Accumulation rate, carbon geochemistry and clay mineralogy of ODP Site 181-1123 sediments, southwest Pacific

Site 1123 is located on the northeastern flank of the Chatham Rise. Sedimentological and clay mineralogical analyses indicate a very fine grained carbonate-rich sediment. Smectite and illite are the main constituents of the clay mineral assemblage. High smectite values in the Eocene decrease in younger sediment sequences. Illite and chlorite concentrations increase in younger sediments with significant steps at 13.5, 9, and 6.4 Ma. The kaolinite content is near the detection limit and not significant. We observed only small fluctuations of the clay mineral composition, which indicates a uniform sedimentation process, probably driven by long-term processes. Good correspondence is shown between increasing illite and chlorite values and the tectonic uplift history of the Southern Alps.

Sulphur geochemistry of interstitial waters and squeeze cake samples of ODP Leg 181 sites

Seventy-nine interstitial water samples from six sites (Ocean Drilling Program Sites 1119-1124) from the southwestern Pacific Ocean have been analyzed for stable isotopes of dissolved sulfate (34S), along with major and minor ions. Sulfate from the interstitial fluids (34S values between +20.7 and +57.5 vs. the Vienna-Canyon Diablo troilite standard) was enriched in 34S with respect to modern seawater (34S +20.6), indicating that differing amounts of microbial sulfate reduction took place at all investigated sites. Microbial sulfate reduction was found at all sites, the intensity depending on the availability of organic matter, which is controlled by paleosedimentation conditions (e.g., sedimentation rate and presence of turbidites). In addition, total reduced inorganic sulfur (essentially pyrite) as a product of microbial sulfate reduction was quantified in selected sediments from Site 1119.

Calcareous nannofossil abundance and datum events of ODP Holes 181-1123C and 181-1124C, southwest Pacific

Seven sites were drilled off the eastern shore of New Zealand during Ocean Drilling Program Leg 181 to gain knowledge of southwest Pacific ocean history, in particular, the evolution of the Pacific Deep Western Boundary Current (DWBC). Holes 1123C and 1124C penetrated lower Oligocene to middle Eocene sediments containing moderately to poorly preserved calcareous nannofossils. Nannofossil assemblages show signs of dissolution and overgrowth, but key marker species can be identified. Nannofossil abundance ranges from abundant to barren. The lower Oligocene sediments are distinctly separated from the overlying Neogene sequences by the Marshall Paraconformity, a regional marker of environmental and sea level change. An age-depth model for Hole 1123C through this sequence was constructed using nine nannofossil age datums and three magnetostratigraphic datums. There is good agreement between the biostratigraphy and magnetostratigraphy, which indicates that the Marshall Paraconformity spans ~12 m.y. in Hole 1123C. The same sequence in Hole 1124C is disrupted by at least three hiatuses, complicating interpretation of the sedimentation history. The Marshall Paraconformity spans at least 3 m.y. in Hole 1124C. A 4- m.y. gap separates lower Oligocene and middle Eocene sediments, and a ~15 m.y. hiatus separates middle Eocene mudstones from middle Paleocene nannofossil-bearing mudstones. Nannofossil biostratigraphy from Holes 1123C and 1124C indicates that the Eocene-Oligocene transition was a time of fluctuating biota and intensification of the DWBC along the New Zealand margin.