形变双奇核~(180)Ir的高自旋态实验研究

利用15 4 Sm( 31P ,5nγ) 180 Ir反应产生并研究了双奇核180 Ir的高自旋态 .实验中进行了180 Ir核的在束γ测量 ,包括γ射线的激发函数测量、X γ和γ γ符合测量 ,首次建立了双奇核180 Ir由 5个转动带构成的能级纲图 .依据从实验数据中提取出的带内B(M1 ) /B(E2 )值与理论计算值的比较 ,以及相邻双奇核的带结构特征 ,给出了转动带的准粒子组态 .在推转壳模型的理论框架中 ,定性地讨论了转动带结构特征的组态依赖性

基于GIS的神经网络法在宗地地价评估中的应用

为了对城市宗地地价进行评估,采用RS和GIS技术对宗地估价底图图层等资料进行更新和管理,建立GIS宗地估价信息系统并从中提取相似交易宗地,提出利用人工神经网络、结合特尔菲法建立宗地地价评估指标体系,以宗地地价为评估目标的宗地评估方法。本文在模型建立过程中,以南昌市22个商业用地资料中的18个为学习样本,以5个评估指标为输入,以宗地地价为输出,建立了三层BP人工神经网络,并以其余4个商业用地资料作为验证,取得了较好的模拟效果。有效地解决了一次大批量地价评估的难题,为宗地地价评估提出新的方向。

黄土坡面坡长对侵蚀一搬运过程的影响研究

通过不同降雨强度的模拟降雨试验,研究了15°时坡面坡长对黄土坡面侵蚀—搬运过程的影响。结果表明,坡面径流量随坡长的增加而增加,在50和75 mm/h降雨强度下,坡面径流量随坡长增加的幅度基本相同。在100 mm/h降雨强度下,当坡长小于5 m时,坡面径流量随坡长的增加幅度较小,而当坡长大于5 m时,坡面径流量随坡长增加的速率明显增大。在8 m坡长内,坡面侵蚀量随坡长变化呈波状起伏的交替变化;随坡长增加,坡面侵蚀现象呈现以侵蚀—搬运过程为主与以侵蚀—沉积过程为主的交替现象。

利用GIS和RS确定长白山自然保护区森林景观分布的环境范围

在对遥感数据进行景观分类和对环境因子进行空间表达基础上 ,在地理信息系统的支持下 ,确定长白山自然保护区森林景观分布的环境 (包括年均温、年降水量、坡度和坡向 )范围 .结果表明 ,从苔原、岳桦、云冷杉到阔叶红松林 ,最适海拔高度范围依次为 1780～ 2 2 12、170 5～ 195 6、10 4 2～ 16 2 5、82 3～ 1184m ;最适温度范围分别为 - 4 .75～ - 2 .4 0℃、- 3.4 2～ - 2 .0 7℃、- 1.4 9～ 1.39℃、0 .71～ 2 .37℃ ;最适降水范围分别为 10 34～ 1110、10 14～ 10 6 0、883～ 10 17、82 4～ 92 5mm ;长白山自然保护区的森林景观主要分布在平、缓坡地上 ,并与坡向关系密切 ,苔原在各个坡向上均有分布 ,且在各个坡向上分布面积的变化不大 ;岳桦、云冷杉林、阔叶红松林、山杨白桦林主要呈现北、西北向分布 ,其次为东北、西向分布 ;落叶松林主要为东北向分布 ,其次为东和北向分布 ;疏林主要为西向分布 ,其次为西南、西北和南向分布 ;风倒区主要为西、西南、西北向分布 .

烯烃共聚酯的合成与表征

通过环辛烯、环辛二烯和降冰片烯与ω-十一烯酸乙二醇二酯的易位共聚合及氢化反应合成了烯烃共聚酯 .改变聚合条件 ,可控制烯烃共聚酯的分子量、极性单体插入率和熔融温度等性质 .两段聚合过程适于制备高分子量的烯烃共聚酯 ,聚合物收率达 90 %,极性单体的插入率大于 1 0 %,熔融温度高达 120℃.

Preparation and simulation of an additional catalyst layer for direct methanol fuel cell

An additional anode catalyst layer with PtRu/C was hot pressed between two Nafion (R) 112 membranes and a conventional direct methanol fuel cell (DMFC) cathode/membrane/anode assembly with the above membranes as separator was fabricated. The additional catalyst layer formed an assistant cell with the cathode to prevent methanol crossover. A simple one-dimensional mathematical model was presented to describe the performance of this new type of membrane electrode assembly system. As seen from both experimental result and model analysis, the additional catalyst layer can not only effectively prevent the methanol crossover, but also generate electrical power with the crossover methanol. The percentage of output power of the assistant cell to the total power analyzed by the model is about 40% under usual condition, which is much higher than that from experimental result, indicating the potential of the development in the DMFC designing. It was also discovered that the electrical power generated from the assistant cell with crossover methanol could take higher percentage in total electrical power when the main DMFC current density became lower.

