Paleomagnetic of ODP Hole 197-1203A

On the basis of studies of Holocene samples,submarine basaltic glass (SBG) is thought to be an ideal paleointensity recorder because it contains unaltered single domain magnetic inclusions that yield Thellier paleointensity data of exceptional quality. To be useful as a recorder of the long-term geomagnetic field, older SBG must retain these optimal properties. Here, we examine this issue through rock magnetic and transmission electron microscope (TEM) analyses of Cretaceous SBG recovered at Ocean Drilling Program Site 1203 (northwestern Pacific Ocean). These SBG samples have very low natural remanent magnetization intensities (NRM <50 nAm**2/g) and TEM analyses indicate a correspondingly low concentration of crystalline inclusions. Thellier experiments on samples with the strongest NRM intensity (>5*10**-11 Am**2) show a rapid acquisition of thermoremanent magnetization (TRM) with respect to NRM demagnetization. Taken at face value,this behavior implies magnetization in a very weak (617 WT) ambient field. But monitoring of magnetic hysteresis properties during the Thellier experiments (on subsamples of the SBG samples used for paleointensity determinations) indicates systematic variations in values over the same temperature range where the rapid TRM acquisition is observed. A similar change in properties during heating is observed on monitor SBG specimens using low-temperature data: with progressive heatings the Verwey transition becomes more distinct. We suggest that these experimental data record the partial melting and neocrystallization of magnetic grains in SBG during the thermal treatments required by the Thellier method,resulting in paleointensity values biased to low values. We further propose that this process is pronounced in Cretaceous and Jurassic SBG (relative to Holocene SBG) because devitrification on geologic time scales (i.e., tens of millions of years) lowers the transition temperature at which the neocrystallization can commence. Magnetic hysteresis monitoring may provide a straightforward means of detecting the formation of new magnetic inclusions in SBG during Thellier experiments.

Desarrollo de un modelo de formación del valor inmobiliario en áreas de crecimiento suburbano. Aplicación a la comarca de la Vega Baja del Segura en el litoral alicantino

Una de las principales líneas de investigación de la economía urbana es el comportamiento del mercado inmobiliario y sus relaciones con la estructura territorial. Dentro de este contexto, la reflexión sobre el significado del valor urbano, y abordar su variabilidad, constituye un tema de especial importancia, dada la relevancia que ha supuesto y supone la actividad inmobiliaria en España. El presente estudio ha planteado como principal objetivo la identificación de aquellos factores, ligados a la localización que explican la formación del valor inmobiliario y justifican su variabilidad. Definir este proceso precisa de una evaluación a escala territorial estableciendo aquellos factores de carácter socioeconómico, medioambiental y urbanístico que estructuran el desarrollo urbano, condicionan la demanda de inmuebles y, por tanto, los procesos de formación de su valor. El análisis se centra en valores inmobiliarios residenciales localizados en áreas litorales donde la presión del sector turístico ha impulsado un amplio. Para ello, el ámbito territorial seleccionado como objeto de estudio se sitúa en la costa mediterránea española, al sur de la provincia de Alicante, la comarca de la Vega Baja del Segura. La zona, con una amplia diversidad ecológica y paisajística, ha mantenido históricamente una clara distinción entre espacio urbano y espacio rural. Esta dicotomía ha cambiado drásticamente en las últimas décadas, experimentándose un fuerte crecimiento demográfico y económico ligado a los sectores turístico e inmobiliario, aspectos que han tenido un claro reflejo en los valores inmobiliarios. Este desarrollo de la comarca es un claro ejemplo de la política expansionista de los mercados de suelo que ha tenido lugar en la costa española en las dos últimas décadas y que derivado en la regeneración de un amplio tejido suburbano. El conocimiento del marco territorial ha posibilitado realizar un análisis de variabilidad espacial mediante un tratamiento masivo de datos, así como un análisis econométrico que determina los factores que se valoran positivamente y negativamente por el potencial comprador. Estas relaciones permiten establecer diferentes estructuras matemáticas basadas en los modelos de precios hedónicos, que permiten identificar rasgos diferenciales en los ámbitos económico, social y espacial y su incidencia en el valor inmobiliario. También se ha sistematizado un proceso de valoración territorial a través del análisis del concepto de vulnerabilidad estructural, entendido como una situación de fragilidad debida a circunstancias tanto sociales como económicas, tanto actual como de tendencia en el futuro. Actualmente, esta estructura de demanda de segunda residencia y servicios ha mostrado su fragilidad y ha bloqueado el desarrollo económico de la zona al caer drásticamente la inversión en el sector inmobiliario por la crisis global de la deuda. El proceso se ha agravado al existir un tejido industrial marginal al que no se ha derivado inversiones importantes y un abandono progresivo de las explotaciones agropecuarias. El modelo turístico no sería en sí mismo la causa del bloqueo del desarrollo económico comarcal, sino la forma en que se ha implantado en la Costa Blanca, con un consumo del territorio basado en el corto plazo, poco respetuoso con aspectos paisajísticos y medioambientales, y sin una organización territorial global. Se observa cómo la vinculación entre índices de vulnerabilidad y valor inmobiliario no es especialmente significativa, lo que denota que las tendencias futuras de fragilidad no han sido incorporadas a la hora de establecer los precios de venta del producto inmobiliario analizado. El valor muestra una clara dependencia del sistema de asentamiento y conservación de las áreas medioambientales y un claro reconocimiento de tipologías propias del medio rural aunque vinculadas al sector turístico. En la actualidad, el continuo descenso de la demanda turística ha provocado una clara modificación en la estructura poblacional y económica. Al incorporar estas modificaciones a los modelos especificados podemos comprobar un verdadero desmoronamiento de los valores. Es posible que el remanente de vivienda construida actualmente vaya dirigido a un potencial comprador que se encuentra en retroceso y que se vincula a unos rasgos territoriales ya no existentes. Encontrar soluciones adaptables a la oferta existente, implica la viabilidad de renovación del sistema poblacional o modificaciones a nivel económico. La búsqueda de respuestas a estas cuestiones señala la necesidad de recanalizar el desarrollo, sin obviar la potencialidad del ámbito. SUMMARY One of the main lines of research regarding the urban economy focuses on the behavior of the real estate market and its relationship to territorial structure. Within this context, one of the most important themes involves considering the significance of urban property value and dealing with its variability, particularly given the significant role of the real estate market in Spain, both in the past and present. The main objective of this study is to identify those factors linked to location, which explain the formation of property values and justify their variability. Defining this process requires carrying out an evaluation on a territorial scale, establishing the socioeconomic, environmental and urban planning factors that constitute urban development and influence the demand for housing, thereby defining the processes by which their value is established. The analysis targets residential real estate values in coastal areas where pressure from the tourism industry has prompted large-scale transformations. Therefore, the focal point of this study is an area known as Vega Baja del Segura, which is located on the Spanish Mediterranean coast in southern Alicante (province). Characterized by its scenic and ecological diversity, this area has historically maintained a clear distinction between urban and rural spaces. This dichotomy has drastically changed in past decades due to the large increase in population attributed to the tourism and real estate markets – factors which have had a direct effect on property values. The development of this area provides a clear example of the expansionary policies which have affected the housing market on the coast of Spain during the past two decades, resulting in a large increase in suburban development. Understanding the territorial framework has made it possible to carry out a spatial variability analysis through massive data processing, as well as an econometric analysis that determines the factors that are evaluated positively and negatively by potential buyers. These relationships enable us to establish different mathematical systems based on hedonic pricing models that facilitate the identification of differential features in the economic, social and spatial spheres, and their impact on property values. Additionally, a process for land valuation was established through an analysis of the concept of structural vulnerability, which is understood to be a fragile situation resulting from either social or economic circumstances. Currently, this demand structure for second homes and services has demonstrated its fragility and has inhibited the area’s economic development as a result of the drastic fall in investment in the real estate market, due to the global debt crisis. This process has been worsened by the existence of a marginal industrial base into which no important investments have been channeled, combined with the progressive abandonment of agricultural and fishing operations. In and of itself, the tourism model did not inhibit the area’s economic development, rather it is the result of the manner in which it was implemented on the Costa Brava, with a land consumption based on the short-term, lacking respect for landscape and environmental aspects and without a comprehensive organization of the territory. It is clear that the link between vulnerability indexes and property values is not particularly significant, thereby indicating that future fragility trends have not been incorporated into the problem in terms of establishing the sale prices of the analyzed real estate product in question. Urban property values are clearly dependent on the system of development and environmental conservation, as well as on a clear recognition of the typologies that characterize rural areas, even those linked to the tourism industry. Today, the continued drop in tourism demand has provoked an obvious modification in the populational and economic structures. By incorporating these changes into the specified models, we can confirm a real collapse in values. It’s possible that the surplus of already-built homes is currently being marketed to a potential buyer who is in recession and linked to certain territorial characteristics that no longer exist. Finding solutions that can be adapted to the existing offer implies the viability of renewing the population system or carrying out modifications on an economic level. The search for answers to these questions suggests the need to reform the development model, without leaving out an area’s potentiality.

