Radiolarian biostratigraphy of ODP Site 111-677

Well-preserved late Miocene through Pleistocene age radiolarian assemblages were recovered during ODP Leg 111 at Site 677, on the southern flank of the Costa Rica Rift in the eastern equatorial Pacific. Radiolarian "event" biostratigraphy (first and last morphotypic appearances) was established for Holes 677A and 677B using 21 species yielding 24 reliable datum levels. The cold upwelling waters above this site have prevented many typical tropical Pacific stratigraphic radiolarians from being useful age indicators. Biostratigraphic datum levels were assigned absolute ages based on previous work and were used to date the cores. Sedimentation rates varied from 3.7 cm/1000 yr in the late Pleistocene to 6.0 cm/1000 yr in the late Miocene. The age of the oldest sediments at this site is estimated as 5.89-6.37 Ma, which indicates that Site 677 is between magnetic anomalies 3A and 4. A total of 67 taxa were assessed for stratigraphic relevance at this site and are listed in the Appendix. One previously unknown Pliocene radiolarian stratigraphic indicator, Botryostrobus euporus (Ehrenberg), is identified.

Eolian deposition on the Ontong Java Plateau

The record of eolian deposition on the Ontong Java Plateau (OJP) since the Oligocene (approximately 33 Ma) has been investigated using dust grain size, dust flux, and dust mineralogy, with the goal of interpreting the paleoclimatology and paleometeorology of the western equatorial Pacific. Studies of modern dust dispersal in the Pacific have indicated that the equatorial regions receive contributions from both the Northern Hemisphere westerly winds and the equatorial easterlies; limited meteorological data suggest that low-altitude westerlies could also transport dust to OJP from proximal sources in the western Pacific. Previous studies have established the characteristics of the grain-size, flux, and mineralogy records of dust deposited in the North Pacific by the mid-latitude westerlies and in the eastern equatorial Pacific by the low-latitude easterlies since the Oligocene. By comparing the OJP records with the well-defined records of the mid-latitude westerlies and the low-latitude easterlies, the importance of multiple sources of dust to OJP can be recognized. OJP dust is composed of quartz, illite, kaolinite/chlorite, plagioclase feldspar, smectite, and heulandite. Mineral abundance profiles and principal components analysis (PCA) of the mineral abundance data have been used to identify assemblages of minerals that covary through all or part of the OJP record. Abundances of quartz, illite, and kaolinite/chlorite covary throughout the interval studied, defining a mineralogical assemblage supplied from Asia. Some plagioclase and smectite were also supplied as part of this assemblage during the late Miocene and Pliocene/Pleistocene, but other source areas have supplied significant amounts of plagioclase, smectite, and heulandite to OJP since the Oligocene. OJP dust is generally coarser than dust deposited by the Northern Hemisphere westerlies or the equatorial easterlies, and it accumulates more rapidly by 1-2 orders of magnitude. These relationships indicate the importance of the local sources on dust deposition at OJP. The grain-size and flux records of OJP dust do not exhibit most of the events observed in the corresponding records of the Northern Hemisphere westerlies or the equatorial easterlies, because these features are masked by the mixing of dust from several sources at OJP. The abundance record of the Asian dust assemblage at OJP, however, does contain most of the features characteristic of dust flux by means of the Northern Hemisphere westerlies, indicating that the paleoclimatic and paleometeorologic signal of a particular source area and wind system can be preserved in areas well beyond the region dominated by that source and those winds. Identifying such a signal requires "unmixing" the various dust assemblages, which can be accomplished by combining grain-size, flux, and mineralogic data.

