EBSD analysis of deformation modes in Mg-3A1-1Zn

Wrought magnesium alloys exhibit poor cold formability and the accepted explanation is the shortage of independent slip systems. In order to improve the formability in these alloys, an understanding of the deformation modes is required. In the present work, activation of different slip and twinning systems are investigated in rolled Mg–3Al–1Zn using electron back scattering diffraction. Analysis was performed on deformed surfaces and on metallographically prepared cross-sections following deformation at room temperature. The results reinforce the importance of prismatic slip and c-axis compression double twinning.

Observation of {1121}twinning in a Mg-based alloy

The magnesium alloy Mg–5%Y–2%Nd–2%RE–0.5Zr, known as WE54, was heat treated to produce different particle dispersions. Specimens were then compressed to a strain of 8%, and this resulted in prolific mechanical twinning.EBSD analysis revealed that {1121} twins were operative in this alloy, a twinning mode not reported before in magnesium alloys. Activation of this twinning mode is ascribed to the presence of alloying elements in solution. Removal of alloying elements from solution by precipitation treatments completely inhibited this twin mode.

Thermo-mechanical processing and the shape memory effect in an Fe–Mn–Si-based shape memory alloy

The effect of cold rolling and annealing on the shape memory effect (SME) in an Fe–Mn–Si-based alloy has been studied. It has been found
that the SME in these alloys can be significantly increased by the appropriate thermo-mechanical processing (TMP). The optimum conditions
were found to be 15% cold rolling followed by annealing at 800 ◦C for 15 min. This produced a total strain recovery of 4.5%. TEM showed that
this processing schedule produces a microstructure of evenly spaced, and well defined stacking faults throughout the parent phase. It is shown for
the first time that samples processed in this way produce a larger fraction of martensite compared to samples in the as-austenitized condition. It
is concluded that the stacking faults induced by TMP act as nucleation sites for martensite formation during deformation. The SME is improved
primarily as a result of the increased amount of martensite that is formed in this condition.

Atomic scale simulation of deformation in magnesium single crystals

The deformation behaviour of magnesium single crystals under plane strain conditions has been examined using molecular dynamics modelling. The simulations were based on an existing atomic potential for magnesium taken from the literature. A strain of 10% was applied at rates of 3x10⁹s^-1 and 3x10⁷s^-1. The simulations predicted the formation of mechanical twins that accommodated extension in the c-axis direction of the hexagonal unit cell. However, the predicted twin is not of the same kind found in magnesium, but is that commonly observed in titanium. It is believed that further analysis of the physical properties predicted by this interatomic potential will shed more light on the atomic processes controlling twinning in Magnesium alloys. It also highlights the need for improvements to the interatomic potential such that more accurate deformation behaviour can be attained.

Solute segregation and texture modification in an extruded magnesium alloy containing gadolinium

The alloy Mg-1.5Gd has been extruded at different temperatures to produce two significantly different textures. At lower extrusion temperatures there was significant solute clustering in the matrix, coupled with segregation of solute to the grain boundaries. At higher temperatures these two phenomena were both less pronounced. It is suggested here that segregation of solute to the grain boundaries plays a significant role in the texture modification effect that rare earth elements have in magnesium alloys.

Prediction interval-based neural network modelling of polystyrene polymerization reactor - a new perspective of data-based modelling

In this paper, prediction interval (PI)-based modelling techniques are introduced and applied to capture the nonlinear dynamics of a polystyrene batch reactor system. Traditional NN models are developed using experimental datasets with and without disturbances. Simulation results indicate that traditional NNs cannot properly handle disturbances in reactor data and demonstrate a poor forecasting performance, with an average MAPE of 22% in the presence of disturbances. The lower upper bound estimation (LUBE) method is applied for the construction of PIs to quantify uncertainties associated with forecasts. The simulated annealing optimization technique is employed to adjust NN parameters for minimization of an innovative PI-based cost function. The simulation results reveal that the LUBE method generates quality PIs without requiring prohibitive computations. As both calibration and sharpness of PIs are practically and theoretically satisfactory, the constructed PIs can be used as part of the decision-making and control process of polymerization reactors. © 2014 The Institution of Chemical Engineers.

