222 resultados para Eutectoid decompositions
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Química - IQ
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Thermogravimetry (TG), energy dispersive X-ray microanalysis (EDX), scanning electron microscopy (SEM), mapping surface and X-ray diffraction (XRD) were used for the study of solid-state reaction on Pt-15%Rh with electrodeposited mercury. The results suggest when heated the mercury film react with the Pt-15%Rh alloy to form intermetallics having different thermal stabilities indicated by three mass loss steps. The first mass loss step occurs between room temperature and 184 degrees C only the bulk Hg is removed and PtHg4, PtHg2 and RhHg2 were characterized by XRD. The second step, between 184 and 271 degrees C, was attributed to PtHg4 decomposition with formation of PtHg2 stabilized by RhHg2. The third step, between 271 and 340 degrees C, was attributed to decomposition of a solid-solution of PtHg2/RhHg2. The fourth step, between 340 and 600 degrees C, was ascribed to: (1) a thermal decomposition of PtHg2, formed by a PtHg eutectoid reaction (similar to 340 degrees C) on the surface and (2) Hg removal from a solid solution of Pt-15%Rh(Hg). (C) 2013 Elsevier B.V. All rights reserved.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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We construct all self-adjoint Schrodinger and Dirac operators (Hamiltonians) with both the pure Aharonov-Bohm (AB) field and the so-called magnetic-solenoid field (a collinear superposition of the AB field and a constant magnetic field). We perform a spectral analysis for these operators, which includes finding spectra and spectral decompositions, or inversion formulae. In constructing the Hamiltonians and performing their spectral analysis, we follow, respectively, the von Neumann theory of self-adjoint extensions of symmetric operators and the Krein method of guiding functionals.
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This pioneering study characterized the chemical, physical and mineralogical aspects of the Urucum Standard manganese ore typology, and evaluated some of its metallurgical characteristics, such as the main mineral heat decompositions, and the particle disintegration at room temperature and under continuous heating. A one-ton sample of ore was received, homogenized and quartered. Representative samples were collected and characterized with the aid of techniques, such as ICP-AES, XRD, SEM-EDS, BET and OM. Representative samples with particle sizes between 9.5 mm and 15.9 mm were separated to perform tumbling tests at room temperature, and thermogravimetry tests for both air and nitrogen constant flow at different temperatures. After each heating cycle, the mechanical strength of the orewas evaluated by means of screening and tumbling procedures. The Urucum Standard typology was classified as an oxidized anhydrous ore, with a high manganese content (~47%). This typology ismainly composed of cryptomelane and pyrolusite; however there is a significantamount of hematite. The Urucum Standard particles presented low susceptibility to disintegration at room temperature, but as temperature increased, susceptibility increased. No significant differences were observed between the tests done with the air or nitrogen injections.