882 resultados para Non book materials
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Mode of access: Internet.
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Includes bibliographies.
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Cover title.
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Microfilm. Ann Arbor, Mich., University Microfilms [n.d.] (American culture series, Reel 35.10)
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Mode of access: Internet.
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Mode of access: Internet.
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"Supplementary bibliographies": p. [871]-915.
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Bibliography: p. [449]-451.
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Mode of access: Internet.
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Preliminary unpublished report.
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Various pagings.
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Mode of access: Internet.
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Nitrogen adsorption on a surface of a non-porous reference material is widely used in the characterization. Traditionally, the enhancement of solid-fluid potential in a porous solid is accounted for by incorporating the surface curvature into the solid-fluid Potential of the flat reference surface. However, this calculation procedure has not been justified experimentally. In this paper, we derive the solid-fluid potential of mesoporous MCM-41 solid by using solely the adsorption isotherm of that solid. This solid-fluid potential is then compared with that of the non-porous reference surface. In derivation of the solid-fluid potential for both reference surface and mesoporous MCM-41 silica (diameter ranging front 3 to 6.5 nm) we employ the nonlocal density functional theory developed for amorphous solids. It is found that, to out, surprise, the solid-fluid potential of a porous solid is practically the same as that for the reference surface, indicating that there is no enhancement due to Surface curvature. This requires further investigations to explain this unusual departure from our conventional wisdom of curvature-induced enhancement. Accepting the curvature-independent solid-fluid potential derived from the non-porous reference surface, we analyze the hysteresis features of a series of MCM-41 samples. (c) 2005 Elsevier Inc. All rights reserved.