Mode II delamination toughness of Z-pinned laminates

Mode II delamination toughness of z-pin reinforced composite laminates is investigated using finite element (FE) method. The z-pin pullout process is simulated by the deformation and breakage of non-linear springs. A critical shear stress criterion based on linear elastic fracture mechanics is used to simulate crack growth in an end-notched-flexure (ENF) beam made of z-pinned laminates. The mode II toughness is quantified by the potential energy release rate calculated using the contour integral method. This FE model is verified for an unpinned ENF composite beam. Numerical results obtained indicate that z-pins can significantly increase the mode II delamination toughness of composite laminate. The effects of design variables on the toughness enhancement of z-pinned laminates are also studied, which provides an important technological base and useful data to optimize and improve the z-pinning technique.

Modeling the tensile strains of non-uniform fibers

The maximum strain experienced by the thinnest segment of a non-uniform fiber governs fiber breakage, yet this maximum strain can not be obtained from a normal single fiber test. Only the average strain of the whole fiber specimen can be obtained from a normal single fiber tensile test. This study has examined the relationship between the average strain, the maximum strain and the degree of fiber non-uniformity, expressed in coefficient of variation (CV) of fiber diameters along fiber length. The tensile strain of irregular fibers has been simulated using the finite element method (FEM). Using this method, average and maximum tensile strains of non-uniform fibers were calculated. The results indicate that for irregular fibers such as wool, there is an exponential relationship (i.e.ɛ _ave ɛ _max=ae ^{−b CV} ) between the ratio of average breaking strain and maximum breaking strain (ɛ _ave ɛ _max) and the along-fiber diameter variation (CV). The strain ratio decreases with the increase of the along-fiber diameter variation.

Modelling yarn balloon motion in ring spinning

Air-drag on a ballooning yarn and balloon shape affect the yarn tension and ends-down (yarn breakage), which in turn affects energy consumption and yarn productivity in ring spinning. In this article, a mathematical model of yarn ballooning motion in ring spinning is established. The model can be used to generate balloon shape and predict tension in the ballooning yarn under given spinning conditions. Yarn tension was measured using a computer data acquisition system and the balloon shapes were captured using a digital camera with video capability during the experiments using cotton and wool yarns at various balloon-heights and with varying yarn-length in the balloon. The air-drag coefficients on ballooning cotton and wool yarns in ring spinning were estimated by making a “best fit” between the theoretical and experimental turning points. The theoretical results were verified with experimental data. The effects of air-drag and balloon shape on yarn tension are discussed.

In-situ tensile properties of a ballooning staple yarn

This study investigated the tensile properties of a rotating or ballooning staple yarn. The results indicated that the effect of rotating speed on the tensile properties of a ballooning staple yarn was significant. As the yarn rotating speed increased, the tenacity of the rotating or ballooning yarn decreased, while the yarn breaking elongation increased. The effect of rotating speed on the tenacity of a ballooning staple yarn varied for different yarns. These results demonstrated that the breaking force of a ballooning yarn was much lower than the yarn breaking force obtained from normal tensile tests. These results provide new insight into the problems of yarn breakage in yarn spinning and twisting processes.

