Influence of cristalline structure of two minerals clays of type 1/1 on their pozzolanic power

Two clayey materials, one provided by a patner in mineral sector and the other coming from Balengou (West Region Cameroon) were subject of a comparative study in order to evaluate the influence of their crystalline structure on their pozzolanic property. These two natural materials were preliminary enriched in clay minerals by wet sieving and the fractions obtained are denoted K and H respectively. K and H were calcinated at 700 °C, with a heating rate of 5 °C/min and 10 hours dwell at the peak temperature, the products obtained were named MK and MH. Samples K, H, MK and MH were physicochemically characterized by the chemical (ICP), thermal(TGA/DTA) and mineralogical (DRX and Spectrometry IR) analyses together with the measurement of specific surface (BET), crystallinity and the pouzzolanicity test. The results confirmed K as a kaolinitic and H halloysic clay. The kaolinite and the halloysite respectively presented in these clayey materials exhibited a poor crystallinity, but the degree of disorder is higher in K than in H. These results were largely affected by the significant fraction of gibbsite in kaolinitic clay K. At the crude state, the pozzolanic activity of the material H is weak compared with that of K, but the heat treatment makes largely improve this property for both samples.

Does tin pre-treatment enhance the bond strength of adhesive systems to enamel?

OBJECTIVES The study investigated the modification of composite-to-enamel bond strength by pre-treatment of enamel with a concentrated, acidic SnCl2-solution. METHODS Six groups of flat human enamel specimens (n=44 per group) were treated as follows: OB-H: H3PO4 etching, Optibond FL application (primer+adhesive; manufacturer's instructions); OB-S: SnCl2 pre-treatment, Optibond FL application (primer+adhesive); OB-HS: H3PO4 etching+SnCl2 pre-treatment, Optibond FL application (primer+adhesive); CF-N: Clearfil SE application (primer+bond; manufacturer's instructions); CF-H: H3PO4 etching, Clearfil SE application (primer+bond); CF-S: SnCl2 pre-treatment, Clearfil SE application (primer+bond). Enamel specimens were then built up with resin composite (Clearfil Majesty Esthetic) and stored (100% humidity, 37 °C, 1 week). μTBS-measurement and failure mode analysis of one-half of the specimens were performed immediately after storage, while the other half was analysed after a thermocycling procedure (8500 cycles; 5 °C and 55 °C; dwell time 30s). Additional specimens were prepared for SEM- and EDX-analysis. RESULTS Highest values were measured for OB-H before and after thermocycling, lowest values for CF-N. Compared to OB-H treatment, OB-S treatment reduced μTBS before/after thermocycling by 23%/28% and OB-HS treatment by 8%/24% (except for OB-SH before (n.s.), all p≤0.001 compared to OB-H). In the Clearfil SE treated groups pre-treatment increased μTBS significantly compared to CF-N (before/after: CF-H: +46%/+70%; CF-S: +51%/42%; all p≤0.001). CONCLUSION Pre-treatment with H3PO4 or SnCl2 markedly increased the μTBS of Clearfil SE to enamel. However, thermocycling partly reduced the gain in μTBS obtained by SnCl2 pre-treatment. CLINICAL SIGNIFICANCE The application of an acidic and highly concentrated SnCl2 solution is a good option to increase the μTBS between enamel and a resin composite mediated by an adhesive system containing the multifunctional monomer MDP.