Sistema de instrumentação e controle para células a combustível

Este trabajo presenta un estudio sobre el funcionamiento y aplicaciones de las células de combustible de membrana tipo PEM, o de intercambio de protones, alimentadas con hidrógeno puro y oxigeno obtenido de aire comprimido. Una vez evaluado el proceso de dichas células y las variables que intervienen en el mismo, como presión, humedad y temperatura, se presenta una variedad de métodos para la instrumentación de tales variables así como métodos y sistemas para la estabilidad y control de las mismas, en torno a los valores óptimos para una mayor eficacia en el proceso. Tomando como variable principal a controlar la temperatura del proceso, y exponiendo los valores concretos en torno a 80 grados centígrados entre los que debe situarse, es realizado un modelo del proceso de calentamiento y evolución de la temperatura en función de la potencia del calentador resistivo en el dominio de la frecuencia compleja, y a su vez implementado un sistema de medición mediante sensores termopar de tipo K de respuesta casi lineal. La señal medida por los sensores es amplificada de manera diferencial mediante amplificadores de instrumentación INA2126, y es desarrollado un algoritmo de corrección de error de unión fría (error producido por la inclusión de nuevos metales del conector en el efecto termopar). Son incluidos los datos de test referentes al sistema de medición de temperatura , incluyendo las desviaciones o error respecto a los valores ideales de medida. Para la adquisición de datos y implementación de algoritmos de control, es utilizado un PC con el software Labview de National Instruments, que permite una programación intuitiva, versátil y visual, y poder realizar interfaces de usuario gráficas simples. La conexión entre el hardware de instrumentación y control de la célula y el PC se realiza mediante un interface de adquisición de datos USB NI 6800 que cuenta con un amplio número de salidas y entradas analógicas. Una vez digitalizadas las muestras de la señal medida, y corregido el error de unión fría anteriormente apuntado, es implementado en dicho software un controlador de tipo PID ( proporcional-integral-derivativo) , que se presenta como uno de los métodos más adecuados por su simplicidad de programación y su eficacia para el control de este tipo de variables. Para la evaluación del comportamiento del sistema son expuestas simulaciones mediante el software Matlab y Simulink determinando por tanto las mejores estrategias para desarrollar el control PID, así como los posibles resultados del proceso. En cuanto al sistema de calentamiento de los fluidos, es empleado un elemento resistor calentador, cuya potencia es controlada mediante un circuito electrónico compuesto por un detector de cruce por cero de la onda AC de alimentación y un sistema formado por un elemento TRIAC y su circuito de accionamiento. De manera análoga se expone el sistema de instrumentación para la presión de los gases en el circuito, variable que oscila en valores próximos a 3 atmosferas, para ello es empleado un sensor de presión con salida en corriente mediante bucle 4-20 mA, y un convertidor simple corriente a tensión para la entrada al sistema de adquisición de datos. Consecuentemente se presenta el esquema y componentes necesarios para la canalización, calentamiento y humidificación de los gases empleados en el proceso así como la situación de los sensores y actuadores. Por último el trabajo expone la relación de algoritmos desarrollados y un apéndice con información relativa al software Labview. ABTRACT This document presents a study about the operation and applications of PEM fuel cells (Proton exchange membrane fuel cells), fed with pure hydrogen and oxygen obtained from compressed air. Having evaluated the process of these cells and the variables involved on it, such as pressure, humidity and temperature, there is a variety of methods for implementing their control and to set up them around optimal values for greater efficiency in the process. Taking as primary process variable the temperature, and exposing its correct values around 80 degrees centigrade, between which must be placed, is carried out a model of the heating process and the temperature evolution related with the resistive heater power on the complex frequency domain, and is implemented a measuring system with thermocouple sensor type K performing a almost linear response. The differential signal measured by the sensor is amplified through INA2126 instrumentation amplifiers, and is developed a cold junction error correction algorithm (error produced by the inclusion of additional metals of connectors on the thermocouple effect). Data from the test concerning the temperature measurement system are included , including deviations or error regarding the ideal values of measurement. For data acquisition and implementation of control algorithms, is used a PC with LabVIEW software from National Instruments, which makes programming intuitive, versatile, visual, and useful to perform simple user interfaces. The connection between the instrumentation and control hardware of the cell and the PC interface is via a USB data acquisition NI 6800 that has a large number of analog inputs and outputs. Once stored the samples of the measured signal, and correct the error noted above junction, is implemented a software controller PID (proportional-integral-derivative), which is presented as one of the best methods for their programming simplicity and effectiveness for the control of such variables. To evaluate the performance of the system are presented simulations using Matlab and Simulink software thereby determining the best strategies to develop PID control, and possible outcomes of the process. As fluid heating system, is employed a heater resistor element whose power is controlled by an electronic circuit comprising a zero crossing detector of the AC power wave and a system consisting of a Triac and its drive circuit. As made with temperature variable it is developed an instrumentation system for gas pressure in the circuit, variable ranging in values around 3 atmospheres, it is employed a pressure sensor with a current output via 4-20 mA loop, and a single current to voltage converter to adequate the input to the data acquisition system. Consequently is developed the scheme and components needed for circulation, heating and humidification of the gases used in the process as well as the location of sensors and actuators. Finally the document presents the list of algorithms and an appendix with information about Labview software.

