Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives

Artículo científico CrystEngComm

Patterns of Impact Resulting from a 'Sit Less, Move More' Web-Based Program in Sedentary Office Employees

Purpose Encouraging office workers to 'sit less and move more' encompasses two public health priorities. However, there is little evidence on the effectiveness of workplace interventions for reducing sitting, even less about the longer term effects of such interventions and still less on dual-focused interventions. This study assessed the short and mid-term impacts of a workplace web-based intervention (Walk@WorkSpain, W@WS; 2010-11) on self-reported sitting time, step counts and physical risk factors (waist circumference, BMI, blood pressure) for chronic disease. Methods Employees at six Spanish university campuses (n=264; 42 +/- 10 years; 171 female) were randomly assigned by worksite and campus to an Intervention (used W@WS; n=129; 87 female) or a Comparison group (maintained normal behavior; n=135; 84 female). This phased, 19-week program aimed to decrease occupational sitting time through increased incidental movement and short walks. A linear mixed model assessed changes in outcome measures between the baseline, ramping (8 weeks), maintenance (11 weeks) and follow-up (two months) phases for Intervention versus Comparison groups. Results A significant 2 (group) x 2 (program phases) interaction was found for self-reported occupational sitting (F[3]=7.97, p=0.046), daily step counts (F[3]=15.68, p=0.0013) and waist circumference (F[3]=11.67, p=0.0086). The Intervention group decreased minutes of daily occupational sitting while also increasing step counts from baseline (446 +/- 126; 8,862 +/- 2,475) through ramping (+425 +/- 120; 9,345 +/- 2,435), maintenance (+422 +/- 123; 9,638 +/- 3,131) and follow-up (+414 +/- 129; 9,786 +/- 3,205). In the Comparison group, compared to baseline (404 +/- 106), sitting time remained unchanged through ramping and maintenance, but decreased at follow-up (-388 +/- 120), while step counts diminished across all phases. The Intervention group significantly reduced waist circumference by 2.1cms from baseline to follow-up while the Comparison group reduced waist circumference by 1.3cms over the same period. Conclusions W@WSis a feasible and effective evidence-based intervention that can be successfully deployed with sedentary employees to elicit sustained changes on "sitting less and moving more".

Invasionsoft: a web-enabled tool for invasive species colonization predictions

Predicting and averting the spread of invasive species is a core focus of resource managers in all ecosystems. Patterns of invasion are difficult to forecast, compounded by a lack of user-friendly species distribution model (SDM) tools to help managers focus control efforts. This paper presents a web-based cellular automata hybrid modeling tool developed to study the invasion pattern of lionfish (Pterois volitans/miles) in the western Atlantic and is a natural extension our previous lionfish study. Our goal is to make publically available this hybrid SDM tool and demonstrate both a test case (P. volitans/miles) and a use case (Caulerpa taxifolia). The software derived from the model, titled Invasionsoft, is unique in its ability to examine multiple default or user-defined parameters, their relation to invasion patterns, and is presented in a rich web browser-based GUI with integrated results viewer. The beta version is not species-specific and includes a default parameter set that is tailored to the marine habitat. Invasionsoft is provided as copyright protected freeware at http://www.invasionsoft.com.

Assessment of existing information on Atlantic coastal fish habitats: development of a web-based spatial bibliography, query tools, and data summaries

The primary objective of this project, “the Assessment of Existing Information on Atlantic Coastal Fish Habitat”, is to inform conservation planning for the Atlantic Coastal Fish Habitat Partnership (ACFHP). ACFHP is recognized as a Partnership by the National Fish Habitat Action Plan (NFHAP), whose overall mission is to protect, restore, and enhance the nation’s fish and aquatic communities through partnerships that foster fish habitat conservation. This project is a cooperative effort of NOAA/NOS Center for Coastal Monitoring and Assessment (CCMA) Biogeography Branch and ACFHP. The Assessment includes three components; 1. a representative bibliographic and assessment database, 2. a Geographical Information System (GIS) spatial framework, and 3. a summary document with description of methods, analyses of habitat assessment information, and recommendations for further work. The spatial bibliography was created by linking the bibliographic table developed in Microsoft Excel and exported to SQL Server, with the spatial framework developed in ArcGIS and exported to GoogleMaps. The bibliography is a comprehensive, searchable database of over 500 selected documents and data sources on Atlantic coastal fish species and habitats. Key information captured for each entry includes basic bibliographic data, spatial footprint (e.g. waterbody or watershed), species and habitats covered, and electronic availability. Information on habitat condition indicators, threats, and conservation recommendations are extracted from each entry and recorded in a separate linked table. The spatial framework is a functional digital map based on polygon layers of watersheds, estuarine and marine waterbodies derived from NOAA’s Coastal Assessment Framework, MMS/NOAA’s Multipurpose Marine Cadastre, and other sources, providing spatial reference for all of the documents cited in the bibliography. Together, the bibliography and assessment tables and their spatial framework provide a powerful tool to query and assess available information through a publicly available web interface. They were designed to support the development of priorities for ACFHP’s conservation efforts within a geographic area extending from Maine to Florida, and from coastal watersheds seaward to the edge of the continental shelf. The Atlantic Coastal Fish Habitat Partnership has made initial use of the Assessment of Existing Information. Though it has not yet applied the AEI in a systematic or structured manner, it expects to find further uses as the draft conservation strategic plan is refined, and as regional action plans are developed. It also provides a means to move beyond an “assessment of existing information” towards an “assessment of fish habitat”, and is being applied towards the National Fish Habitat Action Plan (NFHAP) 2010 Assessment. Beyond the scope of the current project, there may be application to broader initiatives such as Integrated Ecosystem Assessments (IEAs), Ecosystem Based Management (EBM), and Marine Spatial Planning (MSP).

