994 resultados para marine evaporitic petroleum


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Recent demands for petroleum to carry on the war effort have resulted in widespread prospecting in the northern Great Plains. Nearly all oil wells now drilled are of a depth to penetrate the marine Jurassic formations. It is known that these strata differ in thickness from place to place, but information of distribution, thickness, and lithology has not yet been compiled.

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Sediments from the Gulf of California contain sufficient amounts of thermally reactive organic matter to be considered fair-to-good potential petroleum source rocks. While sediments deposited within the present oxygen-minimum zone have the greatest amounts of organic matter, those deposited below the oxygen-minimum contain sufficient organic matter to be considered potential source rocks. The organic matter in the sediment is almost exclusively marine, Type II kerogen. Different techniques of determining kerogen composition produce generally compatible answers, although pyrolysis gives somewhat misleading results. Elemental analysis of the kerogen and vitrinite reflectance measurements indicate that the organic matter is not buried to sufficiently great depth for significant petroleum generation, despite the high temperature gradients.

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We analyzed samples from ODP Holes 652A and 654A (Leg 107, Tyrrhenian Sea) for the amount, type, and thermal maturity of organic matter. The sediments encompass clastic and biogenic lithologies, which were deposited on the passive margin east of Sardinia since the late Miocene to the Pleistocene. Marine, hypersaline/evaporitic, lacustrine/riverine, and finally hemipelagic marine conditions with occasional anoxic(?) interludes gave rise to very diverse sedimentary facies. The majority of samples is lean in organic matter (<0.2% TOC). Notable exceptions are Tortonian sediments (TOC average 0.3%), Messinian oil shales from Core 107-652A-64R (up to 11% TOC), Messinian lacustrine/fluvial sediments from Hole 652A (TOC average 0.42%,), and Pleistocene sapropel samples (>2% TOC). The Messinian oil shale in Hole 652A appears to be the only mature hydrocarbon source rock. In general, Pliocene sediments are the leanest and least mature samples. Pleistocene and Pliocene samples derive organic matter from a marine source. In spite of obvious facies differences in the Messinian between the two sites, pyrolysis results are not conclusive in separating hypersaline facies of Site 654 from the fresh water facies of Site 652, because both appear to have received terrestrial organic tissue as the main component of TOC. It is apparent from the distribution of maximum pyrolysis temperatures that heat flow must have been considerably higher at Site 652 on the lower margin in the Messinian. Molecular maturity indices in lipid extracts substantiate the finding that the organic matter in Tortonian and Messinian samples from Hole 654A is immature, while thermal maturation is more advanced in coeval samples from Hole 652A. Analyses of lipid biomarkers showed that original odd-even predominance was preserved in alkanes and alkylcyclohexanes from Messinian samples in Hole 654A, while thermal maturation had removed any odd-even predominance in Hole 652A. Isomerization data of hopanes and steranes support these differences in thermal history for the two sites. Hopanoid distribution further suggests that petroleum impregnation from a deeper, more mature source resulted in the co-occurrence of immature and mature groups of pentacyclic biomarkers. Even though the presence of 4-methylsteranes may imply that dinoflagellates were a major source for organic matter in the oil shale interval of Hole 652, we did not find intact dinoflagellates or related nonskeletal algae during microscopic investigation of the organic matter in the fine laminations. Morphologically, the laminations resemble bacterial mats.