Educar en valores a través de programas de deporte escolar: un estudio comparado entre la “Union Nationale du Sport Scolaire” (Francia) y los “Campeonatos Escolares en los IES de la Comunidad de Madrid” (España)

El interés de las administraciones públicas por promover el deporte escolar, suele justificarse por los beneficios educativos y saludables que los escolares obtendrían de las prácticas físico-deportivas. Mas allá de concepciones neutrales o excesivamente idealizadas sobre su valor educativo, las condiciones socioculturales que lo configuran y las intervenciones pedagógicas en el terreno marcan la orientación de la educación en valores propuesta en los programas de deporte escolar. El objeto de estudio de esta tesis doctoral es comprender la educación en valores desde el punto de vista de la estructura organizativa y de los actores implicados en dos programas de deporte escolar seleccionados de países diferentes: la “Union Nationale du Sport Scolaire” (UNSS) en Francia y los “Campeonatos Escolares en los IES de la Comunidad de Madrid” (CEIESCM) en España. El diseño metodológico es un estudio comparado internacional y de corte cualitativo, donde se han analizado 66 entrevistas semiestructuradas, 28 observaciones directas, 45 documentos y el cuaderno etnográfico del investigador por medio de análisis de contenido temático apoyado con el programa NVivo 10. Los resultados aportan dos concepciones distintas de deporte escolar con repercusión en la educación en valores: la UNSS complementa valores del sistema educativo y deportivo proporcionando cauces de implicación y compromiso del alumnado en el arbitraje y la organización asociativa, mientras que en CEIESCM, eximiéndoles de esas responsabilidades, se prioriza la máxima práctica de actividad físico-deportiva reforzando o sancionando durante la misma las conductas que vayan a promover valores del juego limpio propios del deporte. La explicación de estos resultados, contextualizados en sus países respectivos, permite proyectar un eventual deporte escolar europeo basado en valores ciudadanos y democráticos que recogería la perspectiva moral, jurídica y política propuesta a partir del estudio. RÉSUMÉ L’intérêt des administrations publiques pour promouvoir le sport scolaire est souvent justifié par les bénéfices éducatifs et ceux liés à la santé que les élèves obtiendraient des pratiques physiques et sportives. Au-delà des conceptions neutres et excessivement idéalistes sur sa valeur éducative, les conditions socio-culturelles qui le configurent et les interventions pédagogiques sur le terrain marquent l’orientation de l’éducation des valeurs proposée par les programmes de sport scolaire. L’objet de cette étude est de comprendre l’éducation des valeurs du point de vue de la structure organisationnelle et des acteurs impliqués dans deux programmes de sport scolaire sélectionnés de différents pays: l’« Union Nationale du Sport Scolaire » (UNSS) en France et les « Campeonatos Escolares de los IES de la Comunidad de Madrid » (CEIESCM) en Espagne. L’approche méthodologique est une étude comparée internationale et qualitative, où l’on a analysé 66 entretiens semi-directifs, 28 observations directes, 45 documents et le carnet ethnographique du chercheur par le biais d’une analyse de contenu thématique à l’aide du programme NVivo 10. Les résultats apportent deux conceptions différentes du sport scolaire qui ont des répercussions dans l’éducation des valeurs: l’UNSS regroupe les valeurs du système éducatif et sportif en proposant aux élèves des espaces d’implication et d’engagement avec l’arbitrage et l’organisation associative, alors que les CEISCM, les exemptent de ces responsabilités et donnent la priorité au maximum d’activité physique et sportive pratiquée où l’on renforce ou sanctionne pendant son déroulement les conduites qui encourageront les valeurs de fair-play liées au sport. L’explication des résultats, contextualisée dans leurs pays respectifs, permet de projeter un éventuel sport scolaire européen basé sur des valeurs citoyennes et démocratiques qui recueillerait la perspective morale, juridique et politique proposée suite à cette étude. ABSTRACT The interest of public institutions for promoting school sports is often justified by the educational and healthy benefits that the students obtained through physical activity and sports practice. Beyond neutral or overly idealised conceptions about the educational value of sport, sociocultural conditions and pedagogical interventions shape the orientation of education in values given in school sports programs. The aim of this thesis is to understand the values education from the perspectives of the organizational structure and actors involved in two school sports programs selected from different countries: the "Union Nationale du Sport Scolaire" (UNSS) in France and the "School Championships in the IES of the Community of Madrid" (CEIESCM) in Spain. The methodology is a comparative international and qualitative study, with 66 semistructured interviews, 28 direct observations, 45 documentary resources and the ethnographic research notebook being analysed through thematic content analysis using the program NVivo 10. The results provide two different conceptions of school sport that impact on values education: on the one hand, the UNSS complements values of the educational and sports system providing channels of participation and promoting the involvement of students in refereeing and associative organization; on the other hand, CEIESCM is does not assume these responsibilities and the maximum sportive practice is prioritized reinforcing or punishing behaviours that promote sport fair play. The explanation of these results, contextualized in their respective countries, can project an eventual European school sport based on citizens and democratic values and reflect moral, legal and political perspective proposed in this study.

