等电子杂质Sb对InP中缺陷的影响

于2010-11-23批量导入

~(125)Sb高自旋态:粒子-核芯激发耦合

利用在束γ谱学方法,通过~(124)Sn(~7Li,α2n)反应研究了~(125)Sb的激发态,首次建立了~(125)Sb的高自旋能级纲图,其中包括21条新γ跃迁和14个新能级。发现1970,2110和2470 keV3个能级为同质异能态,基于延迟符合测量确定了它们的寿命范围,并确定其自旋、宇称分别为15/2~-,19/2~-和23/2~+。根据粒子-核芯耦合图像和经验壳模型计算解释了~(125)Sb的能级结构,3个同质异能态的组态分别被指定为πg_(7/2)(×)V(h_(11/2)s_(1/2))_(5~-),πg_(7/2)(×)V(h_(11/2)d_(3/2))_(7~-)和πg_(7/2)(×)V(h_(11/2)~2)_(10~+),

丰中子核~(125)Sb的高自旋态(英文)

利用在束γ谱学方法 ,通过1 2 4 Sn( 7Li,α2n)反应首次研究了丰中子核1 2 5Sb的高自旋态 .建立了自旋达 2 3 2 +、激发能至 2 63 7keV的能级纲图 ,其中包括 2 1条新γ跃迁和 1 4个新能级 .在 1 970 ,2 1 1 0和 2 471keV识别出了 3个同质异能态 ,估计了它们的寿命范围 ,并建议分别具有πg7 2 ν(h1 1 2 s1 2 ) ,πg7 2 ν(h1 1 2 d3 2 ) ,πg7 2 ν(h21 1 2 )三准粒子组态 .根据价质子与1 2 4 Sn核芯激发态的耦合讨论了1 2 5Sb的能级结构 .

污染土壤中Sn、Hg、Sb、Bi解吸动力学特性的研究

土壤中重金属的解吸直接影响重金属在环境中的形态转化和植物有效性。文章以我国东北地区草甸棕壤作为研究对象,通过对Sn、Hg、Sb、Bi单一及复合污染土壤中Sn、Hg、Sb、Bi的解吸动力学行为的研究,探索污染土壤中重金属Sn、Hg、Sb、Bi的解吸特性与规律。结果表明,不同污染类型的污染土壤中Sn、Hg、Sb、Bi这几种重金属的解吸量随着振荡时间的延长而不断增加。重金属Sn、Hg、Sb、Bi的解吸过程可分为快速反应阶段和慢速反应阶段。描述土壤Sn、Hg、Sb、Bi解吸动力学过程的最优模型为Elovich方程,其次为双常数方程,而一级动力学方程拟合效果不佳。此外,污染土壤中重金属Sn、Hg、Sb、Bi的解吸过程受共存重金属元素的影响。

Size-controlled synthesis and characterization of quantum-size SnO2 nanocrystallites by a solvothermal route

By using ethylenediamine as both an alkali and ligand, quantum size SnO2, nanocrystallites were synthesized with a solvothermal route. The transmission electron micrographs (TEM) were employed to characterize the morphologies of the products. The crystal sizes of the as-synthesized SnO2 were ranged form 2.5 to 3.6 nm. The crystal structure and optical properties of the products were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, optical absorption spectra, photoluminescence and Raman spectra.

One-step synthesis of graphene/SnO2 nanocomposites and its application in electrochemical supercapacitors

A one-step method was developed to fabricate conductive graphene/SnO2 (GS) nanocomposites in acidic solution. Graphite oxides were reduced by SnCl2 to graphene sheets in the presence of HCl and urea. The reducing process was accompanied by generation of SnO2 nanoparticles. The structure and composition of GS nanocomposites were confirmed by means of transmission electron microscopy, x-ray photoelectron and Raman spectroscopy. Moreover, the ultracapacitor characteristics of GS nanocomposites were studied by cyclic voltammograms (CVs) and electrical impedance spectroscopy (EIS). The CVs of GS nanocomposites are nearly rectangular in shape and the specific capacitance degrades slightly as the voltage scan rate is increased. The EIS of GS nanocomposites presents a phase angle close to p/2 at low frequency, indicating a good capacitive behavior.

Direct electrochemistry of glucose oxidase and biosensing for glucose based on carbon nanotubes@SnO2-Au composite

Multiwalled carbon nanotubes@SnO2-Au (MWCNTs@SnO2-Au) composite was synthesized by a chemical route. The structure and composition of the MWCNTs@SnO2-Au composite were confirmed by means of transmission electron microscopy, X-ray photoelectron and Raman spectroscopy. Due to the good electrocatalytic property of MWCNTs@SnO2-Au composite, a glucose biosensor was constructed by absorbing glucose oxidase (GOD) on the hybrid material. A direct electron transfer process is observed at the MWCNTs@SnO2-Au/GOD-modified glassy carbon electrode. The glucose biosensor has a linear range from 4.0 to 24.0 mM, which is suitable for glucose determination by real samples. It should be worthwhile noting that, from 4.0 to 12.0 mM, the cathodic peak currents of the biosensor decrease linearly with increasing the glucose concentrations in human blood. Meanwhile, the resulting biosensor can also prevent the effects of interfering species.