Calcareous microfossil isotopes and Miocene datum events of ODP Holes 189-1170A and 189-1172A

Downcore oxygen and carbon stable isotope records of planktonic and benthic foraminifers and fine-fraction carbonate from the southern high latitudes provide critical paleohydrographic constraints on the evolution of the Southern Ocean climate. In particular, the potential effects of an intensified Antarctic Circumpolar Current on the thermal isolation and cooling of the southern high latitudes, production of cold deep waters, and, ultimately, accumulation of continental ice on Antarctica in the middle Miocene are matters of interest. Using sediment materials from Ocean Drilling Program Leg 189 Sites 1170 and 1172 off Tasmania, Ennyu and Arthur (2004, doi:10.1029/151GM13) established the surface- and deepwater stable isotope records in the Southern Ocean across the middle Miocene event of the east Antarctic ice sheet expansion and discussed the paleoclimate proxy records in terms of the thermal evolution of the southern high latitudes and its effect on deepwater circulation. This report provides data tables and other supporting information relevant to discussions presented in Ennyu and Arthur (2004, doi:10.1029/151GM13). Items included in this report are (1) the oxygen and carbon stable isotope data measured on the Miocene bulk fine-fraction (i.e., <63 µm, primarily polyspecific nannofossil assemblage) carbonate and planktonic and benthic foraminifers from Holes 1170A and 1172A and (2) the Miocene depth-age models for the two sites.

Calcareous nannofossil abundance and datums of ODP Holes 171B-1051A and 171B-1052A

During Ocean Drilling Program Leg 171B, a thick sequence of lower to middle Eocene sediments was recovered from Sites 1051 and 1052 at Blake Nose in the North Atlantic Ocean. Calcareous nannofossils are moderately well preserved in the upper to middle Eocene sediments but are moderate to poorly preserved in the lower Eocene sediments. Calcareous nannofossils are diverse throughout the recovered sequence, which extends from nannofossil Zone CP8 to Subzone CP15a. The nannofossil biostratigraphy of these sites indicates the presence of a hiatus in Subzone CP12a in the middle Eocene, in which the major nannofossil assemblage changes dramatically from Toweius to reticulofenestrid; however, no major change in the nannoflora was observed across the Eocene/Paleocene boundary. Coccolith size evolution patterns were recognized. Coccolithus, Reticulofenestra, and Cribrocentrum specimens may suggest a trend of increasing size upward through the sedimentary sequence, but Dictyococcites does not show a similar simple trend. Most traditional zonal markers are present. The reworking of Discoaster sublodoensis and overgrowth of Tribrachiatus in the lower Eocene makes zonal subdivision of this part of the sequence difficult. For this reason, tentative nannofossil zonation is given for the lower Eocene.

Stable and strontium isotope ratios and age determination of ODP Site 130-803

Stratigraphic information from strontium, oxygen, and carbon isotopic ratios has been integrated with diatom and planktonic foraminifer datums to refine the Oligocene to early Miocene chemostratigraphy of Site 803. The Sr isotope results are based on analyses of mixed species of planktonic foraminifer and bulk carbonate samples. 87Sr/86Sr ratios of bulk carbonate samples are, in most cases, less radiogenic than contemporaneous seawater. Estimated sediment ages based on planktonic foraminifer 87Sr/86Sr ratios, using the Sr-isotope-age relation determined by Hess and others in 1989, are in moderately good agreement with the biostratigraphic ages. Chronological resolution is significantly enhanced with the correlation of oxygen and carbon isotope records to those of the standard Oligocene section tied to the Geomagnetic Polarity Time Scale at Site 522. Ages revised by this method and other published ages of planktonic foraminifer datums are used to revise the Oligocene stratigraphy of Site 77 to correlate the stable isotope records of Sites 77 and 803. Comparison of the Cibicidoides stable isotope records of Sites 77 and 574 with paleodepths below 2500 m in the central equatorial Pacific, and Site 803 at about 2000-m paleodepth in the Ontong Java Plateau reveals inversions in the vertical d18O gradient at several times during the Oligocene and in the early Miocene. The shallower water site had significantly-higher d18O values than the deeper water sites after the earliest Oligocene 18O enrichment and before 34.5 Ma, in the late Oligocene from 27.5 to at least 25 Ma, and in the early Miocene from 22.5 to 20.5 Ma. It is not possible to ascertain if the d18O inversion persisted during the Oligocene/Miocene transition because the deeper sites have hiatuses spanning this interval. We interpret this pattern to reflect that waters at about 2000 m depth were cold and may have formed from mixing with colder waters originating in northern or southern high-latitude regions. The deeper water appear to have been warmer and may have been a mixture with warm saline waters from mid- or low-latitude regions. No apparent vertical d13C gradient is present during the Oligocene, suggesting that the age difference of these water masses was small.