Influencia de la adición de nanosílice y microsílice en el comportamiento mecánico, microestructural y durable de un hormigón autocompactante

Desde mediados de la década de los 80 se está investigando sobre el hormigón autocompactante. Cada día, su uso en el mundo de la construcción es más común debido a sus numerosas ventajas como su excelente fluidez ya que puede fluir bajo su propio peso y llenar encofrados con formas complicadas y muy armados sin necesidad de compactaciones internas o externas. Por otra parte, la búsqueda de materiales más resistentes y duraderos, ha dado lugar a la incorporación de adiciones en materiales a base de cemento. En las últimas dos décadas, los ensayos con los nanomateriales, ha experimentado un gran aumento. Los resultados hasta ahora obtenidos pueden asumir no sólo un aumento en la resistencia de estos materiales, pero un cambio es su funcionalidad. Estas nanopartículas, concretamente la nanosílice, no sólo mejoran sus propiedades mecánicas y especialmente sus propiedades durables, sino que pueden implicar un cambio sustancial en las condiciones de uso y en su ciclo de vida. Este trabajo tiene como principal objetivo el estudio de las propiedades mecánicas, características microestructurales y durables de un hormigón autocompactante cuando se le agrega como adición nanosílice, microsílice y mezcla binarias de ambas, como adición al cemento. Para ello se han realizado 10 mezclas de hormigón. Se utilizó como referencia un hormigón autocompactante obtenido con cemento, caliza, árido, aditivo modificador de viscosidad Se han fabricado tres hormigones con la misma dosificación pero con diferentes contenidos de nanosílice. 2,5%, 5% y 7,5% Tres dosificaciones con adición de microsílice 2,5%, 5% y 7,5% y las tres restantes con mezclas binarias de nanosílice y microsílice con respectivamente2,5%-2,5%, 5%-2,5% y 2,5%-5%, sobre el peso del cemento. El contenido de superplastificante se modificó para conseguir las características de autocompactabilidad. Para observar los efectos de las adiciones añadidas al hormigón, se realiza una extensa campaña experimental. En ella se evaluaron en primer lugar, las características de autocompactabilidad del material en estado fresco, mediante los ensayos prescritos en la Instrucción Española del hormigón estructural EHE 08. Las propiedades mecánicas fueron evaluadas con ensayos de resistencia a compresión, resistencia a tracción indirecta y módulo de elasticidad. Las características microestructurales fueron analizadas mediante porosimetría por intrusión de mercurio, el análisis termogravimétrico y la microscopía electrónica de barrido. Para el estudio de la capacidad durable de las mezclas se realizaron ensayos de resistividad eléctrica, migración de cloruros, difusión de cloruros, carbonatación acelerada, absorción capilar y resistencia al hielo-deshielo. Los resultados ponen de manifiesto que la acción de las adiciones genera mejoras en las propiedades resistentes del material. Así, la adición de nanosílice proporciona mayores resistencias a compresión que la microsílice, sin embargo las mezclas binarias con bajas proporciones de adición producen mayores resistencias. Por otra parte, se observó mediante la determinación de las relaciones de gel/portlandita, que las mezclas que contienen nanosílice tienen una mayor actividad puzolánica que las que contienen microsílice. En las mezclas binarias se obtuvo como resultado que mientras mayor es el contenido de nanosílice en la mezcla mayor es la actividad puzolánica. Unido a lo anteriormente expuesto, el estudio de la porosidad da como resultado que la adición de nanosílice genera un refinamiento del tamaño de los poros mientras que la adición de microsílice disminuye la cantidad de los mismos sin variar el tamaño de poro medio. Por su parte, en las micrografías, se visualizó la formación de cristales procedentes de la hidratación del cemento. En ellas, se pudo observar, que al adicionar nanosílice, la velocidad de hidratación aumenta al aumentar la formación de monosulfoaluminatos con escasa presencia de etringita. Mientras que en las mezclas con adición de microsílice se observan mayor cantidad de cristales de etringita, lo que confirma que la velocidad de hidratación en estos últimos fue menor. Mediante el estudio de los resultados de las pruebas de durabilidad, se observó que no hay diferencias significativas entre el coeficiente de migración de cloruros y el coeficiente de difusión de cloruros en hormigones con adición de nano o microsílice. Aunque este coeficiente es ligeramente menor en mezclas con adición de microsílice. Sin embargo, en las mezclas binarias de ambas adiciones se obtuvo valores de los coeficientes de difusión o migración de cloruros inferiores a los obtenidos en mezclas con una única adición. Esto se evidencia en los resultados de las pruebas de resistividad eléctrica, de difusión de cloruros y de migración de cloruros. Esto puede ser debido a la suma de los efectos que producen el nano y micro adiciones en la porosidad. El resultado mostró que nanosílice tiene un papel importante en la reducción de los poros y la microsílice disminuye el volumen total de ellos. Esto permite definir la vida útil de estos hormigones a valores muy superiores a los exigidos por la EHE-08, por lo que es posible reducir, de forma notable, el recubrimiento exigido en ambiente de alta agresividad asegurando un buen comportamiento en servicio. Por otra parte, la pérdida de masa debido a los ciclos de congelación-descongelación es significativamente menor en los hormigones que contienen nanosílice que los que contienen microsílice. Este resultado está de acuerdo con el ensayo de absorción capilar. De manera general, se puede concluir que son las mezclas binarias y más concretamente la mezcla con un 5% de nanosílice y 2,5% de microsílice la que presenta los mejores resultados tanto en su comportamiento resistente con en su comportamiento durable. Esto puede ser debido a que en estas mezclas la nanosílice se comporta como un núcleo de activación de las reacciones