Domoic acid contamination within eight representative species from the benthic food web of Monterey Bay, California, USA

Benthic food webs often derive a significant fraction of their nutrient inputs from phytoplankton in the overlying waters. If the phytoplankton include harmful algal species like Pseudo-nitzschia australis, a diatom capable of producing the neurotoxin domoic acid (DA), the benthic food web can become a depository for phycotoxins. We tested the general hypothesis that DA contaminates benthic organisms during local blooms of P. australis, a widespread toxin producer along the US west coast. To test for trophic transfer and uptake of DA into the benthic food web, we sampled 8 benthic species comprising 4 feeding groups: filter feeders (Emerita analoga and Urechis caupo); a predator (Citharichthys sordidus); scavengers (Nassarius fossatus and Pagurus samuelis) and deposit feeders (Neotrypaea californiensis, Dendraster excentricus and Olivella biplicata). Sampling occurred before, during and after blooms of P. australis in Monterey Bay, CA, USA during 2000 and 2001. DA was detected in all 8 species, with contamination persisting over variable time scales. Maximum DA levels in N. fossatus (674 ppm), E. analoga (278 ppm), C. sordidus (515 ppm), N. californiensis (145 ppm), P. samuelis (56 ppm), D. excentricus (15 ppm) and O. biplicata (3 ppm) coincided with P. australis blooms, while DA levels in U. caupo remained above 200 ppm (max. = 751 ppm) throughout the study period. DA in 6 species exceeded levels thought to be safe for higher level consumers (i.e. ≥20 ppm) and thus is likely to have deleterious effects on marine birds, sea lions and the endangered California sea otter, known to prey upon these benthic species.

Aerodynamic effects in ink-jet printing on a moving web

The airflow between the fast-moving substrate and stationary print heads in a web print press may cause print quality issues in high-speed, roll-to-roll printing applications. We have studied the interactions between ink drops and the airflow in the gap between the printhead and substrate, by using an experimental flow channel and high-speed imaging. The results show: 1) the gap airflow is well approximated by a standard Couette flow profile; 2) the effect of gap airflow on the flight paths of main drops and satellites is negligible; and 3) the interaction between the gap airflow and the wakes from the printed ink drops should be investigated as the primary source of aerodynamically- related print quality issues. ©2012 Society for Imaging Science and Technology.

Transfer, distribution and bioaccumulation of microcystins in the aquatic food web in Lake Taihu, China, with potential risks to human health

In this paper, accumulation and distribution of microcystins (MCs) was examined monthly in six species of fish with different trophic levels in Meiliang Bay, Lake Taihu, China, from June to November 2005, Microcystins were analyzed by liquid chromatography electrospray ionization mass spectrometry (LC-ESI-MS). Average recoveries of spiked fish samples were 67.7% for MC-RR, 85.3% for MC-YR, and 88.6% for MC-LR. The MCs (MC-RR+MC-YR+MC-LR) concentration in liver and gut content was highest in phytoplanktivorous fish, followed by omnivorous fish, and was lowest in carnivorous fish; while MCs concentration in muscle was highest in omnivorous fish, followed by phytoplanktivorous fish, and was lowest in carnivorous fish. This is the first study reporting MCs accumulation in the gonad of fish in field. The main uptake of MC-YR in fish seems to be through the gills from the dissolved MCs. The WHO limit for tolerable daily intake was exceeded only in common carp muscle. (C) 2008 Elsevier B.V. All rights reserved.

