the cooling effect in the coastal areas adjacent to the Changjiang (Yangtze) River Estuary (CRE), the average SST increase was about 0.53A degrees C during the same period. The causes of this SST warming up in summer are different from in winter. The warming trend and intensification of the TWCW in summer were primarily influenced by the strengthening of the Kuroshio transport, while the warming in winter was mainly induced by the variability of the climate system.

现代黄河三角洲地区地面沉降特征研究

针对目前现代黄河三角洲地区普遍存在的地面沉降问题，本文以整个现代黄河三角洲平原地区为研究对象，通过收集的重复性水准测量数据、遥感影像、渤海海底及三角洲平原沉积物物理力学数据、长期验潮站数据以及前人文献数据等资料，综合运用雷达差分干涉测量技术（D-InSAR）、工程地质学、GIS和随机动态分析方法，探讨了现代黄河三角洲地区近期地面沉降的现状，并对其自然因素影响下的形成与发展过程进行了综合分析，最后探讨了地面沉降对三角洲发育演化的环境地质效应。 研究结果表明：现代黄河三角洲在以宁海为顶点的河口扇形区域，近期均经历了不同程度的地表下沉过程，但是随区域地理位置和时间的不同，地表变化空间差异性比较明显；三角洲顶点附近区域的下沉速率自上世纪末开始逐渐减小，后期甚至出现轻微的抬升；滨海沿岸附近地区的地表形变特征相对比较复杂，各期叶瓣相互叠置及其各类沉积物的不均匀分配，使由沉积物自然固结压实引起的地表形变具有显著的空间差异；目前，除清水沟流路叶瓣表现为快速沉降以外，其它滨海沿岸区基本上都表现为微弱的下沉。自然状态下三角洲平原的地面沉降分布主要受中―高压缩性软土层和黏性土层固结沉降的控制，分别占沉积物总固结沉降量的40～95%和3～12%（或30～50%）。三角洲平原区沉积层的自重固结沉降已进入后期缓慢沉降阶段，软弱土层的性质及厚度是控制本区不均匀沉降的主导因素。黄河新近沉积物的自重应力对海底浅层沉积物和前三角洲沉积层的固结压缩影响较大，特别是海底淤泥和淤泥质土层在受压初期会发生快速固结压缩，足以引起明显的地表下沉。近几十年来，因区域构造运动和均衡运动引起的地表绝对下沉速率约为3.42 mm/a。该区地面沉降的时空差异性及其在相对海平面上升中的叠加作用，不仅关系到三角洲的垂向发育过程，且对黄河尾闾的摆动、下游河道的淤积、海岸侵蚀和潮滩冲刷等方面都有着重要的影响。

长江口上升流区营养盐动力学

近年来，东中国海赤潮灾情严重，且74.7%的赤潮集中在 30°30′～32°00′N、122°15′～123°10′E的“赤潮高发区”。在研究该区赤潮成因时，长江口沿岸上升流的影响越来越受到人们的关注，并被一些专家观测和研究。但目前为止，针对该区营养盐动力学特征及其对叶绿素a影响的研究较少，且不系统。 本文根据2004年四个季度月的调查资料，系统地探讨了长江口上升流区营养盐动力学特征；估算了上升流的营养盐通量，并和陆源输入通量进行了比较。初步探讨了上升流对该区营养盐结构和浮游植物生长的影响。为深入研究长江口富营养化和赤潮形成机制提供了参考。 结果表明春季在122°20′～123°00′E，31°00′～32°00′N以北海域存在低温、高盐、低溶解氧的沿岸上升流。它不但可把底层高含量磷酸盐输送到10m层以上海区，而且还为上层海区输入了相对低含量硝酸盐和硅酸盐，从而改善了上层营养盐结构，使得营养盐比值接近Redfield Ratios，同时还改善了上层的透明度；从而有利于浮游植物的繁殖。夏季上升流受到强大的长江冲淡水压制，表现不如春季明显，主体水团出现在122°20′～123°00′E，31°15′～31°50′N海区10m层以下。 在秋、冬季，上升流现象被更强的对流现象所掩盖，表现为台湾暖流表层水的入侵。表、底层水域不仅温、盐度分布十分接近，而且营养盐结构差异也较小。冬季台湾暖流水中的磷酸盐含量远比秋季高，与春、夏季上升流水团中磷酸盐含量接近。硝酸盐和硅酸盐含量比秋季稍高，比春、夏季上升流水团中的含量稍低。 叶绿素a季节性分布表明，在春、夏季的10m层以下水域，叶绿素a受到透明度限制，含量相差不大；而在表层和10m层之间，春季叶绿素a的含量远高于夏季，说明春季的营养盐结构和自然条件更有利于浮游植物的繁荣生长。在秋季台湾暖流水影响的区域，表层叶绿素a含量较夏季稍低。而冬季该区叶绿素a含量则是最低的。 对长江口上升流水团春季营养盐通量的计算结果表明，上升流水团中磷酸盐输送通量远远高于长江径流输入，是其径流通量的两倍以上，可能会成为影响该海区磷酸盐分布以及浮游植物生长的一个值得关注的因素。 关键词：上升流，营养盐动力学，营养盐结构，叶绿素a，长江冲淡水