puzolánicas rodeado de partículas de mayor tamaño. Además, el extraordinario comportamiento durable puede deberse también a la continuidad en la curva granulométrica por la existencia de la microsílice, el filler calizo, el cemento, la arena y la gravilla con tamaños de partículas que garantice mezclas muy compactas que presentan elevadas prestaciones. Since the middle of the decade of the 80 is being investigated about self-consolidating concrete. Every day, its use in the world of construction is more common due to their numerous advantages as its excellent fluidity such that it can flow under its own weight and fill formworks with complicated shapes and congested reinforcement without need for internal or external compactions. Moreover, the search for more resistant and durable materials, has led to the incorporation of additions to cement-based materials. In the last two decades, trials with nanomaterials, has experienced a large increase. The results so far obtained can assume not only an increase in the resistance of these materials but a change is its functionality. These nano particles, particularly the nano silica, not only improve their mechanical properties and especially its durable properties, but that may imply a substantial change in the conditions of use and in their life cycle. This work has as its main objective the study of the mechanical properties, the microstructural characteristics and durability capacity in one self-compacting concrete, when added as addition to cement: nano silica, micro silica o binary mixtures of both. To this effect, 10 concrete mixes have been made. As reference one with a certain amount of cement, limestone filler, viscosity modifying additive and water/binder relation. Furthermore they were manufactured with the same dosage three mix with addition of 2.5%, 5% and 7.5% of nano silica by weight of cement. Other three with 2.5%, 5% and 7.5% of micro silica and the remaining three with binary mixtures of 2.5%-2.5%, 5%-2.5% and 2.5%-5% of silica nano-micro silica respectively, b weight of cement, varying only the amount of superplasticizer to obtain concrete with characteristics of self-compactability. To observe the effects of the additions added to the concrete, an extensive experimental campaign was performed. It assessed, first, the characteristics of self-compactability of fresh material through the tests prescribed in the Spanish Structural Instruction Concrete EHE 08. The mechanical properties were evaluated by compression strength tests, indirect tensile strength and modulus of elasticity. The microstructural properties were analyzed by mercury intrusion porosimetry, thermogravimetric analysis and scanning electron microscopy. To study the durability, were performed electrical resistivity tests, migration and diffusion of chlorides, accelerated carbonation, capillary suction and resistance to freeze-thaw cycles. The results show that the action of the additions generates improvements in the strength properties of the material. Specifically, the addition of nano silica provides greater resistance to compression that the mix with micro silica, however binary mixtures with low addition rates generate higher strengths. Moreover, it was observed by determining relationships gel/portlandite, that the pozzolanic activity in the mixtures with nano silica was higher than in the mixtures with micro silica. In binary mixtures it was found that the highest content of nano silica in the mix is the one with the highest pozzolanic activity. Together with the foregoing, the study of the porosity results in the mixture with addition of nano silica generates a refinement of pore size while adding micro silica decreases the amount thereof without changing the average pore size. On the other hand, in the micrographs, the formation of crystals of cement hydration was visualized. In them, it was observed that by adding nano silica, the speed of hydration increases with increasing formation monosulfoaluminatos with scarce presence of ettringite. While in mixtures with addition of micro silica, ettringite crystals are observed, confirming that the hydration speed was lower in these mixtures. By studying the results of durability testing, it observed that no significant differences between the coefficient of migration of chlorides and coefficient of diffusion of chlorides in concretes with addition of nano or micro silica. Although this coefficient is slightly lower in mixtures with addition of micro silica. However, in binary mixtures of both additions was obtained values of coefficients of difusion o migration of chlorides lower than those obtained in mixtures with one of the additions. This is evidenced by the results of the tests electrical resistivity, diffusion of chlorides and migration of chlorides. This may be due to the sum of the effects that produced the nano and micro additions in the porosity. The result showed that nano silica has an important role in the pores refining and the micro silica decreases the total volume of them. This allows defining the life of these concretes in values to far exceed those required by the EHE-08, making it possible to reduce, significantly, the coating required in highly aggressive environment and to guarantee good behavior in service. Moreover, the mass loss due to freeze-thaw cycles is significantly lower in concretes containing nano silica than those containing micro silica. This result agrees with the capillary absorption test. In general, one can conclude that the binary mixture and more specifically the mixture with 5% of nano silica and 2.5% silica fume is which presents the best results in its durable behavior. This may be because in these mixtures, the nano silica behaves as cores activation of pozzolanic reactions. In addition, the durable extraordinary behavior may also be due to the continuity of the grading curve due to existence of micro silica, limestone filler, cement, sand and gravel with particle sizes that guarantees very compact mixtures which have high performance.