Cathodoluminescence on GaN hexagonal pyramids on submicron dot-patterns via selective MOVPE

Three-dimensional GaN pyramids have been successfully obtained on submicron dot-patterned (0001) sapphire substrates by using the selective metalorganic vapor phase epitaxy (MOVPE) technique. The dot-pattern is a hexagon arranged with a 0.5-mu m width and 1.0-mu m spacing. The GaN structure comprises a hexagonal pyramid covered with six {1 (1) over bar 01} pyramidal facets on the side of a hexagonal pyramid having a (0001) facet on the top. Cathodoluminescence (CL) measurement was carried our. on the hexagonal pyramid at low temperature. Two distinct spectra were observed to occur at about 359 and 329 nm. The higher energy is thought to be related to GaN dot, and the lower one is due to GaN dot band edge emission. The intensities of the two spectra were investigated as a function of temperature in the range of 135-150 K. (C) 2000 Published by Elsevier Science B.V.

The content calculation of hexagonal phase inclusions in cubic GaN films on GaAs(001) substrates grown by metalorganic chemical vapor deposition

Cubic GaN(c-GaN) films are grown on GaAs(001) substrates by metalorganic chemical vapor deposition (MOCVD). Two GaN samples were grown with different buffer layer, the deposition time of each was 1 and 3 min, respectively. 4-circle X-ray double crystal diffraction (XRDCD) was used to study the secondary crystallographic phases presented in the c-GaN films. The phase composition of the epilayers was determined by X-ray reciprocal space mapping. The intensities of the c-GaN(002) and h-GaN(10 (1) over bar 1) planes detected in the mapping were investigated by omega scans. The content of the hexagonal phase inclusions in the c-GaN films was calculated to about 1.6 and 7.9%, respectively. The thicker buffer layer is not preferable for growing high quality pure c-GaN films. (C) 2000 Elsevier Science S.A. All rights reserved.

Effect of buffer layer growth conditions on the secondary hexagonal phase content in cubic GaN films on GaAs(001) substrates

In this letter, we investigated the effect of the buffer layer growth conditions on the secondary hexagonal phase content in cubic GaN films on GaAs(0 0 1) substrate. The reflection high-energy electron diffraction (RHEED) pattern of the low-temperature GaN buffer layers shows that both the deposition temperature and time are important in obtaining a smooth surface. Four-circle X-ray double-crystal diffraction (XRDCD) reciprocal space mapping was used to study the hexagonal phase inclusions in the cubic GaN (c-GaN) films grown on the buffer layers. The calculation of the volume contents of the hexagonal phase shows that higher temperature and longer time deposition of the buffer layer is not preferable for growing pure c-GaN film. Under optimized condition, 47 meV FWHM of near band gap emission of the c-GaN film was achieved. (C) 2000 Elsevier Science B.V. All rights reserved.

Web Services Workflows—Composition, Co-Ordination, and Transactions in Service-Oriented Computing

Web services can be seen as a newly emerging research area for Service-oriented Computing and their implementation in Service-oriented Architectures. Web services are self-contained, self-describing modular applications or components providing services. Web services may be dynamically aggregated, composed, and enacted as Web services Workflows. This requires frameworks and interaction protocols for their co-ordination and transaction support. In a Service-oriented Computing setting, transactions are more complex, involve multiple parties (roles), span many organizations, and may be long-running, consisting of a highly decentralized service partner and performed by autonomous entities. A Service-oriented Transaction Model has to provide comprehensive support for long-running propositions including negotiations, conversations, commitments, contracts, tracking, payments, and exception handling. Current transaction models and mechanisms including their protocols and primitives do not sufficiently cater for quality-aware and long running transactions comprising loosely-coupled (federated) service partners and resources. Web services transactions require co-ordination behavior provided by a traditional transaction mechanism to control the operations and outcome of an application. Furthermore, Web services transactions require the capability to handle the co-ordination of processing outcomes or results from multiple services in a more flexible manner. This requires more relaxed forms of transactions—those that do not strictly have to abide by the ACID properties—such as loosely-coupled collaboration and workflows. Furthermore, there is a need to group Web services into applications that require some form of correlation, but do not necessarily require transactional behavior. The purpose of this paper is to provide a state-of-the-art review and overview of some proposed standards surrounding Web services composition, co-ordination, and transaction. In particular the Business Process Execution Language for Web services (BPEL4WS), its co-ordination, and transaction frameworks (WS-Co-ordination and WS-Transaction) are discussed.