Tribology of lubricated nitrocarburised and titanium carbonitride surfaces

In the current work, two different coatings, nitrocarburised (CN) and titanium carbonitride (TiCN) on M2 grade high speed tool steel, were prepared by commercial diffusion and physical vapour deposition (PVD) techniques, respectively. Properties of the coating were characterised using a variety of techniques such as Glow-Discharge Optical Emission Spectrometry (GD-OES) and Scanning Electron Microscopy (SEM). Three non-commercial, oil-based lubricants with simplified formulations were used for this study. A tribological test was developed in which two nominally geometrically-identical crossed cylinders slide over each other under selected test conditions. This test was used to evaluate the effectiveness of a pre-applied lubricant film and a surface coating for various conditions of sliding wear. Engineered surface coatings can significantly improve wear resistance of the tool surface but their sliding wear performances strongly depend on the type of coating and lubricant combination used. These coating-lubricant interactions can also have a very strong effect on the useful life of the lubricant in a tribological system. Better performance of lubricants during the sliding wear testing was achieved hen used with the nitrocarburised (CN) coating. To understand the nature of the interactions and their possible effects on the coating-lubricant system, several surface analysis techniques were used. The molecular level investigation of Fourier Transform Infrared Spectroscopy (FTIR) revealed that oxidative degradation occurred in all used oil-based lubricants during the sliding wear test but the degradation behaviour of oil-based lubricants varied with the coating-lubricant system and the wear conditions. The main differences in the carbonyl oxidation region of the FTIR spectra (1900-1600 cm-1) between different coating-lubricant systems may relate to the effective lifetime of the lubricant during the sliding wear test. Secondary Ion Mass Spectrometry (SIMS) depth profiling shows that the CN coating has the highest lubricant absorbability among the tested tool surfaces. Diffusion of chlorine (C1), hydrogen (H) and oxygen (O) into the surface of subsurface of the tool suggested that strong interactions occurred between lubricant and tool surface during the sliding wear test. The possible effects of the interactions on the performance of whole tribological system are also discussed. The study of Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) indicated that the envelope of hydrocarbons (CmHn) of oil lubricant in the positive TOF-SIMS spectra shifted to lower mass fragment after the sliding wear testing due to the breakage of long-chain hydrocarbons to short-chain ones during the degradation of lubricant. The shift of the mass fragment range of the hydrocarbon (CmHn) envelope caries with the type of both tool surface and lubricant, again confirming that variation in the performance of the tool-lubricant system relates to the changes in surface chemistry due to tribochemical interactions at the tool-lubricant interface under sliding wear conditions. The sliding wear conditions resulted in changes not only in topography of the tool surface due to mechanical interactions, as outlined in Chapter 5, but also in surface chemistry due to tribochemical interactions, as discussed in Chapters 6 and 7.

Tensile behaviour of non-uniform fibres and fibrous composites

This work investigates the tensile behaviour of non-uniform fibres and fibrous composites. Wool fibres are used as an example of non-uniform fibres because they're physical, morphological and geometrical properties vary greatly not only between fibres but also within a fibre. The focus of this work is on the effect of both between-fibre and within-fibre diameter variations on fibre tensile behaviour. In addition, fit to the Weibull distribution by the non-brittle and non-uniform visco-elastic wool fibres is examined, and the Weibull model is developed further for non-uniform fibres with diameter variation along the fibre length. A novel model fibre composite is introduced to facilitate the investigation into the tensile behaviour of fibre-reinforced composites. This work first confirms that for processed wool, its coefficient of variation in break force can be predicted from that of minimum fibre diameters, and the prediction is better for longer fibres. This implies that even for processed wool, fibre breakage is closely associated with the occurrence of thin sections along a fibre, and damage to fibres during processing is not the main cause of fibre breakage. The effect of along-fibre diameter variation on fibre tensile behaviour of scoured wool and mohair is examined next. Only wet wool samples were examined in the past. The extensions of individual segments of single non-uniform fibres are measured at different strain levels. An important finding is the maximum extension (%) (Normally at the thinnest section) equals the average fibre extension (%) plus the diameter variation (CV %) among the fibre segments. This relationship has not been reported before. During a tensile test, it is only the average fibre extension that is measured. The third part of this work is on the applicability of Weibull distribution to the strength of non-uniform visco-elastic wool fibres. Little work has been done for wool fibres in this area, even though the Weibull model has been widely applied to many brittle fibres. An improved Weibull model incorporating within-fibre diameter variations has been developed for non-uniform fibres. This model predicts the gauge length effect more accurately than the conventional Weibull model. In studies of fibre-reinforced composites, ideal composite specimens are usually prepared and used in the experiments. Sample preparation has been a tedious process. A novel fibre reinforced composite is developed and used in this work to investigate the tensile behaviour of fibre-reinforced composites. The results obtained from the novel composite specimen are consistent with that obtained from the normal specimens.

An evaluation of the performance of advanced melded composite joints

Melding is an efficient three step composite joining process that involves the selective cure of composite adherends before the final adhesive joint is created using the adherends own resin system. Melding does not require many of the processes and compromises associated with conventional techniques like adhesive bonding and mechanical fastening.

The Taguchi design of experiments technique was used to optimise three melded joint factors for a unidirectional epoxy prepreg material. The performance of the joint was evaluated using tensile and flexural strength as well as flexural modulus. It was found that not having a step for every ply in the joint was the most influential factor affecting joint performance. This was due to the differing failure modes induced by this factors various levels, which varied the amount of fibre breakage at failure.

