Structure, organization and dynamics of functional supramolecular materials studied by solid-state NMR

Functional materials have great importance due to their many important applications. The characterization of supramolecular architectures which are held together by non-covalent interactions is of most importance to understand their properties. Solid-state NMR methods have recently been proven to be able to unravel such structure-property relations with the help of fast magic-angle spinning and advanced pulse sequences. The aim of the current work is to understand the structure and dynamics of functional supramolecular materials which are potentially important for fuel-cell (proton conducting membrane materials) and solar-cell or plastic-electronic applications (photo-reactive aromatic materials). In particular, hydrogen-bonding networks, local proton mobility, molecular packing arrangements, and local dynamics will be studied by the use of advanced solid-state NMR methods. The first class of materials studied in this work is proton conducting polymers which also form hydrogen-bonding network. Different materials, which are prepared for high 1H conduction by different approaches are studied: PAA-P4VP, PVPA-ABPBI, Tz5Si, and Triazole-functional systems. The materials are examples of the following major groups; - Homopolymers with specific functional groups (Triazole functional polysiloxanes). - Acid-base polymer blends approach (PAA-P4VP, PVPA-ABPBI). - Acid-base copolymer approach (Triazole-PVPA). - Acid doped polymers (Triazole functional polymer doped with H3PO4). Perylenebisimide (PBI) derivatives, a second type of important functional supramolecular materials with potent applications in plastic electronics, were also investigated by means of solid-state NMR. The preparation of conducting nanoscopic fibers based on the self-assembling functional units is an appealing aim as they may be incorporated in molecular electronic devices. In this category, perylene derivatives have attracted great attention due to their high charge carrier mobility. A detailed knowledge about their supramolecular structure and molecular dynamics is crucial for the understanding of their electronic properties. The aim is to understand the structure, dynamics and packing arrangements which lead to high electron conductivity in PBI derivatives.

Governing the Local: Sovereignty, Social Governance and Community Safety

There has been much commentary about the re-ordering of the relations between nation state government, geographical territory, and populations in the advanced liberal democracies. This is seen as a product of: increasing demographic and cultural diversity due to legal and illegal migration; economic, cultural, and political global interdependence; footloose mobility of capital and the outsourcing of jobs to poorer countries; the growing power of international corporations and financial markets; and the growth of supra-national bodies like the European Union and The North Atlantic Free Trade Association, the World Trade Organisation, and (debatably), the UN. These developments are held to be associated with the gradual demise of the model of the increasingly secular nation state first crystallised by the Treaty of Westphalia in 1648. This conception provided a mutual, guarantee of states’ jurisdiction over territory and populations through their legitimated attempts to monopolise the use of force. Though, the relations between these states have always been asymmetrical and often challenged (Hunter 1998).

The prevalence of burnout among psychologists and psychological associates in the state of Texas

This study investigates the prevalence of burnout among a sample of Texas psychologists and psychological associates as well as differences between the three categories of practitioners within that group (Licensed Psychology Health Care Providers (LPHCP), Licensed Psychologists - Certified Psychologists (LP-CP), Psychological Associates (PA)).^ The Maslach Burnout Inventory and a questionnaire seeking demographic information was used in this cross-sectional survey. Sample size was 654. A stratified proportionate random sample of Texas Psychologists was drawn. The response rate based on usable returns was 55% (n = 359). General demographic characteristics were determined mainly by frequency distributions. For comparing means of samples, t and multiple range tests were used. A series of one-way and two-way analysis of variance procedures were used to compare subgroup differences in burnout.^ The universe was representative for the sample and for the three categories of psychologists. Urban subjects were more likely to respond, as were male PAs. Practitioners were as likely male as female, working in an urban area, in their present job eight years, and in the occupation for fifteen. The LPHCP group were older, had been in psychology and at their present job longer, and were more likely to belong to both state and local professional organizations than the other two groups. Males outnumbered females in this group and in LP-CPs. This gender trend was reversed for PAs. Of the total sample, 76% reported high job satisfaction and 77% had high levels of perceived job autonomy. There was no significant difference between the study sample and the mental health norms in emotional exhaustion (EE). Our sample had significantly less feelings of depersonalization (DP) and higher feelings of personal accomplishment (PA). Psychological Associates felt significantly less personal accomplishment than the other groups. Predictors for the total sample indicated younger practitioners and those with low job satisfaction had significantly higher burnout, as did males when compared to their female cohorts. Some types of jobs were more likely to contribute to burnout than others. Membership in their local area professional organization lessened the chances for burnout significantly. Predictors for categories of psychologists indicated that males in the LPHCP and LP-CP groups were at higher risk than females. Further, for LP-CPs low job satisfaction and job autonomy, as well as job sites, were significant. Those in this group who worked as school psychologists were at the highest risk for burnout. Job dissatisfaction was the major predictor of burnout for psychological associates. Practitioners working in state or government agencies, school systems and administrative jobs generally had higher burnout than those on a university faculty or in private practice. (Abstract shortened by UMI.) ^

As iniciativas e experiências em agroecologia como estratégia de desenvolvimento local em um assentamento de reforma agrária

This paper searches to understand which disputes and conflicts are around the consolidation of agroecology as one of the alternatives and initiatives of local development in a land reform settlement. Thus, this paper, which consists of one of the results presented in the author´s dissertation, aims to identify the disputes and conflicts that occur among local initiatives related to agroecology. Santa Rosa settlement is located in one of the densest areas in relation to rural settlements in Rio Grande do Sul (RS) State. The research sources used to collect data and references to this paper were obtained in: researched bibliography in the writing of the author's dissertation; academic articles; and perceptions from the author's experiences in some land reform settlements. In this research it was considered that initiatives and actions in agroecology in the studied settlement can be strategic to make the social relations potential to the occurrence of experiences in local development different from those that occur alongside agribusiness.

