Studies of the voltammetric behavior and determination of diazo reactive dyes at mercury electrode

The electrochemical reduction of two reactive dyes: Procion Red HE-3B 9 (RR120) and Procion Green HE-4BD (RG19) was investigated using cyclic voltammetry, differential pulse and DC, polarography, chronoamperometry and controlled potential electrolysis at mercury electrodes. The bis-azo groups of the RR120 dye are reduced together in one single step of four electrons, the bis-azo groups of the RG19 dye are reduced in two steps owing to the difference in the electron densities promoted by the different substituents in the benzene rings adjacent to the azo groups. The bis-monochlorotriazine reactive groups in both dyes are reduced only in acidic medium in their protonated form, leading to the reduction of the triazine groups. The reduction mechanism of both reactive dyes is discussed. Both dyes can be quantified in aqueous medium by differential pulse polarography in the concentration range of 1 x 10(-7) mol L-1 to 1 x 10(-5) mol L-1 by monitoring the reduction of the chromophore group or the reactive group.

Nuclear phenotypes and morphometry of human secretory prostate cells: A comparative study of benign and malignant lesions in Brazilian patients

Prostatic lesions in Brazilian patients with benign prostatic hyperplasia (BPH, 26 cases) or adenocarcinoma (AC, 25 cases) were compared by qualitative microscopy and morphometric analysis. In 12 cases of BPH, prostate regions with no histological alterations were considered as controls (Ct). Archival material consisted of formalin-fixed, paraffin-embedded specimens obtained from prostatic transurethral resection and radical prostatectomy. Haematoxylin/eosin (HE)-stained sections were used to estimate the nuclear areas, perimeters and form factor values. HE-stained sections from AC specimens were also used for Gleason grading. BPH, AC and Ct could be discriminated by their nuclear areas and nuclear perimeters, but not by the nuclear form factor parameter. No significant differences were found when the AC data were compared using the combined version or the predominant grade version of the Gleason score (p = 0.8380 for nuclear area; p = 0.6076 for nuclear perimeter; p = 0.9202 for nuclear form factor; n = 200 nuclei per patient). This finding indicates that there is extensive heterogeneity in the size and shape of the nucleus in AC cells. These results also show that although the nuclear morphometry served to discriminate BPH and AC from each other and from Ct, it was not sufficient to correlate AC lesions with their respective Gleason scores in the human population analyzed.

Conversor CA-CA de elevado fator de potência para aplicações com geradores de Ímã permanente

This paper proposes and describes a high power factor AC-AC converter for naval applications using Permanent Magnet Generator (PMG). The three-phase output voltages of the PMG vary from 260 Vrms (220 Hz) to 380 Vrms (360 Hz), depending on load conditions. The proposed converter consists of a Y-/ΔY power transformer, which provides electrical isolation between the PMG and remaining stages, and a twelve-pulse uncontrolled rectifier stage directly connected to a single-phase inverter stage, without the use of an intermediary DC-DC topology. This proposal results in more simplicity for the overall circuitry, assuring robustness, reliability and reduced costs. Furthermore, the multipulse rectifier stage is capable to provide high power factor and low total harmonic distortion for the input currents of the converter. The single-phase inverter stage was designed to operate with wide range of DC bus voltage, maintaining 120 Vrms, 60 Hz output. The control philosophy, implemented in a digital signal processor (DSP) which also contains protection routines, alows series connections between two identical converters, achieving 240 Vrms, 60 Hz total output voltage. Measured total harmonic distortion for the AC output voltage is lower than 2% and the input power factor is 0.93 at 3.6kW nominal load. © 2010 IEEE.

Foetal echoencephalography and Doppler ultrasonography of the middle cerebral artery in canine foetuses

Objectives: This study aimed to evaluate the characteristics of the brain and vascular indicesof the middle cerebral artery of canine foetuses. Methods: Twenty-five bitches were selected. Tissue development, echogenicity, echotexture and brain echobiometric data were studied, and the major structures were identified between the 5th and 8th gestational weeks. The area and volume of the brain mass (BMA and BMV), cranial area and volume (AC and VC), brain mass index (BMI) and brain volume index (BVI) were determined. A single ultrasound examination was performed during each studied week (6th, 7th and 8th). Doppler ultrasonography was performed to assess the maximum and minimum velocity, resistance and pulsatility index of middle cerebral artery of the foetuses. Results: Echoencephalography was performed to evaluate the morphological characteristics of the central nervous system. Cerebral echobiometry indicated an increase in area and volume of the hemispheres and cranium (P<0·001) but no changes in BMI or BVI over the gestational period studied. Doppler ultrasonography identified increases in peak systolic velocity (P=0·0188) and end diastolic velocity (P=0·0274) and decreases in resistance index (P=0·0002) and pulsatility index (P<0·001). Clinical Significance: Echoencephalography and spectral Doppler ultrasonography of the middle cerebral artery in canine foetuses might be a useful technique for prenatal care. © 2013 British Small Animal Veterinary Association.