Modelización de las fallas activas para la estimación de la Peligrosidad Sísmica. Aplicación Metodológica en Haití

The development of this Master's Thesis is aimed at modeling active for estimating seismic hazard in Haití failures. It has been used zoned probabilistic method, both classical and hybrid, considering the incorporation of active faults as independent units in the calculation of seismic hazard. In this case, the rate of seismic moment is divided between the failures and the area seismogenetic same region. Failures included in this study are the Septentrional, Matheux and Enriquillo fault. We compared the results obtained by both methods to determine the importance of considering the faults in the calculation. In the first instance, updating the seismic catalog, homogenization, completeness analysis and purification was necessary to obtain a catalog ready to proceed to the estimation of the hazard. With the seismogenic zoning defined in previous studies and the updated seismic catalog, they are obtained relations Gutenberg-Richter recurrence of seismicity, superficial and deep in each area. Selected attenuation models were those used in (Benito et al., 2011), as the tectonic area of study is very similar to that of Central America. Its implementation has been through the development of a logical in which each branch is multiplied by an index based on the relevance of each combination of models. Results are presented as seismic hazard maps for return periods of 475, 975 and 2475 years, and spectral acceleration (SA) in structural periods: 0.1 - 0.2 - 0.5 - 1.0 and 2.0 seconds, and the difference accelerations between maps obtained by the classical method and the hybrid method. Maps realize the importance of including faults as separate items in the calculation of the hazard. The morphology of the zoned maps presented higher values in the area where the superficial and deep zone overlap. In the results it can determine that the minimum values in the zoned approach they outweigh the hybrid method, especially in areas where there are no faults. Higher values correspond to those obtained in fault zones by the hybrid method understanding that the contribution of the faults in this method is very important with high values. The maximum value of PGA obtained is close to Septentrional in 963gal, near to 460 gal in Matheux, and the Enriquillo fault line value reaches 760gal PGA in the Eastern segment and Western 730gal in the segment. This compares with that obtained in the zoned approach in this area where the value of PGA obtained was 240gal. These values are compared with those obtained by Frankel et al., (2011) with those have much similarity in values and morphology, in contrast to those presented by Benito et al., (2012) and the Standard Seismic Dominican Republic

Herramienta de certificación para la Bioconstrucción

En este trabajo se presenta una propuesta de herramienta para la certificación de viviendas de Bioconstrucción en España. Se basa en que la Bioconstrucción es una práctica consolidada en el territorio Español, pero que carece de estudio científico para definir, caracterizar y comprobar esta práctica como alternativa constructiva comprometida con el medio ambiente y con la salud humana. Primeramente se hace el estudio de las referencias específicas existentes y se complementa con bibliografía afín, para así tener una caracterización en la que pueda asentarse el trabajo de campo. En el trabajo de campo se comprueban los aspectos que componen la Bioconstrucción. Se han buscado casos de estudio diversificados y una detallada evaluación de proyectos y construcciones, así como de la información obtenida en encuestas a los propietarios y usuarios, y a los profesionales responsables de los procesos constructivos. Con esta base de datos se establecieron características tanto constructivas como geográficas o socio ambientales, y se ha definido la estructura para la herramienta. Se propone entonces una metodología de certificación que integra tres dimensiones identificadas a lo largo del estudio de la Bioconstrucción: salud, medio ambiente y responsabilidad social. A partir de una visión sistémica y basándose en valores como la promoción de espacios de la salud humana en consonancia con los patrones de la naturaleza, el equilibrio ambiental hacia al impacto positivo, y la acción consciente de respecto, dignidad y equidad social durante todo su ciclo de vida; con el objetivo de poder evaluarla en todos sus aspectos y contribuir al avance de las políticas de habitabilidad, medioambiental y de responsabilidad social. Se establecen 10 apartados fundamentales: territorio, bioclimática, saludabilidad, materiales, sistemas constructivos, energías, agua, aire, residuos y gestión. Cada uno se desarrolla en forma de requerimientos, en un total de 175, que evalúan los diversos aspectos de una vivienda de Bioconstrucción. En la valoración cada requerimiento es evaluado en su relación con cada etapa del ciclo de vida de la edificación: concepción, construcción, ocupación y pos-ocupación. Así la valoración será transversal y multidisciplinar, permitiendo análisis tanto parciales como globales para que se pueda mejorar el tema que no cumple con el mínimo pedido. El resultado de la evaluación es la valoración del estado “bio” de la construcción o proyecto. Se hace la validación de la herramienta en casos estudiados. Los resultados de la investigación son la definición y la caracterización de la Bioconstrucción en España, una base de datos de más de 100 casos de estudio, una herramienta específica y validada que evidencia diversas líneas de investigación dónde profundizar y fomentar su desarrollo. Con ello, se pretende contribuir al cambio de paradigma que hace de la construcción actual un desafío hacia un contexto equilibradamente respetuoso con toda la vida que habita nuestro ecosistema. ABSTRACT This work presents a certification tool for the Bioconstrucción's housings in Spain. Based in that the Bioconstrucción is a consolidated practice in the Spanish territory, but there ins´t scientific study to define, to characterize and to verify this practice as a constructive alternative compromised with the environment and with the human health. At first we study about the specific references and them complements itself with related bibliography. By this way to have a characterization in the one that could settle the fieldwork. In the fieldwork there are verified the aspects that compose the Bioconstrucción. Cases of study have been looked diversified and a detailed evaluation of projects and constructions, as well as of the information obtained in you poll the owners and users, and to the professionals responsible for the constructive processes. With this database there were established both constructive and geographical characteristics or partner environmental, and the structure has been defined for the tool. The certification methodology proposes integrates three dimensions identified along the study of the Bioconstrucción: health, environment and social responsibility. From a systemic vision and basing in values as the promotion spaces of the human health in agreement with the bosses of the nature, the environmental balance towards to the positive impact, and the conscious action of respect, dignity and social equity during all his life cycle. With the aim to be able to evaluate it in all his aspects and contribute to the advance of the policies of habitability, environmental and of social responsibility. Ten fundamental paragraphs are established: territory, bioclimátic, saludability, materials, constructive systems, energies, water, air, residues and management. Each one develops requirements, in a total of 175, who evaluate the diverse aspects of Bioconstrucción's housing. In the valuation every requirement is evaluated in his relation by every stage of the life cycle of the building: conception, construction, occupation and post-occupation. This way we get a transverse and multidisciplinary valuation, allowing both partial and global analysis in order that it could improve the topic that does not expire with the asked minimum. The result of the evaluation is the "bio" condition of the construction or project. The validation of the tool is done in studied cases. The results of the investigation are the definition and the characterization of the Bioconstrucción in Spain, a database of more than 100 cases of study, a specific and validated tool, and diverse lines for new investigation and to promote his development. It is tried to contribute to change a paradigm that does of the current construction a challenge towards a context in a balanced way respectfully with the whole life that lives in our ecosystem.

