Produção e caracterização de carbono vítreo monolítico a partir das resinas poliarilacetileno e furfurílica

Pós-graduação em Engenharia Mecânica - FEG

Persistência da lactação e Influência da estrutura de dados sobre a estimação de parâmetros genéticos para a produção de leite de bovinos da raça Holandesa

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Investigação eletroquímica e aplicação de eletrodos de carbono vítreo modificados por filmes de poli-L-lisina na determinação de antioxidantes

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Preparação, caracterização e aplicação de carbono polimérico vítreo em sensores eletroquímicos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Persistência e liberação de elementos da fitomassa do consórcio crotalária com milheto sob fragmentação

Objetivou-se, com esse trabalho, avaliar a taxa de decomposição e a velocidade de liberação de macronutrientes e Si da fitomassa do consórcio crotalária mais milheto, em função do tempo após manejo, sem e com fragmentação. O experimento foi conduzido em condições de campo, em Botucatu-SP. O delineamento experimental foi de blocos casualizados, com quatro repetições, em esquema fatorial constituído por dois manejos da fitomassa da parte aérea (sem e com fragmentação mecânica) e seis épocas de coleta [0; 18; 32; 46; 74 e 91 dias após manejo (DAM)]. Foram determinadas a massa de matéria seca, teor de macronutrientes e Si e quantidade dos nutrientes remanescentes. Os dados foram submetidos à análise de variância, as médias dos tratamentos do fator manejo comparadas pelo teste de t (LSD) a 5% e do fator épocas de coletas ajustados a equações matemáticas. A fragmentação da fitomassa aumenta a taxa de decomposição e a liberação de N, P, Ca e S. O K é rapidamente disponibilizado, restando 91 DAM, em média, 1,5% da quantidade total acumulada. Aos 91 DAM pelo menos 80% de todos os macronutrientes já haviam sido liberados ao solo. A máxima liberação diária dos macronutrientes ocorre entre 0 a 18 DAM. A taxa de liberação de Si é constante e ocorre aumento do teor do elemento na fitomassa com o tempo devido à acentuada liberação de C. O Si é o elemento liberado mais lentamente ao solo, restando ainda 91 DAM, em média, 85% da quantidade total acumulada na fitomassa.

Análise histopatológica do comportamento pulpar, pós cimentação de coroas totais metálicas com cimentos de ionômero vítreo e fosfato de zinco

Pós-graduação em Odontologia Restauradora - ICT

Representação e Persistência para acesso a Recursos Informacionais Digitais gerados dinamicamente em sítios oficiais do Governo Federal

The Information Access law, sanctioned in November 18, 2011, regulates the constitutional right of access to public information by Brazilian citizens. Although this law requires the provision of information of public interest, it does not define how such information should be made available. Ideally, information should be in an open format, allowing its use in an efficient and fast way. In the official sites of the federal government the way information is currently available does not allow its reuse as they are presented in dynamic pages from the selection parameters and filters. The objective aim of this paper is to present the system called MDDIR Tool, which proposes ways to persist, represent and retrieve digital information resources generated by the Federal Government official sites. Although this system had been designed for a specific purpose, it may be applied to other fields with similar characteristics. The purpose is to facilitate the access to open data, allowing such data to be consolidated and organized , generating new knowledge and information easy to be interpreted by the general population.

Eletrodos impressos descartáveis e de carbono vítreo modificados com grafeno e compósito de nanotubos de carbono-quitosana aplicados na determinação de corantes de cabelo

Pós-graduação em Química - IQ

A transitoriedade entre o mundo primitivo e o moderno nas obras The Sea-Wolf e White Fang de Jack London