Célula de comutação de três estados aplicada ao pré-regulador boost de estágio único e elevado fator de potência

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo da hidrólise enzimática do amido de mandioquinha-salsa (Arracacia xanthorrhiza): efeito do tamanho dos grânulos

Pós-graduação em Engenharia e Ciência de Alimentos - IBILCE

Retificador entrelaçado boost, no modo de condução descontínua, com técnica de correção da corrente de entrada e elevado fator de potência, para aplicação em sistema trólebus

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Caracterização do pescador e da frota pesqueira comercial de Manoel Urbano e Sena Madureira (AC) e Boca do Acre (AM)

Vários estudos sobre o setor pesqueiro têm sido feitos na região amazônica, entretanto, a maior parte se concentra em regiões próximas à calha do rio do Amazonas e sua foz. Este trabalho foi voltado para caracterização da pesca no rio Purus, frota pesqueira comercial e do pescador em três municípios pesquisados nas margens desse rio, estimando, assim, a produção e a renda da frota pesqueira naquela região. Os resultados mostram que em Manoel Urbano (AC) predomina a pesca de lagos, enquanto que Sena Madureira (AC) os ambientes de pesca são mais diversificados, com registros de pesca em lagos, rios e igarapés. Em Boca do Acre (AM) prevalece a pesca no rio Purus, principalmente na área dos municípios de Pauiní e Lábrea. Quanto ao tipo de embarcação utilizada, em Manoel Urbano a pesca é praticada somente em canoas, sendo que um pequeno percentual corresponde a canoas sem motor, enquanto que em Sena Madureira a maioria dos pescadores pesca de canoas e alguns utilizam barco motor; já em Boca do Acre a pesca é praticada basicamente de barcos, sendo menor o número de canoas motorizadas. Em relação aos custos da viagem, a análise mostrou que os custos variáveis representam 63% da receita dos pescadores de canoa e 76% da receita total dos barcos de pesca. A análise também mostra que pescadores de canoa motorizada apresentaram maior capacidade produtiva por unidade de esforço em relação aos pescadores de barcos.

Relações de equivalência após treino com pareamento consistente de estímulos sob controle contextual

Alguns estudos têm produzido relações condicionais que se mostraram também equivalentes, através do treino com pareamento consistente de estímulos. O presente estudo buscou verificar se essas relações podem ocorrer também sob controle contextual. Quatro universitários foram submetidos ao treino AB, AC e AD, intercalado aos testes de simetria correspondentes BA, CA e DA. Em seguida, ao treino AD e ao teste de simetria DA sob controle contextual. Por último, foram testadas as relações de equivalência BC, CB, BD, DB, CD e DC, na ausência de estímulos contextuais, e DB e DC, com estímulos de contexto. Os participantes alcançaram o critério de acerto em todos os treinos. Três participantes apresentaram as relações simétricas, na ausência de estímulos contextuais, e a relação DA, em sua presença. Estes resultados replicam e expandem estudos anteriores, mostrando que mesmo sem conseqüências diferenciais, é possível obter um desempenho consistente sob controle condicional de segunda ordem.

Glutamina mais ácido glutâmico e aditivos fitogênicos nas dietas de frangos de corte criados no sistema alternativo de produção

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Phytogenic additives and glutamine plus glutamic acid in broiler diets

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Caracterização do compósito obtido a partir de borracha natural com negro e resíduos de couro aplicado como pisos e revestimentos

Pós-graduação em Ciência e Tecnologia de Materiais - FC

M-CSF Priming of Osteoclast Precursors Can Cause Osteoclastogenesis-Insensitivity, Which Can be Prevented and Overcome on Bone

Osteoclasts and macrophages share progenitors that must receive decisive lineage signals driving them into their respective differentiation routes. Macrophage colony stimulation factor M-CSF is a common factor; bone is likely the stimulus for osteoclast differentiation. To elucidate the effect of both, shared mouse bone marrow precursor myeloid blast was pre-cultured with M-CSF on plastic and on bone. M-CSF priming prior to stimulation with M-CSF and osteoclast differentiation factor RANKL resulted in a complete loss of osteoclastogenic potential without bone. Such M-CSF primed cells expressed the receptor RANK, but lacked the crucial osteoclastogenic transcription factor NFATc1. This coincided with a steeply decreased expression of osteoclast genes TRACP and DC-STAMP, but an increased expression of the macrophage markers F4/80 and CD11b. Compellingly, M-CSF priming on bone accelerated the osteoclastogenic potential: M-CSF primed cells that had received only one day M-CSF and RANKL and were grown on bone already expressed an array of genes that are associated with osteoclast differentiation and these cells differentiated into osteoclasts within 2 days. Osteoclastogenesis-insensitive precursors grown in the absence of bone regained their osteoclastogenic potential when transferred to bone. This implies that adhesion to bone dictates the fate of osteoclast precursors. Common macrophage-osteoclast precursors may become insensitive to differentiate into osteoclasts and regain osteoclastogenesis when bound to bone or when in the vicinity of bone. J. Cell. Physiol. 229: 210-225, 2014. (c) 2014 Wiley Periodicals, Inc.

Study of MDM2 and SUMO-1 expression in actinic cheilitis and lip cancer

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Implementação de microrredes residenciais em corrente contínua através da microgeração

This paper discusses the importance of energy efficiency and the use of alternative energy sources, facing to the increasing energy demand and the concomitant economic, social and environmental restrictions imposed by society. In this work, alternative sources are illustrated by photovoltaic, micro turbines and fuel cells microgeneration systems. Energy efficiency is presented by direct current microgrids because its uses excludes the conversions of direct current (DC) to alternating current (AC) losses made with the intention of injecting energy into the electric grid and then the inverse conversion, AC to DC, in order to feed residential loads. The object of this paper is to analyze a case study and evaluates the costs and technical feasibility of a Project that combines a DC microgrid and a microgeneration system