Miocene strontium isotope record of DSDP Hole 30-289

A composite strontium isotopic seawater curve was constructed for the Miocene between 24 and 6 Ma by combining 87Sr/86Sr measurements of planktonic foraminifera from Deep Sea Drilling Project sites 289 and 588. Site 289, with its virtually continuous sedimentary record and high sedimentation rates (26 m/m.y.), was used for constructing the Oligocene to mid-Miocene part of the record, which included the calibration of 63 biostratigraphic datums to the Sr seawater curve using the timescale of Cande and Kent (1992 doi:10.1029/92JB01202). Across the Oligocene/Miocene boundary, a brief plateau occurred in the Sr seawater curve (87Sr/86Sr values averaged 0.70824) which is coincident with a carbon isotopic maximum (CM-O/M) from 24.3 to 22.6 Ma. During the early Miocene, the strontium isotopic curve was marked by a steep rise in 87Sr/86Sr that included a break in slope near 19 Ma. The rate of growth was about 60 ppm/m.y. between 22.5 and 19.0 Ma and increased to over 80 ppm/m.y. between 19.0 and 16 Ma. Beginning at ~16 Ma (between carbon isotopic maxima CM3 and CM4 of Woodruff and Savin (1991 doi:10.1029/91PA02561)), the rate of 87Sr/86Sr growth slowed and 87Sr/86Sr values were near constant from 15 to 13 Ma. After 13 Ma, growth in 87Sr/86Sr resumed and continued until ~9 Ma, when the rate of 87Sr/86Sr growth decreased to zero once again. The entire Miocene seawater curve can be described by a high-order function, and the first derivative (d87Sr/86Sr/dt) of this function reveals two periods of increased slope. The greatest rate of 87Sr/86Sr change occurred during the early Miocene between ~20 and 16 Ma, and a smaller, but distinct, period of increased slope also occurred during the late Miocene between ~12 and 9 Ma. These periods of steepened slope coincide with major phases of uplift and denudation of the Himalayan-Tibetan Plateau region, supporting previous interpretations that the primary control on seawater 87Sr/86Sr during the Miocene was related to the collision of India and Asia. The rapid increase in 87Sr/86Sr values during the early Miocene from 20 to 16 Ma imply high rates of chemical weathering and dissolved riverine fluxes to the oceans. In the absence of another source of CO2, these high rates of chemical weathering should have quickly resulted in a drawdown of atmospheric CO2 and climatic cooling through a reversed greenhouse effect. The paleoclimatic record, however, indicates a warming trend during the early Miocene, culminating in a climatic optimum between 17 and 14.5 Ma. We suggest that the high rates of chemical erosion and warm temperatures during the climatic optimum were caused by an increase in the contribution of volcanic CO2 from the eruption of the Columbia River Flood Basalts (CRFB) between 17 and 15 Ma. The decrease in the rate of CRFB eruptions at 15 Ma and the removal of atmospheric carbon dioxide by increased organic carbon burial in Monterey deposits eventually led to cooling and increased glaciation between ~14.5 and 13 Ma. The CRFB hypothesis helps to explain the significant time lag between the onset of increased rates of organic carbon burial in the Monterey at 17.5 Ma (as marked by increased delta13C values) and the climatic cooling and glaciation during the middle Miocene (as marked by the increase in delta18O values), which did not begin until ~14.5 Ma.

