Space-selective co-precipitation of silver and gold nanoparticles in femtosecond laser pulses irradiated Ag+, Au3+ co-doped silicate glass

We report on space-selective co-precipitation of silver and gold nanoparticles in Ag+, Au3+ co-doped silicate glasses by irradiation of femtosecond laser pulses and subsequent annealing at high temperatures. The color of the irradiated area in the glass sample changed from yellow to red with the increase of the annealing temperature. The effects of average laser power and annealing temperature on precipitation of the nanoparticles were investigated. A reasonable mechanism was proposed to explain the observed phenomena. (c) 2006 Elsevier Ltd. All rights reserved.

Effect of PbO on precipitation of laser-induced gold nanoparticles inside silicate glasses

We report on three-dimensional precipitation of Au nanoparticles in gold ions-doped silicate glasses by a femtosecond laser irradiation and further annealing. Experimental results show that PbO addition plays the double roles of inhibiting hole-trapped centers generation and promoting formation and growth of gold nanoparticles. Additionally, glass containing PbO shows an increased non-linear absorption after femtosecond laser irradiation and annealing. The observed phenomena are significant for applications such as fabrications of three-dimensional multi-colored images inside transparent materials and three-dimensional optical memory, and integrated micro-optical switches. (c) 2007 Elsevier B.V. All rights reserved.

Space-selective precipitation of Au nanoparticles inside silica gel

Au colloids were prepared by irradiation with a Nd:YAG laser. Au nanoparticles were characterized by absorption spectra, transmission electron microscopy (TEM) and X-ray diffraction (XRD) analysis. It is found that the wavelength of the laser has no effect on the size but the number of the Au nanoparticles. By irradiating a transparent silica gel doped with gold ions with the focused laser in the gel and subsequent exposing in air, a space-selective pattern of letter "P" consisting of Au nanoparticles was observed inside the silica gel.

Preparation of Y1.84La0.16O3 nanopowders by oxalate co-precipitation method

Nanopowder of Y(1.84)mLa(0.16)O(3) was prepared by oxalate co-precipitation method. The powder was characterized by TG-DTA, XRD and TEM. The results show that the precursor is Re-2 (NO3)(2) (C2O4)(2)center dot 2H(2)O (Re=Y, La), and the Y1.84La0.16O3 nanopowders produced by calcining the precursor at 1000 degrees C for 4 h are 20 similar to 40 nm spherical particles and well dispersed. The powders were with high sintering activity and could be fabricated to transparent ceramic without additive at 1450 similar to 1550 degrees C in H-2 atmosphere for 3 hours. The total transmission of the transparent ceramic could reach 80%.

Precipitation of Ge nanoparticles from GeO2 glasses in transmission electron microscope

We show, using spatially resolved energy loss spectroscopy in a transmission electron microscopy (TEM), that GeO2 and GeO2-SiO2 glasses are extremely sensitive to high energy electrons. Ge nanoparticles can be precipitated in GeO2 glasses efficiently by the high-energy electron beam of a TEM. This is relevant to TEM characterization of luminescent Ge nanoparticles in silicate glasses, which may produce artificial results. (C) 2005 American Institute of Physics.

Dendroclimatic reconstructions of temperature, precipitation, and pressure patterns over the western and central USA, 1602-1961 [abstract]

EXTRACT (SEE PDF FOR FULL ABSTRACT): Verified reconstructions of seasonal temperature, precipitation and sea-level pressure over North America and the North Pacific have been derived from 65 arid-site tree-ring chronologies in the North American West. Significant reconstructions were obtained for temperature for wide areas in the West and mid-continent. Precipitation reconstructions were significant only in the West, and pressure was reconstructed over wide areas of the North Pacific Ocean and the North American continent.

400 years of precipitation variability in central and southern California reconstructed from tree-rings [abstract]

EXTRACT (SEE PDF FOR FULL ABSTRACT): Precipitation variability at 31 stations hanging from San Diego to San Francisco and from the coast to the Sierras was characterized ...

Surface temperature and precipitation variations in the western U.S. and their relation to large scale circulation indices [abstract]

EXTRACT (SEE PDF FOR FULL ABSTRACT): An analysis of the principal components of surface temperature and precipitation in the western U.S. is presented. Data consist of monthly mean temperature and total precipitation for 66 climate divisions west of the Continental Divide, for the years 1931-1984. The analysis is repeated for three separate combinations of months - the water year (Oct - Sept), the cool season (Oct - Mar) and the warm season (Apr - Sept). Inspection of monthly precipitation climatology indicates that selection of these combinations of months results in very few awkward splittings of the natural precipitation seasons found in the West.

A mechanism for the link between solar-irradiance variations and regional precipitation

Although the mechanisms of climatic fluctuations are not completely understood, changes in global solar irradiance show a link with regional precipitation. A proposed mechanism for this linkage begins with absorption of varying amounts of solar energy by tropical oceans, which may aid in development of ocean temperature anomalies. These anomalies are then transported by major ocean currents to locations where the stored energy is released into the atmosphere, altering pressure and moisture patterns that can ultimately affect regional precipitation. Correlation coefficients between annual averages of monthly differences in empirically modeled solar-irradiance variations and annual state-divisional precipitation values in the United States for 1950 to 1988 were computed with lag times of 0 to 7 years. The highest correlations (R=0.65) occur in the Pacific Northwest with a lag time of 4 years, which is about equal to the travel time of water within the Pacific Gyre from the western tropical Pacific Ocean to the Gulf of Alaska. With positive correlations, droughts coincide with periods of negative irradiance differences (dry, high-pressure development), and wet periods coincide with periods of positive differences (moist, low-pressure development).