Molinism, Open Theism, and Moral Luck

It is sometimes thought that the choice between Molinism and open theism involves a trade-off in values: Molinism asserts that God has providential power but allows God indirectly to manipulate that in virtue of which human beings are to be judged; while open theism grants human beings more power over that in virtue of which they are tp be judged, but at the price of giving up providence. I argue here that this picture is misconstrued---that Molinism gives human agents more power over that in virtue of which they may be judged than does open theism. Since open theism confines the possible avenues for evaluating agents to their behavior in the actual world, open theism is incompatible with any solution to the problem of moral luck which appeals to counterfactual behavior, and so (I argue) is impugned by the problem,. Molinists, by contrast, have a promising solution to that problem.

MARCAS ORGANIZACIONAIS E A AGREGAÇÃO DE VALOR INSTITUCIONAL POR MEIO DO INVESTIMENTO EM AÇÕES SOCIAIS ALTERNATIVAS

Em um cenário de mercado com alta competitividade e saturação, marcas e seus valores podem ter um papel decisivo na diferenciação e decisão de compra por parte dos consumidores. As marcas devem entender a necessidade da responsabilidade social e se preocuparem com questões sociais e ambientais, caso contrário, podem ser vistas com negatividade, isto é, como corporações que só desejam lucrar. Para compreender o espaço das marcas organizacionais na sociedade contemporânea, esta pesquisa apresenta um resgate de evoluções históricas, sobretudo nas últimas décadas, para mostrar os consideráveis progressos no modo de pensar em relação aos valores das marcas, ao relacionamento com públicos interessados e à sociedade em geral. É a partir destas análises que se apresenta a importância do investimento em causas sociais não como obrigação ou autopromoção, mas como abordagem que deve se tornar premissa básica e parte da cultura das organizações. O recorte desta pesquisa volta-se ao estudo de causas sociais menos difundidas ou de menor reper- cussão midiática, procurando verificar se o investimento nessas causas podem se refletir em valores para marcas, assim como se espera do apoio a causas mais conhe- cidas, como por exemplo, o câncer, a pobreza ou a fome. O estudo se complementa a partir de entrevistas em profundidade com executivos do Grupo Abril e da Volkswagen do Brasil para avaliar como estas organizações se posicionam frente à possibilidade de investir em causas menos conhecidas, como o daltonismo.

Abrasão de ferro fundido cinzento: aplicação a motores automotivos.

Uma parte significativa das perdas por atrito num motor automotivo resulta da ação de partículas abrasivas. Dentre as fontes possíveis, podem ser citados o próprio meio ambiente - partículas que passam pelo filtro de ar - o desgaste de partes metálicas do motor ou mesmo resíduos de combustão. Essas partículas podem ficar encrustadas em anéis do pistão, ou ficar na interface entre pistão e bloco ou camisa, e são responsáveis por sulcos axiais, na direção do movimento do pistão, observáveis em motores usados. O objetivo deste trabalho foi obter um melhor entendimento dos mecanismos de desgaste relacionados com o sulcamento de camisa/bloco e identificar conjuntos de testes laboratoriais capazes de reproduzi-los sob condições controladas. Amostras de ferro fundido cinzento (FoFo) e de aço AISI 1070 com dureza de matriz próxima daquela encontrada em FoFo (?200HV30) foram submetidas a ensaios de riscamento em tribômetros. Verificou-se que riscos executados com um endentador cônico submetido a cargas na faixa de 20 a 50 mN eram similares aos sulcos observados em camisas ou blocos. Ensaios com outros materiais, como alumínio e latão e mesmo aço de diferentes durezas contribuíram para melhorar o entendimento dos resultados. Não foi observada transição brusca entre mecanismos de abrasão. O cálculo do fator de remoção de material, fab, a partir de perfilometria óptica resultou em valores com dispersão elevada; não foi possível associa-los aos diferentes mecanismos de abrasão observados. Valores obtidos para o coeficiente de atrito no riscamento permitiram fazer uma estimativa inicial de energia gasta nos processos abrasivos do motor.