Age model and stable isotope record of DSDP holes 48-401 and 86-577

Early Paleogene warm climates may have been linked to different modes and sources of deepwater formation. Warm polar temperatures of the Paleocene and Eocene may have resulted from either increased atmospheric trace gases or increased heat transport through deep and intermediate waters. The possibility of increasing ocean heat transport through the production of warm saline deep waters (WSDW) in the Tethyan region has generated considerable interest. In addition, General Circulation Model results indicate that deepwater source regions may be highly sensitive to changing basin configurations. To decipher deepwater changes, we examined detailed benthic foraminiferal faunal and isotopic records of the late Paleocene through the early Eocene (~60 to 50 Ma) from two critical regions: the North Atlantic (Bay of Biscay Site 401) and the Pacific (Shatsky Rise Site 577). These records are compared with published data from the Southern Ocean (Maud Rise Site 690, Islas Orcadas Rise Site 702). During the late Paleocene, similar benthic foraminiferal delta18O values were recorded at all four sites. This indicates uniform deepwater temperatures, consistent with a single source of deep water. The highest delta13C values were recorded in the Southern Ocean and were 0.5 per mil more positive than those of the Pacific. We infer that the Southern Ocean was proximal to a source of nutrient-depleted deep water during the late Paleocene. Upper Paleocene Reflector Ab was cut on the western Bermuda Rise by cyclonically circulating bottom water, also suggesting a vigorous source of bottom water in the Southern Ocean. A dramatic negative excursion in both carbon and oxygen isotopes occurred in the latest Paleocene in the Southern Ocean. This is a short-term (<100 kyr), globally synchronous event which also is apparent in both the Atlantic and Pacific records as a carbon isotopic excursion of approximately 1 per mil. Faunal analyses from the North Atlantic and Pacific sites indicate that the largest benthic foraminiferal faunal turnover of the Cenozoic was synchronous with the isotopic excursion, lending support to the hypothesis that the extinctions were caused by a change in deepwater circulation. We speculate that the Southern Ocean deepwater source was reduced or eliminated at the time of the excursion. During the early Eocene, Southern Ocean delta13C values remained enriched relative to the North Atlantic and Pacific. However, the Southern Ocean was also enriched in delta18O relative to these basins. We interpret that these patterns indicate that although the Southern Ocean was proximal to a source of cool, nutrient-depleted water, the intermediate to upper deep water sites of the North Atlantic and Pacific were ventilated by a different source that probably originated in low latitudes, i.e., WSDW.

Biogenic and terrigeneous components in Pliocene-Pleistocene sediments of the equatorial Atlantic

High-resolution analyses of sediments at equatorial Atlantic Sites 662, 663, and 664 define the accumulation rates of biogenically produced CaC03 and opal and of eolian dust from North Africa over the last 3.7 m.y. The mean flux of opal increased abruptly by 60%-70% near 2.5 Ma (2.65 to 2.3 Ma), reflecting pulses of increased opal productivity along the equator due mainly to increased upwelling. The mean winter-plume dust influx from Sahelian and Saharan Africa also increased at this time by between 35% and 75%, following smaller increases earlier in the late Pliocene. The increased opal flux implies a stronger zonal component of the southern trade winds in Southern Hemisphere winter. Consistent with this wind configuration, the stronger dust flux suggests a weaker southwesterly monsoonal flow into Africa in Northern Hemisphere summer, thus increasing Sahelian aridity and winter-plume dust fluxes. Dust fluxes to the equator may possibly have also been enhanced by stronger Northern Hemisphere winter trade winds and a more southerly position of the Intertropical Convergence Zone over Africa. These late Pliocene biogenic and terrigenous flux changes coincided with the appearance of Northern Hemisphere ice sheets, implying an ultimate causal link. The immediate control on changes in tropical circulation may, however, have been changes in the Atlantic sector of the Southern Ocean. A steady background trend of increasing winter-plume dust flux occurred from the late Pliocene until the middle Pleistocene. This may reflect a progressive, tectonically induced aridification of northern and eastern Africa because of the gradual uplift of the Tibetan Plateau.

