Stable isotopic record of late Pliocene and Pleistocene foraminifera of ODP Site 114-704

We studied the stable isotopic and carbonate stratigraphy of ODP Hole 704A to reconstruct the paleoceanographic evolution of the eastern subantarctic sector of the South Atlantic Ocean. Site 704 is well positioned with respect to latitude (46°52.8'S, 7°25.3'E) and bathymetry (2532 m) to monitor past migrations in the position of Polar Front Zone (PFZ) and changes in deep-water circulation during the late Pliocene-Pleistocene. Several important changes occurred in proxy paleoceanographic indicators across the Gauss/Matuyama boundary at 2.47 Ma: (1) accumulation rates of biogenic sedimentary components increased by an order of magnitude (Froelich et al., this volume); (2) planktonic d1 8O values increased by an average of 0.5 per mil; (3) the amplitude of the benthic d18O signal increased; (4) the accumulation rate of ice-rafted detritus increased several fold (Warnke and Allen, this volume); and (5) carbon isotopic ratios of benthic foraminifers decreased by 0.5 per mil, as did the d13C of the fine-fraction carbonate by 1.5 per mil (Mead et al., 1991, doi:10.2973/odp.proc.sr.114.152.1991), but no change occurred in planktonic foraminiferal d13C values. Most of these changes are consistent with more frequent expansions and contractions of the PFZ over Site 704 after 2.47 Ma, bringing cold, nutrient-rich waters to 47°S that stimulated both carbonate and siliceous productivity. The synchronous increase in d18O values and ice-rafted detritus accumulation in Hole 704A indicates that the 2.4 Ma paleoceanographic event included ice volume growth on both Antarctica and Northern Hemisphere continents. The decrease in benthic d13C values indicates that the ventilation rate of Southern Ocean deep water decreased and the nutrient content increased during glacial events after 2.5 Ma. At the Gauss/Matuyama boundary, benthic d13C values of the Southern Ocean shifted toward those of the Pacific end member, indicating a decrease in the relative mixing ratio of Northern Component Water and Circumpolar Deep Water. During the early Matuyama (~2.3 to 1.7 Ma), the PFZ generally occupied a southerly position with respect to Site 704 and carbonate productivity prevailed. Exceptions to these general conditions occurred during strong glacial events of the early Matuyama (e.g., isotopic stages 82, 78, 74, and 70), when the PFZ migrated to the north and opal sedimentation predominated at Site 704. At 1.7 Ma, the PFZ migrated toward the equator and occupied a more northerly position for a prolonged interval between ~1.7 and 1.5 Ma. Beginning at ~1.5-1.4 Ma, surface and bottom water parameters (d18O, d13C, %CaCO3, and %opal) in the subantarctic South Atlantic became highly correlated such that glacial events (d18O maxima) corresponded to d13C and carbonate minima and opal maxima. This pattern is typical of the correlation found during the latest Pleistocene in the Southern Ocean (Charles and Fairbanks, in press). This event coincided with increased suppression of Northern Component Water during glacial events after 1.5 Ma (Raymo et al., 1990, doi:10.1016/0012-821X(90)90051-X), which may have influenced the climatology of the Southern Hemisphere by altering the flux of heat and salt to the Southern Ocean).

Census of calcareous nannofossil taxa expressed as percent of total number of individuals counted, ODP Legs 113, 114, 119, 120

Quantitative analysis of upper Eocene-upper Oligocene calcareous nannofossil assemblages from five Ocean Drilling Program sites in the Atlantic and Indian Ocean sectors of the Southern Ocean reveals an abrupt increase in cool-water taxa at the top of magnetic Subchron C13R ca. 35.9 Ma, coincident with an enrichment of ~1? d18O in the planktonic foraminifers at these sites. The synchrony of the abrupt increase in cool-water taxa in the Southern Ocean renders this event a useful biostratigraphic datum at southern high latitudes. This earliest Oligocene cool-water taxa increase was the sharpest and largest during the late Eocene-late Oligocene interval and indicates a drop in surface-water temperature of more than 3°C in the Southern Ocean. This suggests that the earliest Oligocene d18O shift represents primarily a temperature signal; a small portion (~0.2?) is attributable to a global ice-volume increase.

