钠离子与电子复合电离动力学的激波管研究

利用反射激波加热使试验气体电离,继之以强稀波快速冷却,构成一种新的激波管方法,并测定了在氩气氛中钠离子与电子三体复合速率系数。由于稀疏波冷却速度达10~6K/s,电离过程处于非平衡状态。选用氨基钠作为向实验体系中引入钠离子的源物质。用压电传感器和Langmuir静电探针分别监测反射激波后5区压力和离子浓度变化。稀疏波的冷却过程被视为绝热的。分析了探针工作状态,引入了探针鞘层内的弹性散射修正。测定了在800~2 600K温度范围内以惰性气体氩为碰撞第三体的钠离子与电子离复合速率系数k_r=3.43×10~(-14)T~(-3.77)cm~6s~(-1)。

In Situ Synthesis of Nanocrystalline Intermetallic Compound Layer During Surface Mechanical Attrition Treatment of Zirconium

The surface mechanical attrition treatment (SMAT) technique was developed to synthesize a nanocrystalline (NC) layer on the surface of metallic materials for upgrading their overall properties and performance. In this paper, by means of SMAT to a pure zirconium plate at the room temperature, repetitive multidirectional peening of steel shots (composition (wt%): 1C, 1.5Cr, base Fe) severely deformed the surface layer. A NC surface layer consisting of the intermetallic compound FeCr was fabricated on the surface of the zirconium. The microstructure characterization of the surface layer was performed by using X-ray diffraction analysis, optical microscopy, scanning and transmission electron microscopy observations. The NC surface layer was about 25 mu m thick and consisted of the intermetallic compound FeCr with an average grain size of 25 +/- 10 nm. The deformation-induced fast diffusion of Fe and Cr from the steel shots into Zr occurred during SMAT, leading to the formation of intermetallic compound. In addition, the NC surface layer exhibited an ultrahigh nanohardness of 10.2 GPa.