Neodymium isotope record of ODP Site 177-1090

Age estimates for the opening of Drake Passage range from 49 to 17 million years ago (Ma), complicating interpretations of the relationship between ocean circulation and global cooling. Secular variations of neodymium isotope ratios at Agulhas Ridge (Southern Ocean, Atlantic sector) suggest an influx of shallow Pacific seawater approximately 41 Ma. The timing of this connection and the subsequent deepening of the passage coincide with increased biological productivity and abrupt climate reversals. Circulation/productivity linkages are proposed as a mechanism for declining atmospheric carbon dioxide. These results also indicate that Drake Passage opened before the Tasmanian Gateway, implying the late Eocene establishment of a complete circum-Antarctic pathway.

Stable isotope and Mg/Ca ratios of Paleogene benthic foraminifera in the western North Atlantic

Global cooling and the development of continental-scale Antarctic glaciation occurred in the late middle Eocene to early Oligocene (~38 to 28 million years ago), accompanied by deep-ocean reorganization attributed to gradual Antarctic Circumpolar Current (ACC) development. Our benthic foraminiferal stable isotope comparisons show that a large d13C offset developed between mid-depth (~600 meters) and deep (>1000 meters) western North Atlantic waters in the early Oligocene, indicating the development of intermediate-depth d13C and O2 minima closely linked in the modern ocean to northward incursion of Antarctic Intermediate Water. At the same time, the ocean's coldest waters became restricted to south of the ACC, probably forming a bottom-ocean layer, as in the modern ocean. We show that the modern four-layer ocean structure (surface, intermediate, deep, and bottom waters) developed during the early Oligocene as a consequence of the ACC.

Geochemical and Nd isotopic investigations of sediments from the South China Sea

Secular variations in geochemistry and Nd isotopic data have been documented in sediment samples at ODP Site 1148 in the South China Sea. Major and trace elements show significant changes at ca. 29.5 Ma and 26-23 Ma, whereas epsilon-Nd values show a single change at ca. 26-23 Ma. Increases in Al/Ti, Al/K, Rb/Sr, and La/Lu ratios and a decrease in the Th/La ratio of the sediments beginning at 29.5 Ma are consistent with more intense chemical weathering in the source region. The abrupt change in Nd isotopes and geochemistry at ca. 26-23 Ma coincides with a major discontinuity in the sedimentology and physical properties of the sediments, implying a drastic change in sedimentary provenance and environment at the drill site. Comparison of the Nd isotopes of sediments from major rivers flowing into the South China Sea suggests that pre-27 Ma sediments were dominantly derived from a southwestern provenance (Indochina-Sunda Shelf and possibly northwestern Borneo), whereas post-23 Ma sediments were derived from a northern provenance (South China). This change in provenance from southwest to north was largely caused by ridge jumping during seafloor spreading of the South China Sea, associated with a southwestward expansion of the ocean basin crust and a global rise in sea level. Thus, the geochemical and Nd isotopic changes in the sediments at ODP Site 1148 are interpreted as a response to a major plate reorganization in SE Asia at ca. 25 Ma.