The subjective present and its modulation in clinical contexts

Time is a basic dimension in psychology, underlying behavior and experience. Timing and time perception constitute implicit processes that are often inaccessible to the individual person. Research in this field has shown that timing is involved in many areas of clinical significance. In the projects presented here, we combine timing with seemingly different fields of research, such as psychopathology, perceptual grouping, and embodied cognition. Focusing on the time scale of the subjective present, we report findings from three different clinical studies: (1) We studied perceived causality in schizophrenia patients, finding that perceptual grouping (‘binding’, ‘Gestalt formation’), which leads to visual causality perceptions, did not distinguish between patients and healthy controls. Patients however did integrate context (provided by the temporal distribution of auditory context stimuli) less into perceptions, in significant contrast to controls. This is consistent with reports of higher inaccuracy in schizophrenia patients’ temporal processing. (2) In a project on auditory Gestalt perception we investigated auditory perceptual grouping in schizophrenia patients. The mean dwell time was positively related to how much patients were prone to auditory hallucinations. Dwell times of auditory Gestalts may be regarded as operationalizations of the subjective present; findings thus suggested that patients with hallucinations had a shorter present. (3) The movement correlations of interacting individuals were used to study the non-verbal synchrony between therapist and patient in psychotherapy sessions. We operationalized the duration of an embodied ‘social present’ by the statistical significance of such associations, finding a window of roughly 5.7 seconds in conversing dyads.We discuss that temporal scales of nowness may be modifiable, e.g., by mindfulness. This yields promising goals for future research on timing in the clinical context: psychotherapeutic techniques may alter binding processes, hence the subjective present of individuals, and may affect the social present in therapeutic interactions.

The imaging and dosimetric capabilities of a CT/MR-suitable, anatomically adaptive, shielded intracavitary brachytherapy applicator for the treatment of cervical cancer

Introduction. Investigations into the shortcomings of current intracavitary brachytherapy (ICBT) technology has lead us to design an Anatomically Adaptive Applicator (A3). The goal of this work was to design and characterize the imaging and dosimetric capabilities of this device. The A3 design incorporates a single shield that can both rotate and translate within the colpostat. We hypothesized that this feature, coupled with specific A3 component construction materials and imaging techniques, would facilitate artifact-free CT and MR image acquisition. In addition, by shaping the delivered dose distribution via the A3 movable shield, dose delivered to the rectum will be less compared to equivalent treatments utilizing current state-of-the-art ICBT applicators. ^ Method and materials. A method was developed to facilitate an artifact-free CT imaging protocol that used a "step-and-shoot" technique: pausing the scanner midway through the scan and moving the A 3 shield out of the path of the beam. The A3 CT imaging capabilities were demonstrated acquiring images of a phantom that positioned the A3 and FW applicators in a clinically-applicable geometry. Artifact-free MRI imaging was achieved by utilizing MRI-compatible ovoid components and pulse-sequences that minimize susceptibility artifacts. Artifacts were qualitatively compared, in a clinical setup. For the dosimetric study, Monte-Carlo (MC) models of the A3 and FW (shielded and unshielded) applicators were validated. These models were incorporated into a MC model of one cervical cancer patient ICBT insertion, using 192Ir (mHDR v2 source). The A3 shield's rotation and translation was adjusted for each dwell position to minimize dose to the rectum. Superposition of dose to rectum for all A3 dwell sources (4 per ovoid) was applied to obtain a comparison of equivalent FW treatments. Rectal dose-volume histograms (absolute and HDR/PDR biologically effective dose (BED)) and BED to 2 cc (BED2cc ) were determined for all applicators and compared. ^ Results. Using a "step-and-shoot" CT scanning method and MR compliant materials and optimized pulse-sequences, images of the A 3 were nearly artifact-free for both modalities. The A3 reduced BED2cc by 18.5% and 7.2% for a PDR treatment and 22.4% and 8.7% for a HDR treatment compared to treatments delivered using an uFW and sFW applicator, respectively. ^ Conclusions. The novel design of the A3 facilitated nearly artifact-free image quality for both CT and MR clinical imaging protocols. The design also facilitated a reduction in BED to the rectum compared to equivalent ICBT treatments delivered using current, state-of-the-art applicators. ^

Description and chemical composition of ferromanganese deposits from Trout Lake, northern Wisconsin