Dislodgment and attachment strength of the intertidal macroalga Hormosira banksii (Fucales, Phaeophyceae)

Hormosira banksii is a dominant intertidal alga characterised by limited dispersal of propagules, yet it has a broad distribution throughout temperate Australasia. However, the high abundance of beach wrack of H. banksii on sandy beaches along southwest Victoria, the frequency of frond dislodgment and the force required to break it from the substratum remain unknown. Dislodgment of macroalgae has been shown to influence dispersal processes; therefore, we tested the model that long-distance dispersal of H. banksii is facilitated by weak attachment to the substratum and frequent dislodgment of fertile fronds. We monitored the dislodgment of H. banksii individuals and conducted in situ pull tests to determine the attachment strength of fronds of H. banksii. We further tested whether thallus size or pull direction influenced attachment strength of H. banksii. We found that breakage of vesicles and fronds was a regular event during the survey period and that the mean attachment strength of fronds of H. banksii was weak compared to other intertidal algae. Furthermore, we found that thallus size did not influence the force required to break fronds of H.banksii from the substratum but that the direction that fronds were pulled from the substratum did. We suggest that fronds of H. banksii do drift frequently and that long-distance dispersal is likely to be an important mechanism for the distributional success of this species.

Application of submerged membrane bioreactor for aquaculture effluent reuse

Discharging the nutrient rich aquaculture effluents into inland water bodies and oceans is becoming a serious concern due to the adverse effect that brings in the form of eutrophication and subsequent damages to those waters. A laboratory scale biological reactor consisting of a denitrifying compartment followed by a submerged membrane bioreactor (SMBR) compartment was used to treat 40 L d−1 of aquaculture effluent with an average concentration of 74 mg L−1 nitrate (NO3 − ). Sugar was added to the aquaculture effluent in order that to enter into the denitrifying compartment at a carbon: nitrogen ratio (C:N) of 2:1 and 4:1. A hollow fibre membrane with a pore size of 0.4 μm and a filtration area of 0.20 m2 was used in the SMBR and was operated at an average flux of 0.20 m3 m−2 d−1. An intermittent suction period of 12 min followed by a relaxation period of 3 min was maintained in the SMBR throughout the experiment. Different aeration rates of 1, 3, 5 and 10 Lpm were applied to the SMBR to determine the rate of membrane fouling and 5 Lpm aeration rate was found to be optimum with respect to the rate of fouling of membrane at a C:N ratio of 4:1. The average rate of fouling at 1, 3, 5 and 10 Lpm were 1.17, 0.70, 0.48 and 0.52 kPa d−1, respectively. The increase in the rate of fouling when the aeration was increased from 5 to 10 Lpm may be due to the breakage of suspended particles into finer particles which could have increased the fouling of membrane. It was also found that increasing the C:N ratio from 2:1 to 4:1 resulted in more cake being formed on the membrane surface as well as an increase in the reduction of NO3 − from 64% to 78%. Preliminary calculations show that 2.4 to 3.2 g of suspended solids could be accumulated per square meter of membrane surface before physical cleaning of membrane is required (at a transmembrane pressure of 20 kPa).

Life expectancy of rigid gas permeable and high water content contact lenses

Purpose: The purpose of this study was to evaluate the life expectancy of various rigid gas permeable (RGP) lens materials used on a daily wear basis and to compare these results with the life expectancy of a matched group of soft lens wearers.

Methods: We retrospectively analyzed the records of 600 contact lens wearing patients (300 soft contact lens users and 300 RGP lens users) fit between September 1987 and September 1994. None of the subjects wore lenses on a planned replacement system. For the purposes of the study, RGP lenses were divided into three groups: <40 Dk were considered low-Dk; 41-89 Dk were considered mid-Dk; and >90 Dk were considered high-Dk. All soft lenses were high water content lenses (>60% water content). Lenses were included if they were replaced due to loss, breakage, deposition, or poor wettability but not if replaced because of changes in fit or prescription.

Results; The mean (+SD) life-spans of each lens type in months were 19.9 +/- 17 for low-Dk RGP lenses, 15.9 +/-13.3 for mid-Dk RGP lenses, 9.0+8.2 for high-Dk RGP lenses, and 6.4 +/-5.2 for high water content soft lenses. Statistical analysis using a one-way ANOVA on ranks indicated that these results were statistically significant (P< 0.0001).

Conclusions: Patients should be informed that high-Dk lenses (RGP and soft) provide substantial clinical benefits and that they should expect to replace high-Dk RGP lenses after approximately 6 months. This lends further credence to the use of high-Dk lenses on a planned replacement basis.