Prediction interval-based modelling of polymerization reactor: a new modelling strategy for chemical reactors

Precise and reliable modelling of polymerization reactor is challenging due to its complex reaction mechanism and non-linear nature. Researchers often make several assumptions when deriving theories and developing models for polymerization reactor. Therefore, traditional available models suffer from high prediction error. In contrast, data-driven modelling techniques provide a powerful framework to describe the dynamic behaviour of polymerization reactor. However, the traditional NN prediction performance is significantly dropped in the presence of polymerization process disturbances. Besides, uncertainty effects caused by disturbances present in reactor operation can be properly quantified through construction of prediction intervals (PIs) for model outputs. In this study, we propose and apply a PI-based neural network (PI-NN) model for the free radical polymerization system. This strategy avoids assumptions made in traditional modelling techniques for polymerization reactor system. Lower upper bound estimation (LUBE) method is used to develop PI-NN model for uncertainty quantification. To further improve the quality of model, a new method is proposed for aggregation of upper and lower bounds of PIs obtained from individual PI-NN models. Simulation results reveal that combined PI-NN performance is superior to those individual PI-NN models in terms of PI quality. Besides, constructed PIs are able to properly quantify effects of uncertainties in reactor operation, where these can be later used as part of the control process. © 2014 Taiwan Institute of Chemical Engineers.

Time and spatial resolution of slip and twinning in a grain embedded within a magnesium polycrystal

Plastic yielding in magnesium alloys frequently involves the initiation of both slip and twinning events. A proper understanding of the phenomenon at the grain level requires knowledge of how these two mechanisms progress and interact over both time and space and what the local resolved stresses are. To date, simultaneous collection of such information has not been achievable. To address this shortfall, we have developed a modified Laue based in situ micro X-ray diffraction technique with an unprecedented combination of time and spatial resolution. A ten-fold reduction in data collection times is realized by the refinement of rapid polychromatic Laue "single-shot" mapping. From single Laue patterns, we extract grain depth information, detect onset of yielding and achieve 2 × 10-4 lattice strain resolution. The technique is employed to examine yielding and twinning in a magnesium grain embedded ∼200 μm below the sample surface. We examine 13 time steps and reveal the following behaviour: initial onset of basal slip, subsequent onset of twinning, development of further accommodation slip and evolution of twin shape and size; along with the corresponding values of local resolved shear stresses. © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Atomic scale analysis of light alloys using atom probe tomography

The present paper reviews recent progress in atomic-scale characterisation of composition and nanostructure of light alloy materials using the technique of atom probe tomography. In particular, the present review will highlight atom-by-atom analysis of solid solution architecture, including solute clustering and short-range order, with reference to current limitations of spatial resolution and detector efficiency of atom probe tomography and methods to address these limitations. This leads to discussion of prediction of mechanical properties by simulation and modelling of the strengthening effect exerted by solute clusters and the role of experimental atom probe data to assist in this process. The unique contribution of atom probe tomography to the study of corrosion and hydrogen embrittlement of light alloys will also be discussed as well as a brief insight into its potential application for the investigation of solute strengthening of twinning in Mg alloys.

The competition between metastable and equilibrium S (Al2CuMg) phase during the decomposition of AlCuMg alloys

Abstract The decomposition sequence of the supersaturated solid solution leading to the formation of the equilibrium S (Al2CuMg) phase in AlCuMg alloys has long been the subject of ambiguity and debate. Recent high-resolution synchrotron powder diffraction experiments have shown that the decomposition sequence does involve a metastable variant of the S phase (denoted S1), which has lattice parameters that are distinctly different to those of the equilibrium S phase (denoted S2). In this paper, the difference between these two phases is resolved using high-resolution synchrotron and neutron powder diffraction and atom probe tomography, and the transformation from S1 to S2 is characterised in detail by in situ synchrotron powder diffraction. The results of these experiments confirm that there are no significant differences between the crystal structures of S1 and S2, however, the powder diffraction and atom probe measurements both indicate that the S1 phase forms with a slight deficiency in Cu. The in situ isothermal aging experiments show that S1 forms rapidly, reaching its maximum concentration in only a few minutes at high temperatures, while complete conversion to the S2 phase can take thousands of hours at low temperature. The kinetics of S phase precipitation have been quantitatively analysed for the first time and it is shown that S1 phase forms with an average activation energy of 75 kJ/mol, which is much lower than the activation energy for Cu and Mg diffusion in an Al matrix (136 kJ/mol and 131 kJ/mol, respectively). The mechanism of the replacement of S1 with the equilibrium S2 phase is discussed.