Sediments were collected with Eckman and Petersen dredges from the bottom of Trout Lake, northern Wisconsin, at 221 stations. Sampling was done with a spud sampler at 32 stations, and core samples were obtained with a Jenkins and Mortimer and a Twenhofel sampler at 17 stations. The shore and offshore deposits of the shores of Trout Lake and the shores of the islands are described. Megascopic descriptions are given of the samples collected with the Eckman and Petersen dredges. Sediments on bottoms of about 10 meters or deeper are mainly gyttja, or crusts composed of mixtures of organic matter, ferric hydroxide, and some form of manganese oxide. The latter deposits are extensive. Detailed descriptions of some of the samples of sands are given, and generalizations respecting size and distribution are made. Tables showing quartiles, medians, and coefficients of sorting and skewness of the coarse sediments collected from the bottom are given in tables. Mechanical analyses of all fine sediments, mainly gyttja, were not made, as previous experience seems to have demonstrated that results have no sedimentational value. Organic matter of the gyttja was determined and also the percentages of lignin in the organic matter. Core samples are composed almost entirely of fine materials, mainly gyttja, and determinations were made on these samples in the same way as on the samples obtained with the Eckman and Petersen dredges. Studies of the core samples show that the fine sediments usually contain in excess of 90 per cent moisture and there is very little change in the moisture content from top to bottom of cores. A map shows the distribution of the iron and manganese deposits. These deposits were found to contain 10 to 20 per cent of organic matter, 11 to 16 per cent of metallic iron, and 12 to 30 per cent of metallic manganese. No stratification of any kind was found in any of the deep-water sediments of Trout Lake except in the iron and manganese crusts. Absence of stratification is considered to be due to the slow rate of deposition and the mixing of sediments by organisms which dwell in them. The data indicate that the rate of deposition in the deep waters of Trout Lake is of the order of 1 foot in 15,000 years.

Caracterización de diferentes homologaciones axiológicas vigentes en los dibujos animados para televisión

Los dibujos animados norteamericanos, sigilosamente, han ido ocupando un lugar cada vez más relevante en la industria cultural. Tanto es así, que hoy se pueden discriminar canales específicamente destinados a la animación y, a su vez, series de animaciones producidas para diversos públicos: niños, adolescentes y adultos. Frente a esta gran cantidad y diversidad de textos llama especialmente mi atención la convivencia de contrapuestos sistemas de valor. Numerosas tiras de dibujos animados, dirigidos especialmente a los niños, ayudan a conformar el gusto infantil contemporáneo (en el sentido de Calabrese) que no responde a un único sistema unificador de valores. Es decir, lo feo o lindo, lo malo o bueno, lo conforme o informe, lo disfórico o eufórico no está dictaminado hoy por un solo discurso axiológico imperante. En este escrito pretendo describir, desde una perspectiva semiótica, las particularidades que resultan de la coexistencia de morfologías, éticas y tímicas distintas. Para ello, me detendré en un grupo de cartoons que se presentan como las antípodas de los tradicionales y conocidos textos audiovisuales de Disney y de las clásicas y exitosas series animadas de la Warner Bross o la Metro Goldywn Mayer. Estas creaciones buscaron exhibir, desde su nacimiento, estabilidad en las formas, armonía cromática y uniformidad de comportamientos. Contrariamente, los mundos posibles que hoy también integran el universo de dibujos animados, evidencian lo que Calabrese denomina el placer de lo impreciso, lo indefinido, lo vago y lo ambiguo. Estas representaciones sincréticas exaltan notorias diferencias en sus homologaciones axiológicas liberándose de las pretensiones de perfección, tanto de sus escenarios como de sus actores figurativos: seres híbridos, animales aversivos, niños nefastos, criaturas deformes y escenarios difusos son algunas de las características que definen a los últimas producciones animadas para televisión.

Voces de un diálogo : Francisco Romero y los filósofos norteamericanos

La obra de Francisco Romero (1891–1962) ha revolucionado el pensamiento argentino no sólo en el sentido de crear un nuevo sistema filosófico, sino en el de sentar una genuina filosofía americana. Su trabajo se extendió no sólo al campo filosófico, sino también al editorial y universitario. En este contexto y a través del epistolario entramos en la práctica y los contenidos de sociabilidad, para delinear las contribuciones de la categoría en el campo de la historia de las ideas. Desde esta perspectiva partimos en el estudio del epistolario de Romero con filósofos de EEUU. Es acerca de un epistolario, esto es, un corpus de cartas que sostuvo con filósofos norteamericanos y europeos con residencia en EEUU entre 1942–1962. Entendemos que tal reservorio nos abre un camino para estudiar la escritura epistolar bajo códigos de sociabilidad.