Buildup of gold nanoparticle multilayer thin films based on the covalent-bonding interaction between boronic acids and polyols

A novel method for the fabrication of gold nanoparticle multilayer films based on the covalent-bonding interaction between boronic acid and polyols, poly(vinyl alcohol) (PVA), was developed. The multilayer buildup was monitored by UV-vis absorbance, spectroscopy, which showed a linear increase of the film absorbance with the number of adsorbed Au layers and indicated the stepwise and uniform assembling process. The atomic force microscopy (AFM) image showed that a compact gold multilayer thin film was successfully assembled. The residual boronic acid group on the surface of thin film Could incorporate glycosylated-protein horseradish peroxidase (HRP), and good catalytic activity for H2O2 could be observed.

Synthesis of barium fluoride nanoparticles from microemulsion

The cetyltrimethylammonium bromide (CTAB)/2-octanol/water microemulsion system was used to synthesize barium fluoride nanoparticles. X-ray powder diffraction (XRD) analysis showed that the products were single phase. The results of scanning electron microscopy and calculations using the Scherrer equation from the line widths of the XRD have been used to estimate the average particle sizes of the powder products. The results showed that the nanoparticle size was affected by water content and surfactant (CTAB) concentration. As water content decreases from 14.2 to 9.47% (w/w), the particle size decreases from 75 to 40 rim. In addition, increasing the reaction times from 5 to 120 min increases the particle size from 75 to 150 rim, and increasing the amount of surfactant decreases the size of the particle. Luminescence spectra of the BaF2:Ce nanoparticles are also discussed.

Synthesis and crystal structure of [Nd(eta(6)-1,3,5-C6H3Me3)(AlCl4)(3)]( C6H6) and structural comparison of Ln(eta(6)-arene)(AlCl4)(3)

Reaction of NdCl3, with AlCl3 and mesitylene in benzene gives complex [Nd(eta (6)-1,3,5-C6H3Me3) (AlCl4)(3)] (C6H6) (1) which was characterized by elemental analysis, IR spectra, MS and X-lay diffractions. The X-ray determination indicates that 1 has a distorted pentagonal bipyramidal geometry and crystallizes in the monoclinic, space group P2(1)/n with a = 0.9586(2), b = 1.1717(5), c = 2.8966(7) nm, beta = 90.85 (2)degrees, V = 3.2529(6) nm(3), D-c = 1.573 g/cm(3), Z = 4. A comparison of bond parameters for all the reported Ln(eta (6)-Ar) (AlCl4)(3) complexes indicates that the bond distance of Ln-C is shortened with the increasing of methyl group on benzene and with the decreasing of radius of lanthanide ions.

Syntheses and crystalline structures of clusters Co-3(CO)(7)(mu(3)-S)(mu, eta(2)-SCNR2)

Through the reaction of Co-2(CO)(8) with four thiuram [R2NC(S)S](2), four new sulfur-capped trinuclear cobalt carbonyl clusters Co-3 (CO)(7) (mu(3)-S) (mu, eta(2)-S* C* NR2) ( I : R = Me; I : R = Et; II : R = i-Pr; IV : NR= -N [GRAPHICS] were prepared and characterized by elementary analysis, IR,H-1 NMR and MS spectroscopy. The crystal structure of the cluster Co-3(CO)(7)(mu(3)-S)[mu, eta(2)-S*C*N (i-Pr)(2)]( III) was determined by X-ray single crystal diffraction method. The crystal of m is monoclinic, belonging to space group P2(1)/n, and the cell parameters are as follows: a = 1, 145 2(2) nm, b = 1. 502 8(3) nm, c = 1, 214 4(2) nmj alpha = 90 degrees, beta = 92, 15(3)degrees, gamma = 90 degrees; V = 2. 088 5(7) nm(3) , Z = 4, F (000) = 1 096, D-c = 1. 747 mg . m(-3), mu = 2. 588 mm(-1), R=0. 040 7, R-w=0. 062 4, The structural analysis shows that cluster II has a pyrimidal Co3S framework and contains a heterocylic bridging bidentate ligand [mu, eta(2)-S* C* N (i-Pr)(2)] linked to the Co2 and Co3 atoms of the cluster by a cobalt-carbon and a cobalt-sulfur bond respectively.

聚合物链结构及链间距对荧光强度的影响

合成并表征了 3种PPV类共聚物 .用荧光光谱和时间分辨荧光光谱研究了它们的膜和溶液的荧光特征 ,并对荧光特征性做了初步的解释和探讨 .研究结果表明 ,在所研究的范围内 ,随着共聚物中非发光链段的增长与共聚物溶液浓度的稀释 ,荧光强度增大 ,荧光衰变寿命延长 ,表明了发光效率增大的趋势

导电炭黑在NBR中的应用研究

对导电炭黑（ＣＳＦ）作为ＮＢＲ的填料时，其填充量、硫化时间和增塑剂用量等因素对ＮＢＲ／ＣＳＦ混炼胶加工性能和硫化特性及硫化胶物理性能和电性能的影响进行了研究，并与乙炔炭黑（ＡＣＥＴ）进行了对比。结果表明，随着ＣＳＦ用量的增大，混炼胶的炭黑结合ＮＢＲ量、门尼粘度［ＭＬ（１＋４）１００℃］、屈服强度和拉伸强度均增大，扯断伸长率和挤出膨胀率降低，挤出物外观变优，焦烧时间和正硫化时间延长，硫化速度放慢，硫化胶的物理性能有所降低，导电性能提高；硫化胶体积电阻率随硫化时间延长和施加负荷的增大而降低，随温度升高和增塑剂