Web应用服务器的可扩展管理模型及其实现

Web应用服务器是为事务性web应用提供一系列运行时服务的分布式系统。它既要管理多种不同类型的资源，又要集成以往成熟的网络管理协议和系统，因此，如何统一有效地管理Web应用服务器的资源、应用和服务成为实现web应用服务的一个难点。为此，本文基于JMX(Java~(TM) Management Extensions)技术，提出了一种可扩展管理模型，该模型具有较好的灵活性和开放性，可扩展能力强。同时，本文还给出了实现该模型的若干关键技术包括可扩展管理内核的实现技术、资源远程管理技术、服务可扩展管理技术。目前该模型已在我们研制的Web应用服务器 WebFrame2．O中成功实现。

EWAF:一种Web应用程序框架

随着Web应用开发变得越来越复杂,如何快速开发出稳定健壮的Web应用程序成为开发者面临的巨大挑战,Web应用程序框架(WAF)就是为了适应这种挑战而出现的.提出了一种基于J2EE的Web应用程序框架EWAF,框架通过其特有的服务层、层次性的控制方式、组合式的视图结构及应用程序级的安全支持,使得Web开发者能够快速高效地构建安全的Web应用程序.目前,EWAF已应用到企业信息门户OncePortal的实现中.

语义Web服务匹配与发现技术研究

在开放的互联网环境中，面向服务的计算（Service-Oriented Computing, SOC）和面向服务的体系架构（Service-Oriented Architecture, SOA）使得信息资源和软件系统的主要形态发生了巨大变化，并引领着互联网计算技术和软件系统新的发展方向。服务是SOC和SOA的核心思想，服务的平台独立、高可重用和松散耦合等特性使之成为复杂分布式应用可行的解决方案。Web服务的出现和发展为实施与部署SOC和SOA提供了最佳支撑技术。目前web服务发现机制在服务描述的全面性和服务匹配方法的有效性方面存在不足之处，难以保证服务发现的性能。特别是在服务数量剧增的情况下，用户亟需一种自动快速而准确的服务发现机制。语义web技术不仅为web的表示内容提供了一种语义标识方法，推动了web内容的自动化和智能化搜索，也为web服务的描述提供了增加语义层次内容的有效方法，两者的结合形成了一个新的研究领域——语义web服务。该领域通过借鉴语义web的相关技术来增加web服务的语义描述，进而为web服务的发现、组合、调用和监控等环节提供语义层次的支持，增强web服务的自动化和智能化水平。 本文的研究目的就是利用语义web的思想，基于SOC和SOA的理念以及现有的web服务发现机制对web服务信息进行语义描述、组织，探索语义web服务匹配与发现的关键问题，提出有效的解决方案。本文的研究工作和贡献主要在以下四个方面： 1. 针对语义近似度的度量和计算问题基于OWL（Web Ontology Language）提出了一个语义近似度计算SSM模型，该模型中所有概念及概念之间的关系、所有的概念属性及属性之间的关系都被抽象定义并建模，根据概念、属性及其语义关系模型，构建了基于概念关系的拓扑近似度计算函数和属性近似度计算函数，从而进一步构建语义近似度计算函数。该语义近似度计算函数以代表OWL本体概念上下级关系和等价关系的树状结构为基础，利用概念间的拓扑关系和属性关系进行语义近似度的度量和计算。语义近似度函数的返回值为一个介于0与1之间的数值，代表函数的两个输入概念之间的语义近似度值。 2. 提出了一个基于概念语义近似度的以OWL-S为顶层本体的web服务语义匹配PSM模型。该模型将服务的匹配项分为服务能力、服务质量、服务名称和服务参数四个部分。基于该模型，提出了相应的PSM服务匹配算法。PSM算法能够对服务内部的服务流程及流程的组合进行与服务请求的语义匹配，并且避免了服务流程中互斥接口参数参与匹配。而且PSM匹配算法实现了服务接口的单射匹配，进一步提高服务发现的性能。在服务质量匹配计算上，提出了服务质量匹配模型PSM-QoS，为服务的QoS匹配建立了计算基础。PSM算法使用语义近似度计算函数度量和计算服务属性概念的语义近似度值，从而能够返回细粒度的服务匹配度值。 3. 在语义服务匹配PSM模型的基础上提出一种语义web服务发现架构系统PSM-SD模型。该模型将OWL-S语义元素引入UDDI服务描述，从而在UDDI中保存语义信息。通过PSM算法提高web服务匹配性能，并通过数据映射机制保证模型对于当前的服务发现标准UDDI基础架构的兼容以及UDDI标准操作接口的透明性。模型使用本体概念的索引机制提高服务发现的效率。在建立和维护索引的过程或服务的匹配过程中，模型使用近似概念搜寻算法进一步提高本体概念搜寻和服务匹配的效率。 4. 设计并开发了基于语义web服务发现架构模型的原型系统。该系统将语义近似度计算模型、语义web服务匹配模型和语义web服务发现架构模型进行软件实现。本文在该原型系统平台上对语义web服务发现的方法进行了实验，验证了方法的有效性。