Remarks on Compositionality (with reference to Gennadij Zeldoviè's article “On Russian Dative Reflexive Constructions: Accidental or Compositional”)

Zeldovič’s article “On Russian Dative Reflexive Constructions: Accidental or Compositional” is very interesting. It contains a good deal of insightful observations and is painstakingly argued. Its research object is the Russian dative reflexive construction (DRC) like Ивану не работается ‘Ivan does not feel like reading’. The aim of the article is to show that the DRC is fully compositional. Like many other works by Zeldovič, the article is written from the radical-pragmatic perspective and constitutes a very good illustration of this trend in linguistic research. The language material that it analyzes has often been investigated within more traditional frameworks, especially in Russian linguistics, which makes Zeldovič’s novel approach to the old problem particularly interesting. In this short note I would like (by way of discussion) to address two problems connected not so much with the DRC itself as with methodological issues concerning compositionality. I will dwell on two aspects: on the question of how we understand the very concept of compositionality, and what instruments we employ to demonstrate it.

Marcel Breuer y el sueño de la cabaña americana

Marcel Breuer arquitecto húngaro y afamado diseñador de mobiliario procedente de la Bauhaus, emigra a Estados Unidos en 1937, invitado por Gropius como profesor en Harvard. Allí comienzan, Breuer y Gropius, una nueva etapa basada en la experimentación de la casa como revisión de los postulados de la arquitectura moderna: la casa como máquina de habitar, propuesta por Le Corbusier, procedente de la vieja Europa; versus la humanización de la máquina a través del efecto del material sobre la estructura y la forma extendidas y en contacto con el territorio, propuesta por Frank Lloyd Wright procedente de la nueva América. Sus experimentos domésticos sobre la casa-cabaña acercaron los métodos tradicionales de la construcción americana a una visión renovada abstracta y pura, donde los modos de vida, los requerimientos básicos, prácticos y funcionales se transformaron en la conexión del "Arte de Construir" a través del material y su puesta en obra. La búsqueda de una respuesta clara del habitar que satisfacía objetivos opuestos y necesidades humanas, llevó a su arquitectura de la abstracción a reconciliar al hombre con la naturaleza, dotarla de arte y vida, arquitectura y paisaje que pasaron a convertirse en los ideales modernos de la cabaña americana. ABSTRACT. Marcel Breuer, Hungarian architect and famed to furniture's designer of the Bauhaus emigrated to America in 1937, invited by Gropius as a professor at Harvard. Breuer and Gropius, there begin a new stage based on the experimentation of the house as a revision to the postulates of modern architecture: the house as a dwell machine proposed by Le Corbusier from old Europe; versus the humanization of the machine through the effect of material on the structure and form extended and in contact with the territory, proposed by Frank LI. Wright from the new America. His experiments on the house-cottage approached traditional methods of the American construction methods to a new vision, abstract and pure, where ways of life, and basic, practical and functional requirements became the connection to "Art of Building" trough the material and its placing. The search for a clear answer of dwelling that satisfied conflicting objectives and human needs, led to the architecture of abstraction to reconcile man with nature, endow it with life and art, an architecture and a landscape that became the modern ideals of American cottage.