南海北部珠江口近海地质风险

南海是我国海洋灾害地质条件最为复杂、潜在地质灾害危险性最大的海区。南海北部尤其是珠江口地区的地理位置尤为重要，是我国经济开发的门户地区。本文使用GeoSwath Plus多波束系统对南海北部珠江口外海面进行了水深测量，通过系统配套软件对多波束数据的精细处理，得出高密度的水深数据以及旁扫声纳数据，经过对数据以及相关成图图件的分析，利用对灾害地貌的加权统计模型对该地区的地质灾害进行定量评定。目前国内使用的多波束型号较多，根据其频率的不同可分为浅水、中水、深水多波束系统。根据波束形成原理（数控法和相干法）的不同可分为传统多波束和具有相干特点的多波束系统，这两种多波束系统由于其原理的差异，在各种性能表现上都存在不同之处，本文从原理及其各种不同的性能表现上对该多波束系统与传统多波束系统进行了详细对比论证。 在对调查区区域地质、第四纪地质充分调研的基础上，通过对调查区地形的概况和相关影响因素的论述（诸如水动力条件、构造特征等），结合水深图、地形图和多条地形剖面的分析，得出该海域在工程施工方面海底地形上的影响因素。 通过对本区所发现的地貌类型，结合海洋地质灾害类型分析，通过对相关地质灾害类型的统计说明，得出该地区地质灾害的影响因素及其潜在危害程度。通过提取南海北部的灾害地质因素和对调查区灾害地质环境的充分研究，以灾害地质因素为评价因子，采用加权统计模型对研究区的海底稳定性进行分区定量评价。利用评价结果，确定了调查区基于地貌类型区划的海底稳定性级别。

