Stable carbon and oxygen isotope record of benthic foraminifera from Paleocene-Eocene sediments

A major change in Cenozoic deep-sea benthic foraminifera occurred in the Atlantic, Indian, and Pacific oceans near the Paleocene/Eocene boundary. Benthic foraminiferal abundance changes began at about 61.5 Ma at Pacific Deep Sea Drilling Project (DSDP) Site 577. A major extinction event followed at 58-57 Ma (between Zones P6a and P6b), and a series of first appearances continued until circa 55.5 Ma (Zone P6c). These faunal changes occurred during a 6°C warming of Pacific bottom water and may indicate that the primary cause was changing temperature. Other potential causes of the faunal turnover include global changes in surface ocean productivity and changing bottom water source regions. Comparison of benthic and planktonic delta13C records requires no change in the ratio of oceanic phosphorous to carbon during the late Paleocene to early Eocene, which weakens the case for (but does not disprove) a change in surface ocean productivity at this time. Interbasinal comparisons of benthic foraminiferal delta13C records document that water with high delta13C values filled the Cape Basin during the late Paleocene and possibly the early Eocene (circa 61-57 Ma), but apparently did not extend into the western basins of the Atlantic. This pattern suggests a supply of Antarctic source water for the Cape Basin and possible tectonic isolation of the western Atlantic basins during at least part of the late Paleocene. Carbon isotope comparisons show that bottom water supply to the Cape Basin was reduced in the early Eocene. Eolian grain size data suggest that a decrease in zonal wind intensity occurred at the end of the Paleocene. These late Paleocene climatic changes (bottom water warming and decreased wind intensity) correspond with evidence for an important global tectonic reorganization and extensive subaerial volcanism, which may have contributed to climatic warming through increased supply of CO2.

Clay mineralogical assemblages, Sm-Nd concentrations, Sm and Nd isotopic ratios and oxygen isotope ratios, OIS number and the age model of ODP Site 105-646

We present 40 Sm-Nd isotope measurements of the clay-size (<2 µm) fractions of sediments from the Southern Greenland rise (ODP-646) that span the last 365 kyr. These data track changes in the relative supply of fine particles carried into the deep Labrador Sea by the Western Boundary Under Current (WBUC) back to the fourth glacial-interglacial cycles. Earlier studies revealed three general sources of particles to the core site: (i) Precambrian crustal material from Canada, Greenland, and/or Scandinavia (North American Shield - NAS), (ii) Palaeozoic or younger crustal material from East Greenland, NW Europe, and/or western Scandinavia (Young Crust - YC) and (iii) volcanic material from Iceland and the Mid-Atlantic Ridge (MAR). Clay-size fractions from glacial sediments have the lowest Nd isotopic ratios. Supplies of young crustal particles were similar during glacial oxygen isotope stages (OIS) 2, 6, and 10. In contrast the mean volcanic contributions decreased relative to old craton material from OIS 10 to OIS 6 and then from OIS 6 to OIS 2. The glacial OIS 8 interval displays a mean Sm/Nd ratio similar to those of interglacials OIS 1, 5, and 9. Compared with other interglacials, OIS 7 was marked by a higher YC contribution but a similar ~30% MAR supply. The overall NAS contribution dropped by a factor of 2 during each glacial/interglacial transition, with the MAR contribution broadly replacing it during interglacials. To decipher between higher supplies and/or dilution, particle fluxes from each end member were estimated. Glacial NAS fluxes were systematically higher than interglacial fluxes. During the time interval examined, fine particle supplies to the Labrador Sea were strongly controlled by proximal ice-margin erosion and thus echoed the glacial stage intensity. In contrast, the WBUC-carried MAR supplies from the eastern basins did not change significantly throughout the last 365 kyr, except for a marked increase in surface-sediments that suggests unique modern conditions. Distal WBUC-controlled inputs from the Northern and NE North Atlantic seem to have been less variable than proximal supplies linked with glacial erosion rate.