COMUNICAÇÃO POPULAR-ALTERNATIVA DESENVOLVIDA POR JOVENS INDÍGENAS DAS ALDEIAS DO JAGUAPIRU E BORORÓ EM DOURADOS / MS

Trata-se de um estudo de caso em que analisamos a comunicação alternativa desenvolvida pela AJI (Ação dos Jovens Indígenas), em Dourados/MS, nas aldeias do Jaguapiru e Bororó. Os jovens, que produzem audiovisuais, fotografias, blog, fotolog e um jornal impresso, encontraram na comunicação uma alternativa ante à marginalidade com que os índios são tratados na cidade, e buscarem seus direitos à voz e ao espaço social, em suas próprias tribos, já que os jovens indígenas solteiros ocupam um não-lugar na Reserva, pois não pertencem à organização tradicional indígena, tampouco estão inseridos entre os brancos. A partir das características e limitações da comunicação alternativa no Jornal AJIndo, por meio de pesquisa bibliográfica, entrevistas semi-estruturadas e análise de conteúdo, buscamos verificar o impacto da utilização desta comunicação nas aldeias para os jovens que a produzem, levando em conta interferências nas formas tradicionais de hierarquia e comunicação entre os indígenas e a função social da comunicação alternativa para eles. Embora não seja o objetivo principal do AJIndo, destaca-se o desenvolvimento da auto-estima como resultado desse processo. Soma-se a esta função, a mobilização por transformação social e a formação crítico-educativa. Após o esforço de organização, os jovens começaram a se sentir pertencentes aos indígenas e a serem ouvidos pelos brancos, mesmo que acreditem ser por interesses políticos da comunidade como um todo.

COMUNICAÇÃO POPULAR-ALTERNATIVA DESENVOLVIDA POR JOVENS INDÍGENAS DAS ALDEIAS DO JAGUAPIRU E BORORÓ EM DOURADOS / MS

Trata-se de um estudo de caso em que analisamos a comunicação alternativa desenvolvida pela AJI (Ação dos Jovens Indígenas), em Dourados/MS, nas aldeias do Jaguapiru e Bororó. Os jovens, que produzem audiovisuais, fotografias, blog, fotolog e um jornal impresso, encontraram na comunicação uma alternativa ante à marginalidade com que os índios são tratados na cidade, e buscarem seus direitos à voz e ao espaço social, em suas próprias tribos, já que os jovens indígenas solteiros ocupam um não-lugar na Reserva, pois não pertencem à organização tradicional indígena, tampouco estão inseridos entre os brancos. A partir das características e limitações da comunicação alternativa no Jornal AJIndo, por meio de pesquisa bibliográfica, entrevistas semi-estruturadas e análise de conteúdo, buscamos verificar o impacto da utilização desta comunicação nas aldeias para os jovens que a produzem, levando em conta interferências nas formas tradicionais de hierarquia e comunicação entre os indígenas e a função social da comunicação alternativa para eles. Embora não seja o objetivo principal do AJIndo, destaca-se o desenvolvimento da auto-estima como resultado desse processo. Soma-se a esta função, a mobilização por transformação social e a formação crítico-educativa. Após o esforço de organização, os jovens começaram a se sentir pertencentes aos indígenas e a serem ouvidos pelos brancos, mesmo que acreditem ser por interesses políticos da comunidade como um todo.

Functional consequences of NR2 subunit composition in single recombinant N-methyl-d-aspartate receptors

Single-channel recordings were obtained from Chinese hamster ovary cells transfected with the N-methyl-d-aspartate (NMDA) receptor subunit NR1 in combination with NR2A, NR2B, NR2C, or NR2A/NR2B. NMDA-activated currents were recorded under control conditions and in the presence of a thiol reductant (DTT), an oxidant (5,5′-dithio-bis[2-nitrobenzoic acid], DTNB), or the noncompetitive antagonist CP101,606 (CP). For all subunit combinations, DTT increased the frequency of channel opening when compared with DTNB. In addition, channels obtained from NR1/NR2A-transfected cells also exhibited a pronounced difference in mean open dwell-time between redox conditions. CP dramatically reduced both the open dwell-time and frequency of channel opening of NR1/NR2B-containing receptors, but only modestly inhibited NR1/NR2A and NR1/NR2C channel activity. A small number of patches obtained from cells transfected with NR1/NR2A/NR2B had channels with properties intermediate to NR1/NR2A and NR1/NR2B receptors, including insensitivity to CP block but redox properties similar to NR1/NR2B, consistent with the coassembly of NR2A with NR2B. Hence, NMDA receptors containing multiple types of NR2 subunits can have functionally distinguishable attributes.