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The marine stratigraphic record of the Granada Basin (central Betic Cordillera, Spain) is composed of three Late Miocene genetic units deposited in different sea-level contexts (from base to top): Unit I (sea-level rise), Unit II (high sea-level), and Unit III (low sea-level). The latter mainly consists of evaporites precipitated in a shallow-basin setting. Biostratigraphic analyses based on planktonic foraminifera and calcareous nannoplankton indicate four late Tortonian bioevents (PF1-CN1, PF2, PF3, and PF4), which can be correlated with astronomically-dated events in other sections of the Mediterranean. PF1-CN1 (7.89 Ma) is characterized by the influx of the Globorotalia conomiozea group (including typical forms of Globorotalia mediterranea) and by the first common occurrence of Discoaster surculus; PF2 (7.84 Ma) is marked by the first common occurrence of Globorotalia suterae; PF3 (7.69 Ma) is typified by the influx of dextral Neogloboquadrina acostaensis; and PF4 (7.37 Ma) is defined by the influx of the Globorotalia menardii group II (dextral forms). The PF1 event occurred in the upper part of Unit I, whereas PF2 to PF4 events occurred successively within Unit II. The age of Unit III (evaporites) can only be estimated in its lower part based on the presence of dextral Globorotalia scitula, which, together with the absence of the first common occurrence of the G. conomiozea group (7.24 Ma), points to the latest Tortonian. Comparisons with data from the other Betic basins indicate that the evaporitic phase of the Granada Basin (7.37–7.24 Ma) is not synchronous with those from the Lorca Basin (7.80 Ma) and the Fortuna Basin (7.6 Ma). In the Bajo Segura Basin (easternmost Betic Cordillera), no evaporite deposition occurred during the late Tortonian. The evaporitic unit of the Granada Basin (central Betics) records the late Tortonian restriction of the Betic seaway (the marine connection between the Atlantic and Mediterranean). The diachrony in the restriction of the Betic seaway is related to differing tectonic movements in the central and eastern sectors of the Betic Cordillera.

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"DOE/EV/06020-T4."

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Acknowledgements Fieldwork and sampling was funded by Petroleum Development Oman during S. Al Marjibis’s Ph.D. Their help is gratefully acknowledged. We also thank colleagues at the University of Aberdeen, Julie Dougans (SUERC) for assisting with stable isotope analysis and Dr. Richard Hinton (EIMF) for assistance with ion microprobe analysis. Profs. Kiessling, Tucker, Bosence, Coleman, Dr. Dickson and an anonymous reviewer are thanked for their helpful and encouraging comments.

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Chemical Stratigraphy, or the study of the variation of chemical elements within sedimentary sequences, has gradually become an experienced tool in the research and correlation of global geologic events. In this paper 87Sr/ 86Sr ratios of the Triassic marine carbonates (Muschelkalk facies) of southeast Iberian Ranges, Iberian Peninsula, are presented and the representative Sr-isotopic curve constructed for the upper Ladinian interval. The studied stratigraphic succession is 102 meters thick, continuous, and well preserved. Previous paleontological data from macro and micro, ammonites, bivalves, foraminifera, conodonts and palynological assemblages, suggest a Fassanian-Longobardian age (Late Ladinian). Although diagenetic minerals are present in small amounts, the elemental data content of bulk carbonate samples, especially Sr contents, show a major variation that probably reflects palaeoenvironmental changes. The 87Sr/86Sr ratios curve shows a rise from 0.707649 near the base of the section to 0.707741 and then declines rapidly to 0.707624, with a final values rise up to 0.70787 in the upper part. The data up to meter 80 in the studied succession is broadly concurrent with 87Sr/86Sr ratios of sequences of similar age and complements these data. Moreover, the sequence stratigraphic framework and its key surfaces, which are difficult to be recognised just based in the facies analysis, are characterised by combining variations of the Ca, Mg, Mn, Sr and CaCO3 contents

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Brucite [Mg(OH)2] microbialites occur in vacated interseptal spaces of living scleractinian coral colonies (Acropora, Pocillopora, Porites) from subtidal and intertidal settings in the Great Barrier Reef, Australia, and subtidal Montastraea from the Florida Keys, United States. Brucite encrusts microbial filaments of endobionts (i.e., fungi, green algae, cyanobacteria) growing under organic biofilms; the brucite distribution is patchy both within interseptal spaces and within coralla. Although brucite is undersaturated in seawater, its precipitation was apparently induced in the corals by lowered pCO2 and increased pH within microenvironments protected by microbial biofilms. The occurrence of brucite in shallow-marine settings highlights the importance of microenvironments in the formation and early diagenesis of marine carbonates. Significantly, the brucite precipitates discovered in microenvironments in these corals show that early diagenetic products do not necessarily reflect ambient seawater chemistry. Errors in environmental interpretation may arise where unidentified precipitates occur in microenvironments in skeletal carbonates that are subsequently utilized as geochemical seawater proxies.