Efeito de um extrato de chrysobalanus icaco na marcação de constituíntes sanguíneos com tecnécio-99m, na morfologia de hemácias, na topologia plasmidial e na ação do cloreto estanoso no dna plasmidial

The use of radionuclides has contributed for advances in Health Sciences, to research or to the diagnosis and/or treatment of diseases. These advances have been possible with the utilization of radiopharmaceuticals labeled with technetium-99m (99mTc). Stannous chloride (SnCl2) has the main reducing agent utilized to obtain radiopharmaceuticals labeled with technetium-99m. It has been reported that several natural or synthetic drugs are capable to alter the labeling of blood constituents with 99mTc, as well as the red blood cells morphology. The aim of this study was to evaluate possible alterations of Chrysobalanus icaco extract on the labeling of blood constituents with 99mTc, on the morphology of RBC of blood of Wistar rats, on the breakage of plasmid DNA and on the effects of stannous chloride on plasmid DNA. The results showed significant (P<0.05) alteration of the labeling of blood constituents with 99mTc, as well as, modification of the morphology and morphometry (perimeter/area ratio) of the RBC in presence of the extract. These data suggest that this abajeru extract could alter the labeling of blood constituents with 99mTc by its chelating/antioxidant action and/or effects on membrane structures. Moreover C. icaco extract altered the electrophoretic profile and decreased significantly (p<0.05) the effect of SnCl2 on plasmid DNA. The results obtained in this work could indicate a dose-dependent protective action against the SnCl2 and a genotoxic effect of C. icaco extract on plasmid DNA

Mutagênese induzida por flavonóides presentes do decocto das cascas da aroeira (Schinus terebinthifolius, Raddi)

The decoction of Brazilian pepper tree barks (Schinus terebinthifolius, Raddi), is used in medicine as wound healing and antiinflamatory. Once extracts from this plant are used for acceleration of scar s process, it is important to study their mutagenic and genotoxic potential. In previous works in our laboratory, it was observed mutagenicity caused by the decoction when in high concentrations. Among the chemical compounds of this plant that could be able to induce mutation, the flavonoids were the only group that was referred to have either an oxidant or antioxidant potential. The flavonoids were isolated, purified and quantified by adsorptive column chromatography under silica gel, bacterial and in vitro genotoxic tests were realized to determine if the flavonoids were the responsible agents for this mutagenicity found. The tests realized with plasmidial DNA were indicative that the flavonoids are probably genotoxic, due to the presence of correlation between increase of the flavonoid concentration and in plasmidial DNA double strand breakage visualized in agarose gel, as well as they were capable to generated abasic sites shown by the in vitro treatment with exonuclease III. The same tests with plasmidial DNA in the presence of copper [10 µM] and of a Tris-HCl pH 7.5 [10 µM] buffer were realized with the isolated flavonoids to determine if there would be or not participation of reactive oxygen species (ROS). The transformation of plasmidial DNA in different bacterial strains proficient and deficient in DNA repair enzymes in the presence or not of a Tris-HCl buffer, suggests that the enzymes that repair oxidative lesions are necessary to repair the lesions generated by the flavonoids and that ROS are generated and are necessary to promote the lesions. Bacterial tests with Escherichia coli strains of the CC collection (deficient or not for DNA repair enzymes), showed that the flavonoids are able to increase the frequency of mutations, mainly in strains mutated in repair enzymes (MutM, MutY-glicosylases and double mutant), suggesting that these agents are responsible for the enhancement in the mutation rate. In order to determine the mutation spectrum caused by the flavonoids of the Brazilian pepper tree stem bark, plasmidial DNA previously treated with the flavonoids were transformed in bacterial strains deficient and proficient in the DNA repair enzymes, followed by a blue-white selection with X-gal, DNA amplification by PCR and sequencing the positive mutant clones. Analysis of the mutants obtained from strains CC104, CC104mutM, CC104mutY, CC104mutMmutY, BW9101, BW9109 indicated a predominance of some mutations like G:C to C:G that can be correlated with the origin of 8-oxoG, due to oxidative lesions caused by the flavonoids. So it can concluded that the flavonoid isolated or in fractions enriched on them are genotoxic and mutagenic, and their mutations are predominantly oxidative, mediated by ROS, and the lesions are recognized by the BER system. In this way it is proposed that the flavonoids can act in two different ways to generate the DNA lesion: 1. in a Fenton-like reaction, when the flavonoid are in the presence of metal ions and that together with the water generate ROS that promotes the DNA lesions; 2. in another way the lesions can be generated by the formation of ROS due to the internal chemical structure of the flavonoid molecule due to the quantity and location of hydroxyl groups, and so producing the DNA lesions, those lesions can be directly (suggested by the in vitro experiments) or indirectly done (supported by the experiments using the CC bacterial strains)