Bacteriophage lambda N protein alone can induce transcription antitermination in vitro.

Specific and processive antitermination by bacteriophage lambda N protein in vivo and in vitro requires the participation of a large number of Escherichia coli proteins (Nus factors), as well as an RNA hairpin (boxB) within the nut site of the nascent transcript. In this study we show that efficient, though nonprocessive, antitermination can be induced by large concentrations of N alone, even in the absence of a nut site. By adding back individual components of the system, we also show that N with nut+ nascent RNA is much more effective in antitermination than is N alone. This effect is abolished if N is competed away from the nut+ RNA by adding, in trans, an excess of boxB RNA. The addition of NusA makes antitermination by the N-nut+ complex yet more effective. This NusA-dependent increase in antitermination is lost when delta nut transcripts are used. These results suggest the formation of a specific boxB RNA-N-NusA complex within the transcription complex. By assuming an equilibrium model, we estimate a binding constant of 5 x 10(6) M-1 for the interaction of N alone with the transcription complex. This value can be used to estimate a characteristic dissociation time of N from the complex that is comparable to the dwell time of the complex at an average template position, thus explaining the nonprocessivity of the antitermination effect induced by N alone. On this basis, the effective dissociation rate of N should be approximately 1000-fold slower from the minimally processive (100-600 bp) N-NusA-nut+ transcription complex and approximately 10(5)-fold slower from the maximally processive (thousands of base pairs) complex containing all of the components of the in vivo N-dependent antitermination system.

Dionne Brand, Austin Clarke, and Tessa McWatt: Blackening Canada

This project analyzes contemporary black diasporic writing in Canada, arguing that Dionne Brand, Austin Clarke and Tessa McWatt evince a unique form of double-consciousness in their writings. Their work transforms African-American double-consciousness by locating it simultaneously within both the black diaspora and the practice of Canadian multiculturalism. The objective of this project is to offer a critical framework for situating these writers within the legacy of both Black Atlantic and Canadian cultural production. These writers do not aim to resolve their double-consciousness but rather dwell within that contradictory doubleness and hyphenation, forcing nation and diaspora to contend with one another in a discomfiting and unsettling dialogue. These authors employ the absences of the black diaspora to imagine new forms of black cultural production, multicultural citizenship and national identity. Their works produce a grammar of diasporic double-consciousness that locates the absented origins of diaspora within Canada. Brand’s depiction of temporality and Clarke’s tracing of movement explore the continuities between nation and diaspora while re-membering neglected aspects of the history of black Canada, such as the life and death of Albert Johnson. McWatt extends this blackening of nation by depicting coalitions between diasporic, indigenous, raced and sexed subjects. These authors transform hegemonic Canadian narratives of nation by dwelling in the hyphen, while their evocation of memory, absence, trauma, and desire gives blackness new meaning and legitimacy.

The EU Global Strategy: going beyond effective multilateralism? EPC Discussion Paper, June 2016

The ongoing consultation process on the European Union Global Strategy (EUGS) presents an occasion for the European Union (EU) to redress the European Security Strategy’s (ESS) shortcomings and update its stance on multilateralism. As rule-based multilateralism remains deeply entrenched in the Union’s DNA, the EUGS is unlikely to represent ground-breaking innovations as to how the EU should act in international affairs. The key challenge in respect of the EU’s multilateralism is twofold. The first challenge lies in setting out clear priorities for the EU’s multilateral action to be pursued collectively by the member states; and the second in determining the form of multilateralism that would best suit the promotion of the priorities concerned. In this collection of six essays, policy analysts and academics are presented with the question: Over a five year horizon, what do you think should be the focus of the EU’s multilateral agenda? The answers dwell on the EU playing a proactive role in relation to emerging powers especially China, and Latin America as a whole; furthering the EU’s soft power through ‘science diplomacy’; and EU leadership in building a global energy and climate community, and counter terrorism measures.