Geochemistry of ODP Site 162-907, North Atlantic

A geochemical analysis is conducted on hemipelagic sediments at ODP Leg 162, Site 907, North Atlantic. On the basis of major and minor element concentrations, the sequence is divided into five units. Geochemical data reveal that the sediments originated from two specific source areas, i.e., continental icerafted debris (IRD) and Icelandic basalt. In the upper part (lithological units I and II, 0 to 63.1 meters below sea floor (mbsf)), sediments were derived from continental IRD, whereas in the lower part, sediments (lithological units III, IV, and V, below 63.1 mbsf) comprise mixture of continental IRD and minor supply from the Icelandic basalt. The ratio of TiO2/Al2O3 to SiO2 content and the Th to Ti/Al molar ratio clearly provide a key to discriminate provenances. The change in source area is most likely related to the oceanographic and climatic evolution in the North Atlantic since the middle Miocene. Biogenic fossil-barren intervals (Units II and V) are considered as a consequence of dissolution caused by oceanic circulation. The timing of IRD initiation confers with that of geochemical analysis. Total organic carbon to total nitrogen (C/N) ratio shows a striking variation in the entire core. The C/N ratios exceed 10 below approximately 196 mbsf (lithological unit V) with a gradual downward increase. This suggests that terrigenous organic matters have been supplied from the neighboring continents. The total organic carbon to total sulfur (C/S) ratio also shows such possibility as well as diagenetic changes in Units IV and V. The carbonate-barren intervals presented in Units II and V, and intermittently in Units III and IV are interpreted as a consequence of dissolution effect related with climatic variation and deep-water circulation. Additional low surface productivity was considerable.

(Table 1) Strontium isotope ratios (87Sr/86Sr) of Neogloboquadrina pachyderma (sinistrally coiling) tests from ODP Hole 151-910A

The sediment sequence at Ocean Drilling Program (ODP) Site 910 (556 m water depth) on the Yermak Plateau in the Arctic Ocean features a remarkable "overconsolidated section" from ~19 to 70-95 m below sea floor (m bsf), marked by large increases in bulk density and sediment strength. The ODP Leg 151 Shipboard Scientific Party interpreted the overconsolidated section to be caused by (1) grounding of a marine-based ice sheet, derived from Svalbard and perhaps the Barents Sea ice sheet, and/or (2) coarser-grained glacial sedimentation, which allowed increased compaction. Here I present planktonic foraminiferal d18O data based on Neogloboquadrina pachyderma (sinistrally coiling) that date the termination of overconsolidation near the boundary between isotope stages 16 and 17 (ca. 660 ka). No evidence is found for coarser grained sedimentation, because lithic fragments >150 µm exhibit similar mean concentrations throughout the upper 24.5 m bsf. The overconsolidated section may reflect more extensive ice-sheet grounding prior to ca. 660 ka, suggesting a major change in state of the Svalbard ice sheets during the mid-Quaternary. Furthermore, continuous sedimentation since that time argues against a pervasive Arctic ice shelf impinged on the Yermak Plateau during the past 660 k.y. These findings suggest that Svalbard ice-sheet history was largely independent of circum-Arctic ice-sheet history during the middle to late Quaternary.