长江口水文、泥沙过程与圆桩冲刷的数值模拟

本文主要利用ECOMSED模式对长江口及邻近海域的水文、泥沙过程进行三维数值模拟，并结合实测资料分析其水动力、泥沙输运、底床冲淤等特征；然后利用欧拉二相流模型模拟小尺度条件下长江口底床上圆桩周围的水流和泥沙冲刷、输运规律。 通过资料分析和ECOMSED数值模拟结果比较，我们得出：长江口口门内为非正规半日潮流区，潮流运动形式多为往复流，落潮流占优。落潮流速大于涨潮流速，流速垂向分布从表层到底层递减。悬沙浓度与流速关系密切，一般来说，流速越大，悬沙浓度越高；一个潮周期过程中会出现两次、三次或四次泥沙再悬浮，分别是涨急、落急、涨转落、落转涨时刻；盐水楔结构对粘性与非粘性悬沙浓度的分布起决定性作用，转流时泥沙再悬浮主要是由于这时会出现盐水楔，并形成垂向环流，使床面大量未被固结的泥沙再悬浮，形成峰值。悬浮泥沙垂向分布可分为垂线型，斜线型，抛物线型和L型。流场和底床冲淤变化与水深关系密切：深水区，流速较大，底床冲淤变化也较大。其中，受径流影响区表现为淤积，受潮流影响区表现为冲刷；浅水区基本表现为淤积。 从模式运行结果和实测资料比较可以看出，该模型可以较好的模拟长江口水流、悬浮泥沙分布与变化；能够再现在径流入海口处，盐水楔结构及其诱生的垂向环流从形成到发展，又到消失的完整过程；也能够展示底床的冲淤变化。对于我们模拟长江口背景流场，了解该区域内水动力变化、悬浮泥沙输运、底床冲淤等有重要意义。 在欧拉二相流模型对长江口底床上圆桩周围的水流和局部冲刷数值模拟过程中，我们不仅考虑水流和泥沙之间的作用，还引入泥沙颗粒之间的相互影响。模拟结果较合理的展示了圆桩周围的流场类型和底床冲刷变化：在圆桩前方，流速减小并形成垂向涡旋，从而产生局部冲刷；在圆桩两侧，水流加速，挟带上游泥沙向下输送，并在内侧堆积；而在圆桩后面，存在流速分离区。在该分离区内流速很小，并且当流速较大时，会产生回流，形成两个对称的漩涡。流速越大，圆桩前由垂向涡旋引起的局部冲刷就越明显；而当底床泥沙粒径变小时，泥沙临界起动流速变小，底床也更容易被冲刷。悬浮泥沙浓度分布受流场的影响，并且当粒径小而流速大时，能悬浮到更高的深度。

夏季长江口外海区域上升流现象的数值研究

中国沿岸海域是上升流的多发区. 渤、黄海域，东海陆架区，台湾海峡，以及南海沿岸都存在众多的上升流区. 上升流有利于穿越陆架的物质输运，可以把下层海水中的营养物质带至真光层，促进浮游植物生长，为赤潮爆发提供有利条件. 长江口外和浙江沿岸上升流区连续几年爆发大规模赤潮，该海域已成为我国近海赤潮严重的区域之一. 同时上升流也是该海域海洋渔场形成的重要动力因子. 因此，对长江口外及浙江沿岸上升流的研究具有重要的意义. 本文基于Blumberg等（1996）的ECOMSED模式，对长江口外海区域夏季的上升流现象进行了数值模拟研究. 为了提高对长江口外海区域上升流模拟的准确性和可靠性，模式综合考虑了径流，风应力，环流，热通量和M2，S2，K1，O1四个主要分潮的作用. 本文首先进行控制实验，综合考虑各种动力因子，模拟长江口外南部冷水区的上升流现象，再单独考虑各个动力因子做数值实验，并对各种数值实验结果进行分析对比来研究产生该区域上升流现象的主要原因. 我们设计了3个数值实验：不考虑风应力和热通量、不考虑环流、仅考虑温盐和潮因子. 方便起见，将综合考虑各种动力因子的数值模拟称作控制实验. 各种实验结果的分析表明，长江口外水下河谷的南边（杭州湾口门中心东侧），上升流主要是由向北流动的台湾暖流通过底Ekman效应和陆坡的抬升共同作用产生的. 夏季偏南风对长江口外水下河谷西侧上升流的产生有一定影响，但作用不大. 此外，潮汐潮流对上升流的产生也起着一定的作用，但在本文关注的上升流区潮作用影响不大.

Relationships between nitrogen and phosphorus forms and ratios and the development of dinoflagellate blooms in the East China Sea