Carbonate composition of Pliocene-Pleistocene sediments of the Maledives

Ocean Drilling Program (ODP) Leg 115 post-cruise research was focused on two Maldives sites, more precisely on the top 108 m of Hole 716B (water depth, 540 m), equivalent to the past 3.5 m.y., and the top 19.5 m of Hole 714A (water depth, 2195 m), equivalent to the past 0.55 m.y. These sediments consist of mostly unaltered and undisturbed, turbidite-free, periplatform ooze. Results of our research are compared with existing data on Hole 633A (water depth, 1681 m), drilled in the Bahamas during ODP Leg 101, using age/depth models built on the basis of oxygen isotope, nannofossil, and magnetic stratigraphies. Climate-induced, long-term (roughly 0.5 m.y.) aragonite cycles, superposed on short-term (roughly 0.04 and 0.1 m.y.) aragonite cycles, have been established at least during the past 2.0 m.y., in the Maldives and the Bahamas. Our most interesting result is the clear correlation among the aragonite long-term cycles in the Maldives and the Bahamas and the carbonate-preservation, long-term cycles from the open Pacific, Indian, and North Atlantic oceans. The mid-Brunhes dissolution interval, corresponding to the youngest preservation minima of the carbonate-preservation, longterm cycles, is clearly defined by fine aragonite minimum values in the deep periplatform sites, and by maximum fragmentation of pteropod tests in the shallow sites. Aragonite and planktonic d18O records, usually in phase during the late Pleistocene, display, further back in time, discreet intervals where the two records do not match with one another. Major mismatches between both records occur synchronously in the Maldives and Bahamas periplatform sites and seem to correspond to extreme events of either carbonate-preservation or dissolution in the deep pelagic carbonate sites of the equatorial Pacific Ocean. Based on our findings, short- and long-term aragonite cycles can no longer be explained only by variations of aragonite input from the nearby shallow carbonate banks, in response to their alternate flooding and exposure through cyclic sea-level fluctuations. The aragonite long-term cycles in the periplatform environments are interpreted as carbonatepreservation cycles at intermediate-water depths. Their occurrence shows, therefore, that the carbonate chemistry of the entire water column has been influenced by long-term (0.5 m.y.) cyclic variations during the past 2.0 m.y. These major changes of the water-column carbonate chemistry are linked to the climate-induced carbon cycling among the different atmospheric, oceanic, and sedimentary carbon reservoirs.

Calcareous nannofossils across the Eocene-Oligocene boundary

This work presents the stratigraphic distribution of several species of calcareous nannofossil in the middle Eocene early-Oligocene from four Ocean Drilling Program (ODP) sites located between 60° and 65°S paleolatitude in the Southern Atlantic and Indian Oceans. Useful nannofossil datums that should facilitate construction of age-models and contribute to an integrated chronology for the upper Paleogene Southern Ocean sediments from ~42 to 33 Ma are summarized. The distribution patterns of calcareous nannofossils, studied by means of quantitative and semiquantitative methods, provide an improvement of the classical Southern Ocean biozonations, introducing new biostratigraphically useful biohorizons, and testing their reproducibility within and outside the region.

The Paleocene-Eocene boundary in ODP Leg 208 sites

The Paleocene-Eocene thermal maximum (PETM) has been attributed to the rapid release of ~2000 * 10**9 metric tons of carbon in the form of methane. In theory, oxidation and ocean absorption of this carbon should have lowerd deep-sea pH, thereby triggering a rapid (<10,000-year) shoaling of the calcite compensation depth (CCD), followed by gradual recovery. Here we present geochemical data from five new South Atlantic deep-sea sections that constrain the timing and extent of massive sea-floor carbonate dissolution coincident with the PETM. The sections, from between 2.7 and 4.8 kilometers water depth, are marked by a prominent clay layer, the character of which indicates that the CCD shoaled rapidly (<10,000 years) by more than 2 kilometers and recovered gradually (>100,000 years). These findings indicate that a large mass of carbon (>>2000 * 10**9 metric tons of carbon) dissolved in the ocean at the Paleocene-Eocene boundary and that permanent sequestration of this carbon occurred through silicate weathering feedback.

Ages at DSDP Site 86-577

A synthesis of paleomagnetic and calcareous nannofossil stratigraphies for the sedimentary sequences recovered at Deep Sea Drilling Project (DSDP) Site 577 on the Shatsky Rise is presented. Numerical ages are estimated for a series of nannofossil datum levels from the late Maestrichtian to middle Eocene period ( about 68 to about 52 m.y. ago) and the late Cenozoic (last about 5 m.y.). Absolute age control is obtained on the basis of the revised geomagnetic polarity time scale of. The results are compared with various sets of data reported in the literature, in particular to magnetobiochronologies derived from marine sections accessible on land in Italy and from recent DSDP boreholes in the South Atlantic, and with the summary by Berggren et al. Although a number of minor discrepancies remain to be resolved, the remarkable general agreement of the data validates the basic concept of this approach to the elaboration of a calibrated geologic time scale.