Investigation of precipitate hardening of slip and twinning in Mg5%Zn by micropillar compression

A Mg-5%Zn alloy has been aged to form c-axis rod precipitates which are known to increase strength. Micropillar compression tests were carried out in the precipitate-free and aged samples to investigate the effects of these precipitates on twinning and slip in magnesium alloys. Basal slip, pyramidal slip and {101¯2} twinning were selectively activated by compressing micropillars in the [112¯3], [0 0 0 1] and [112¯0] orientations, respectively. It has been found that precipitation causes moderate hardening of the basal slip system, and also significantly increases the work hardening rate. The compression of [112¯0] initiated twinning, but the present experiments were dominated by twin nucleation, rather than growth. It was found that the effect of precipitation on twin nucleation was negligible. Precipitation had little effect on specimens compressed in the c-axis.

Polyhydroxybutyrate in Rhizobium and Bradyrhizobium: quantification and phbC gene expression

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Anelastic spectroscopy in a Ti alloy used as biomaterial

Ti and its alloys have been used thoroughly in the production of prostheses and dental implants due to their properties, such as high corrosion resistance, low elasticity modulus and high mechanical strength/density relation. Among the Ti-based alloys, the Ti-35Nb-7Zr-5Ta (TNZT) is one that presents the smallest elasticity modulus, making it an excellent alternative to be used as a biomaterial. In this paper, mechanical spectroscopy measurements were made in TNZT alloys containing several quantities of oxygen and nitrogen in solid solution. Mechanical spectroscopy measurements were made by using a torsion pendulum, operating at an oscillation frequency in the interval 4-30 Hz, temperature in the range 100-700 K, heating rate of about 1 K/min and vacuum lower than 10(-5) Torr. Complex relaxation structures and a reduction in the elasticity modulus were observed for the heat-treated and doped samples. The observed peaks were associated with the interactions of interstitial atoms and the alloy elements. (C) 2009 Elsevier B.V. All rights reserved.

Qualitative and quantitative characterization of aluminium alloys after corrosion testing

The 2024 and 7050 aluminium alloys used as aircraft components were subjected to laboratory corrosion tests in sodium chloride solution, Light-microscope examinations make it possible to characterise morphological aspects of the localised corrosion. Image analysis was used to determine both depth and width of pits over corroded surfaces. It has been concluded that the annealing could reduce the pit growth in both alloys, by means of grains recrystallization or recovery. The 2024 alloy also tends to present an exfoliation mechanism, mainly throughout non-recrystallized and recrystallized grain boundaries, increasing the width and sustaining the depth of pit cavities during exposition to saline atmosphere. SEM and EDS analysis reveal the morphology and elemental distribution of the corrosion products formed after immersion corrosion test. Some of these products were identified by X-ray diffraction analysis. For 2024, Al(OH)(3), MS(OH)(2) and Cu2O were found. AI(OH)(3) and Cu2O were also found in 7050 samples.

Removal of total coliforms, thermotolerant coliforms, and helminth eggs in Swine production wastewater treated in anaerobic and aerobic reactors

The present work evaluated the performance of two treatment systems in reducing indicators of biological contamination in swine production wastewater. System I consisted of two upflow anaerobic sludge blanket (UASB) reactors, with 510 and 209 L in volume, being serially arranged. System II consisted of a UASB reactor, anaerobic filter, trickling filter, and decanter, being also organized in series, with volumes of 300, 190, 250, and 150 L, respectively. Hydraulic retention times (HRT) applied in the first UASB reactors were 40, 30, 20, and 11 h in systems I and II. The average removal efficiencies of total and thermotolerant coliforms in system I were 92.92% to 99.50% and 94.29% to 99.56%, respectively, and increased in system II to 99.45% to 99.91% and 99.52% to 99.93%, respectively. Average removal rates of helminth eggs in system I were 96.44% to 99.11%, reaching 100% as in system II. In reactor sludge, the counts of total and thermotolerant coliforms ranged between 10(5) and 10(9) MPN (100 mL)(-1), while helminth eggs ranged from 0.86 to 9.27 eggs g(-1) TS.