During late spring and early summer of 2005, large-scale (> 15 000 km(2)), mixed dinoflagellate blooms developed along the the coast of the East China Sea. Karenia mikimotoi was the dominant harmful algal bloom species in the first stage of the bloom (late May) and was succeeded by Prorocentrum donghaiense approximately 2 wk later. Samples were collected from different stations along both north-south and west-east transects, from the Changjiang River estuary to the south Zhejiang coast, during 3 cruises of the Chinese Ecology and Oceanography of Harmful Algal Blooms Program, before and during the bloom progression. Nitrogen isotope tracer techniques were used to measure rates of NO3-, NH4+, urea, and glycine uptake during the blooms. High inorganic nitrogen (N), but low phosphorus (P) loading from the Changjiang River led to high dissolved inorganic N:dissolved inorganic P ratios in the sampling area and indicate the development of P limitation. The rates of N-15-uptake experiments enriched with PO43- were enhanced compared to unamended samples, suggesting P limitation of the N-uptake rates. The bloom progression was related to the change in availability of both organic and inorganic N and P. Reduced N forms, especially NH4+, were preferentially taken up during the blooms, but different bloom species had different rates of uptake of organic N substrates. K mikimotoi had higher rates of urea uptake, while P. donghaiense had higher rates of glycine uptake. Changes in the availability of reduced N and the ratios of N:P in inorganic and organic forms were suggested to be important in the bloom succession. Nutrient ratios and specific uptake rates of urea were similar when compared to analogous blooms on the West Florida Shelf.

Estuarine nutrient loading affects phytoplankton growth and microzooplankton grazing at two contrasting sites in Hong Kong coastal waters

To investigate the effects of enhanced nutrient loading in estuarine waters on phytoplankton growth and microzooplankton grazing, we conducted monthly dilution experiments at 2 stations in Hong Kong coastal waters with contrasting trophic conditions. The western estuarine station (WE) near the Pearl River estuary is strongly influenced by freshwater discharge, while the eastern oceanic station (EO) is mostly affected by the South China Sea. Growth rates of phytoplankton were often limited by nutrients at EO, while nutrient limitation of phytoplankton growth seldom Occurred at WE due to the high level of nutrients delivered by the Pearl River, especially in the summer rainy season. Higher chlorophyll a, microzooplankton biomass, phytoplankton growth and microzooplankton grazing rates were found at WE than at EO. However, the increase in chlorophyll greatly exceeded the increase in phytoplankton growth rate, reflecting different response relationships to nutrient availability. Strong seasonality was observed at both stations, with temperature being an important factor affecting both phytoplankton growth and microzooplankton grazing rates. Picophytoplankton, especially Synechococcus, also exhibited great seasonality at EO, with summer abundances being 2 or 3 orders of magnitude higher than those during winter, Our results confirm that in eutrophic coastal environments, microzooplankton grazing is a dominant loss pathway for phytoplankton, accounting for the utilization of >50%, of primary production on average.

Persistent organic pollutant residues in the sediments and mollusks from the Bohai Sea coastal areas, North China: An overview

The Bohai Sea costal area is one of the most developed zones of China and the sewage water from populous and developed cities, including Beijing, Tianjin. Qinhuangdao and Dalian is discharged into the Bohai Sea. Additionally, its semi-enclosed characteristic restricts water exchange, which leads to high accumulation of pollutants in the environment. This overview presents the residues of 6 classes of Persistent Organic Pollutants (POPs). including PAHs, DDTs. HCHs, PCBs and PCDD/Fs. in the sediments and mollusks of the Bohai Sea through analyzing previous literatures. In the sediments. the highest PAH concentrations were detected in the vicinities of Qinhuangdao, while the northeast corner of the Bohai Bay possessed the highest levels of DDTs and PCBs. The investigations on HCHs and PCDD/Fs distributions on the whole sea scale have not been reported. In mollusks, PAH concentrations were in the same order of magnitude in the whole Bohai Sea, so were DDTs. HCHs and PCBs, while the outlier maximum values of PCDDs and PCDFs occurred in Yingkou. In general, the POPs residues in mollusks collected from Shandong Province were higher than the other areas. The compositions of DDTs, HCHs and PCBs in sediments indicated their recent usage. By comparing POP concentrations in sediments with the recommended criterions, it was shown that some individual PAH compounds occasionally associated with adverse biological effects in the vicinities of the Liaodong Bay and Qinhuangdao, and the Liaohe River Estuary were heavily contaminated with DDTs, but PCBs were all below the thresholds. In order to reveal the transference and transformation of POPs in the environment, further studies concerning with their behavior, fate and bioaccumulation in the different trophic levels should be programmed. Moreover, laws and regulations should be enforced to ban the illegal usage of POPs-containing pesticides to guarantee health of the environment and human. (C) 2008 Elsevier Ltd. All rights reserved.