The American author Jack London wrote the books The Sea-Wolf and White Fang in 1904 and 1906, respectively. The former portrays the life of a literary critic, Humphrey Van Weyden, who after the wreckage of the ship in which he was is rescued by a seal-hunting schooner, where he is obliged to work and to live with the brutal captain Wolf Larsen, and in doing so he develops a more primitive profile. The latter work portrays the life of the eponymous character, a wolf that leaves the wild world in which it was born to follow its last master in the city, thus developing features of the modern world. This paper aims to conduct an analysis of the aspects that allow the transition between the primitive and the modern world in those works

Produção de eletrodos em carbono vítreo monolítico e reticulado a partir da resina furfurílica dopada com cobre

The glassy carbon is a material with a huge technological evolution. Due to its lightness, biocompatibility and their thermal and electrical properties this material finds applications in several industrial fields such as electronics, medical, aerospace and chemical. In order to explore the conductive properties of glassy carbon for use as modified electrodes, the present work aims the processing of monolithic and reticulated glassy carbon with colloidal copper for use in electrochemical applications. First, the best parameters for the cure of furfuryl alcohol resin doped were established through viscosimetry measurements and pressurized differential scanning calorimetry. The analysis of the micrographs of the cured resins show that copper concentrations above 3% weight, generate higher porosity in the material. The characterizations of the monolithic and reticulated glassy carbon resulting from carbonization were performed by scanning electron microscopy (SEM), Raman and Electrochemical impedance spectroscopy, and although it was not possible to detect the presence of copper by SEM, the influence of these particles have been observed by Raman and FT-IR spectra and electrochemical behavior of the material. The decrease in conductivity of monolithic and reticulated glassy carbon in the presence of copper may be related to the defects caused by the presence of copper in the structure of the material.

Sintese e caracterização da resina fenol-furfurílica para a obtenção de carbono vítreo monolítico

The monolithic glassy carbon is a carbonaceous material, isotropic, non graphitizable obtained by means of carbonization of resins up to 1000 °C. The good physicochemical properties make this material applied in several areas such as aerospace, medicine, electronics, chemistry, among others. It has generally been processed from the use of phenolic and furfuryl alcohol resins. These resins have high crosslink density and high fixed carbon content and are therefore widely applied in aerospace. The combination phenol / furfuryl alcohol resins search for obtaining the most suitable process for the glass-like carbon processing with phenolic resins currently available and of lower cost and easier to synthesize than the furfuryl alcohol resin. The main objective of this work is to obtain a phenol-furfuryl resin with high fixed carbon content combined with low porosity of the material. Different synthesis routes have been adopted along with thermal analysis techniques, FTIR and image analysis. The resin obtained through partial synthesis process presented the characteristics sought in this work

Estudo da superfície do carbono vítreo reticulado após tratamento de implantação iônica por imersão em plasma (3IP) para a obtenção de eletrodos

In this work, RVC samples were treated by plasma immersion ion implantation (PIII) for electrodes production. High-voltage pulses with amplitudes of -3.0 kV or -10.0 kV were applied to the RVC samples while the treatment time was 10, 20 and 30 minutes. Nitrogen, atmospheric air and H2:N2 mixture were employed as plasma sources. The samples were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and electrochemical measurements. The SEM images present an apparent enhancement of the surface roughness after the treatment probably due to the surface sputtering during the PIII process. This observation is in agreement with the specific electrochemical surface area (SESA) of RVC electrodes. An increase was observed of the SESA values for the PIII treated samples compared to the untreated specimen. Some oxygen and nitrogen containing groups were introduced on the RVC surface after the PIII treatment. Both plasma-induced process: the surface roughening and the introduction of the polar species on the RVC surface are beneficial for the RVC electrodes application

Estudo comparativo de filmes de corantes fenotiazínicos na superfície de eletrodo de carbono vítreo e adsorvidos em titânio fosfatado e suas aplicações eletroanalíticas

Pós-graduação em Ciência dos Materiais - FEIS

Análise da espessura da película de cimentos de ionômero vítreo e fosfato de zinco, empregados na cimentação de coroas totais metálicas, preparadas in vivo

Pós-graduação em Odontologia Restauradora - ICT