Estimativas de mortalidade para a região nordeste do Brasil em 2010: uma associação do método demográfico equação geral de balanceamento, com o estimador bayesiano empírico

One of the greatest challenges of demography, nowadays, is to obtain estimates of mortality, in a consistent manner, mainly in small areas. The lack of this information, hinders public health actions and leads to impairment of quality of classification of deaths, generating concern on the part of demographers and epidemiologists in obtaining reliable statistics of mortality in the country. In this context, the objective of this work is to obtain estimates of deaths adjustment factors for correction of adult mortality, by States, meso-regions and age groups in the northeastern region, in 2010. The proposal is based on two lines of observation: a demographic one and a statistical one, considering also two areas of coverage in the States of the Northeast region, the meso-regions, as larger areas and counties, as small areas. The methodological principle is to use the General Equation and Balancing demographic method or General Growth Balance to correct the observed deaths, in larger areas (meso-regions) of the states, since they are less prone to breakage of methodological assumptions. In the sequence, it will be applied the statistical empirical Bayesian estimator method, considering as sum of deaths in the meso-regions, the death value corrected by the demographic method, and as reference of observation of smaller area, the observed deaths in small areas (counties). As results of this combination, a smoothing effect on the degree of coverage of deaths is obtained, due to the association with the empirical Bayesian Estimator, and the possibility of evaluating the degree of coverage of deaths by age groups at counties, meso-regions and states levels, with the advantage of estimete adjustment factors, according to the desired level of aggregation. The results grouped by State, point to a significant improvement of the degree of coverage of deaths, according to the combination of the methods with values above 80%. Alagoas (0.88), Bahia (0.90), Ceará (0.90), Maranhão (0.84), Paraíba (0.88), Pernambuco (0.93), Piauí (0.85), Rio Grande do Norte (0.89) and Sergipe (0.92). Advances in the control of the registry information in the health system, linked to improvements in socioeconomic conditions and urbanization of the counties, in the last decade, provided a better quality of information registry of deaths in small areas

Bermuda grass sod production as related to nitrogen rates

O N é o nutriente que proporciona as maiores respostas no crescimento das gramas, e a adubação nitrogenada adequada pode proporcionar a formação do tapete com boa qualidade em menor tempo. Neste trabalho, objetivou-se avaliar a influência da adubação nitrogenada na produção e qualidade de tapetes de grama-bermuda. O experimento foi instalado e conduzido em área de produção comercial de grama, localizada na cidade de Capela do Alto, SP. A grama utilizada foi a Cynodon dactylon (Pers) L., conhecida como grama-bermuda. O delineamento experimental utilizado foi o de blocos casualizados, com cinco tratamentos e quatro repetições. Os tratamentos foram constituídos por cinco doses de N: 0, 150, 300, 450 e 600 kg ha-1. O aumento das doses de N aumentou a taxa de cobertura do solo pela gramabermuda, reduzindo o tempo para formação do tapete. O máximo acúmulo de matéria seca de rizomas + estolões + raízes foi proporcionado pela dose de 354 kg ha-1 de N, e a resistência dos tapetes, pela dose de 365 kg ha-1 de N. Doses de N entre 354 e 365 kg ha-1, aumentaram a resistência dos tapetes e, com isso, a capacidade deles serem manuseados após a colheita, podendo promover assim maior rendimento da área.

Evaluation of stitched fabric composite processed by RTM in quasi-static test

Stitched fabrics have been widely studied for potential application in aircraft structures since stitch yarns offer improvements in the out-of-plane mechanical properties and also can save time in the lay up process. The down side of stitch yarns came up in the manufacturing process of fabric in which defects introduced by the needle movement creating fiber-free-zones, fiber breakage and misalignment of fibers. The dry stitched carbon fabric preform has mainly been used in the Resin Transfer Molding (RTM) process which high fiber content is aimed, those defects influence negatively the injection behavior reducing the mechanical properties of final material. The purpose of this research work focused on testing in quasi-static mechanical mode (in-plane tension) of a monocomponent resin CYCOM (R) 890 RTM/carbon fiber anti-symmetric quadriaxial fabric stitched by PE 80Dtex yarn processed by RTM. The evaluation consisted in comparing the scatter of the quasi-static test with the attenuation of ultrasonic maps, which show the path of the resin and possible dry spots considering that interference of yarn in resin flow is detectable in ultrasonic measurement. Microscopic analysis was also considered for further evaluation in case of premature failure. (C) 2011 Published by Elsevier Ltd. Selection and peer-review under responsibility of ICM11