Biogenic opal and carbonate concentration in late Neogene sediments of ODP Site 114-704

A preliminary composite depth section was generated for Site 704 by splicing Holes 704A and 704B together over the interval 0-350 mbsf (0-9 m.y.). High-resolution carbonate and opal data from the cores were correlated with the calcium and silicon signals from the GST logging run in Hole 704B to identify missing and disturbed intervals in the cores. Paleomagnetic and biostratigraphic age boundaries were then transferred to the composite depth records to obtain an age model, and sedimentation rates were calculated by linear interpolation between datums. Algorithms relating measured dry-bulk density to carbonate content and depth were generated to produce predicted values of density for every sample. Accumulation rates of bulk, carbonate, opal, and terrigenous sediment components were then computed to generate a record of sediment deposition on the Meteor Rise that has a resolution of better than 200,000 yr for the period from 8.6 to 1.0 m.y. From 8.6 to 2.5 m.y., bulk-accumulation rates on the Meteor Rise averaged less than 2 g/cm**2/1000 yr and were dominated by carbonate deposition. The first significant opal deposition (6.0 m.y.) punctuated a brief (less than 0.6 Ma) approach of the Polar Front Zone (PFZ) northward that heralded a period of increasing severity of periodic carbonate dissolution events (terrigenous maxima) that abruptly terminated at 4.8 m.y. (base of the Thvera Subchron), synchronous with the reflooding of the Mediterranean after the Messinian salinity crisis. From 4.8 to 2.5 m.y., carbonate again dominated deposition, and the PFZ was far south except during brief northward excursions bracketing 4.2-3.9, 3.3-2.9, and 2.8-2.7 m.y. At 2.5 m.y., all components of bulk-accumulation rates increased dramatically (up to 15 g/cm2/1000 yr), and by 2.4 m.y., a pattern of alternating, high-amplitude carbonate and opal cyclicity marked the initiation of rapid glacial to interglaci·l swings in the position of the PFZ, synchronous with the "onset" of major Northern Hemisphere glaciation. Both mass-accumulation rates and the amplitude of the cycles decreased by about 2 m.y., but opal accumulation rates remained high up through the base of the Jaramillo (0.98 m.y.). From 1.9 to 1 m.y., the record is characterized by moderate amplitude fluctuations in carbonate and opal. This record of opal accumulation rates is interpreted as a long-term "Polar Front Indicator" that monitors the advance and retreat of the opal-rich PFZ northward (southward) toward (away from) the Meteor Rise in the subantarctic sector of the South Atlantic Ocean. The timing of PFZ migrations in the subantarctic South Atlantic Ocean is remarkably similar to Pliocene-Pleistocene climate records deduced from benthic oxygen isotope records in the North Atlantic Ocean (Raymo et al., 1989, doi:10.1029/PA004i004p00413; Ruddiman et al., 1989, doi:10.1029/PA004i004p00353). These include northward migrations during "cold" intervals containing strong glacial isotope stages (2.4-2.3, 2.1-2.0, 1.95-1.55, 1.45-1.30 m.y. and at about 1.13 and 1.09 m.y.) and southward migrations during "warm" intervals containing weak glacial and/or strong interglacial stages (2.45-2.40, 2.30-2.10, 2.00-1.95, 1.52-1.45, 1.30-1.18, 1.11, and 1.06-0.93 m.y.). Although our preliminary composite record is not continuous (some stages are obviously missing), there is hope that future work will identify these missing intervals in the as yet incomplete Hole 704B and will extend this high-resolution Southern Hemisphere climate record back to 8.6 m.y.