'Todo por los chicos' o las disputas en torno de los sentidos de la política : Nociones legitimadoras, planes de empleo y proyecto colectivo en un espacio de sociabilidad local

Cuando en 2002 la política de planes de empleo se masificó, la asistencia social pasó de tener un papel residual a constituir parte explícita de las políticas de Estado. Este proceso promovió que diversos actores pugnaran por los modos de distribución y gestión de los recursos 'planes', así como por legitimar su lugar en la trama de vínculos que este modo de intervención estatal comporta. De esta manera, se configuraron experiencias de organización locales que incorporaron, a las ya múltiples temporalidades de sus dinámicas organizativas, el ritmo de la política social. En este contexto, nos proponemos indagar los modos de politicidad que emergen en una forma social específica, una copa de leche que gestiona planes sociales, en tanto espacio de interacción que condensa diferentes formas de presencia estatal, conflictos en torno de la definición de las necesidades locales y la posibilidad de imbricar criterios individuales de participación en el marco de un proyecto colectivo, que se articula en un horizonte polisémico compartido : 'Todo por los chicos'

As iniciativas e experiências em agroecologia como estratégia de desenvolvimento local em um assentamento de reforma agrária

This paper searches to understand which disputes and conflicts are around the consolidation of agroecology as one of the alternatives and initiatives of local development in a land reform settlement. Thus, this paper, which consists of one of the results presented in the author´s dissertation, aims to identify the disputes and conflicts that occur among local initiatives related to agroecology. Santa Rosa settlement is located in one of the densest areas in relation to rural settlements in Rio Grande do Sul (RS) State. The research sources used to collect data and references to this paper were obtained in: researched bibliography in the writing of the author's dissertation; academic articles; and perceptions from the author's experiences in some land reform settlements. In this research it was considered that initiatives and actions in agroecology in the studied settlement can be strategic to make the social relations potential to the occurrence of experiences in local development different from those that occur alongside agribusiness.

'Todo por los chicos' o las disputas en torno de los sentidos de la política : Nociones legitimadoras, planes de empleo y proyecto colectivo en un espacio de sociabilidad local

Cuando en 2002 la política de planes de empleo se masificó, la asistencia social pasó de tener un papel residual a constituir parte explícita de las políticas de Estado. Este proceso promovió que diversos actores pugnaran por los modos de distribución y gestión de los recursos 'planes', así como por legitimar su lugar en la trama de vínculos que este modo de intervención estatal comporta. De esta manera, se configuraron experiencias de organización locales que incorporaron, a las ya múltiples temporalidades de sus dinámicas organizativas, el ritmo de la política social. En este contexto, nos proponemos indagar los modos de politicidad que emergen en una forma social específica, una copa de leche que gestiona planes sociales, en tanto espacio de interacción que condensa diferentes formas de presencia estatal, conflictos en torno de la definición de las necesidades locales y la posibilidad de imbricar criterios individuales de participación en el marco de un proyecto colectivo, que se articula en un horizonte polisémico compartido : 'Todo por los chicos'

As iniciativas e experiências em agroecologia como estratégia de desenvolvimento local em um assentamento de reforma agrária

This paper searches to understand which disputes and conflicts are around the consolidation of agroecology as one of the alternatives and initiatives of local development in a land reform settlement. Thus, this paper, which consists of one of the results presented in the author´s dissertation, aims to identify the disputes and conflicts that occur among local initiatives related to agroecology. Santa Rosa settlement is located in one of the densest areas in relation to rural settlements in Rio Grande do Sul (RS) State. The research sources used to collect data and references to this paper were obtained in: researched bibliography in the writing of the author's dissertation; academic articles; and perceptions from the author's experiences in some land reform settlements. In this research it was considered that initiatives and actions in agroecology in the studied settlement can be strategic to make the social relations potential to the occurrence of experiences in local development different from those that occur alongside agribusiness.

'Todo por los chicos' o las disputas en torno de los sentidos de la política : Nociones legitimadoras, planes de empleo y proyecto colectivo en un espacio de sociabilidad local

Cuando en 2002 la política de planes de empleo se masificó, la asistencia social pasó de tener un papel residual a constituir parte explícita de las políticas de Estado. Este proceso promovió que diversos actores pugnaran por los modos de distribución y gestión de los recursos 'planes', así como por legitimar su lugar en la trama de vínculos que este modo de intervención estatal comporta. De esta manera, se configuraron experiencias de organización locales que incorporaron, a las ya múltiples temporalidades de sus dinámicas organizativas, el ritmo de la política social. En este contexto, nos proponemos indagar los modos de politicidad que emergen en una forma social específica, una copa de leche que gestiona planes sociales, en tanto espacio de interacción que condensa diferentes formas de presencia estatal, conflictos en torno de la definición de las necesidades locales y la posibilidad de imbricar criterios individuales de participación en el marco de un proyecto colectivo, que se articula en un horizonte polisémico compartido : 'Todo por los chicos'