Características cineantropométricas en jugadores de baloncesto adolescentes

Introducción: El baloncesto presenta una gran heterogeneidad antropométrica entre jugadores en relación a la posición de juego. El base suele ser el más bajo del equipo pero también el más rápido. El escolta suele ser similar al base, más bajo, rápido y ágil que el resto. El alero es de una altura intermedia entre los jugadores interiores y exteriores, combina la altura con la velocidad, y el pívot tiene un rol más físico, es el más alto y con mayor masa muscular. El objetivo del estudio es describir el perfil cineantropométrico del equipo cadete masculino del Valencia Basket Club. Material y Métodos: Se han evaluado 20 jugadores de baloncesto cadete masculino (15,35±0,59años). Un antropometrista nivel I tomó las medidas según la metodología de la Society for the Advancement of Kinanthropometry (ISAK). Se calculó la composición corporal según el consenso de cineantropometría del Grupo Español de Cineantropometría (GREC), el somatotipo según Heath-Carter, e índices adiposo-musculares. Resultados: Se observaron diferencias en los valores de peso, talla, pliegues cutáneos y composición corporal, de las variables estudiadas de la muestra total y por posición de juego, siendo los valores menores los de la posición base y mayores en los pívots. Se estableció una tendencia creciente de estos parámetros en el siguiente orden: base, escolta, alero y pívot. Conclusiones: El somatotipo global del jugador de baloncesto cadete del Valencia Basket Club es ectomorfo balanceado. Conocer el perfil cineantropométrico puede beneficiar la elaboración de planes de entrenamiento y nutrición, así como reflejar la evolución y dirigirla hacia las características ligadas al rendimiento óptimo.

Building learning communities to support beginning teachers use of technology

This paper reports on the early stages of a three year study that is investigating the impact of a technology-enriched teacher education program on beginning teachers' integration of computers, graphics calculators, and the internet into secondary school mathematics classrooms. Whereas much of the existing research on the role of technology in mathematics learning has been concerned with effects on curriculum content or student learning, less attention has been given to the relationship between technology use and issues of pedagogy, in particular the impact on teachers' professional learning in the context of specific classroom and school environments. Our research applies sociocultural theories of learning to consider how beginning teachers are initiated into a collaborative professional community featuring both web-based and face to face interaction, and how participation in such a community shapes their pedagogical beliefs and practices. The aim of this paper is to analyse processes through which the emerging community was established and sustained during the first year of the study. We examine features of this community in terms of identity formation, shifts in values and beliefs, and interaction patterns revealed in bulletin board discussion between students and lecturers.

Dielectric relaxation of polysiloxanes and kerr effect of p-phenylene vinylene oligomers

The dielectric relaxation behaviour of a series of cyclic and linear poly(dimethylsiloxanes) with overline nn in the range 28 to 99 has been studied, as a function of temperature (142.0K-157.5K) and frequency (12-105Hz). Activation energies for the -relaxation process, Davidson-Cole empirical distribution factors, , and mean-square dipole moments per repeat unit, < 2> , have been calculated. Differences in values of H_act reflected restricted dipolar rotation for the cyclic structures, compared to the linear structures, over the range of molecular weights studied. The dielectric relaxation behaviour of a series of linear oligomers of methyl phenyl siloxane, with n in the range 4 to 10, a series of linear fractions of poly(methyl phenyl siloxane), with overline n_n in the range 31 to 1370, and a cyclic oligomer of mehyl phenyl siloxane, with n = 10, has been studied as a function of temperature (155.5K-264.0K) and frequency (12-105Hz). Activation energies for the -relaxation process, Davidson-Cole and Cole-Cole empirical distribution factors, and , respectively, and mean-square dipole moments per repeat unit have been calculated. The reduced flexibility of short methyl phenyl siloxane chains, compared to dimethyl siloxane chains, was apparent from a comparison of dipole moment ratios. The dilectric relaxation behaviour of poly(methyl hydrogen siloxane) and poly(n-hexyl methyl siloxane) has been studied as a function of temperature and frequency. A polysiloxane liquid crystal has been synthesised and its dielectric relaxation behaviour has been studied, as a function of temperature and frequency, in the liquid crystalline phase and below T_g. Poly(p-phenylene vinylene) and related oligomers have been synthesised and characterised by a variety of experimental techniques. The Kerr effect of two oligomeric fractions, in solution in PPG 2025, has been measured. The electrical conductivities of the undoped and I_2-doped polymer and oligomers have been measured.

Extração, caracterização e avaliação bioativa do extrato de Arrabidaea chica

The use of plants for medicinal purposes is ancient, with widespread application in medicinal drugs. Although plants are promising sources for the discovery of new molecules of pharmacological interest, estimates show that only 17% of them have been studied for their possible use in medicine. Thus, biodiversity of Brazilian flora represents an immense potential for economic use by the pharmaceutical industry. The plant Arrabidaea chica, popularly known as “pariri”, is common in the Amazon region, and it is assigned several medicinal properties. The leaves of this plant are rich in anthocyanins, which are phenolic compounds with high antioxidant power. Antioxidant compounds play a vital role in the prevention of neurological and cardiovascular diseases, cancer and diabetes, among others. Within the anthocyanins found in Arrabidaea chica, stands out Carajurin (6,7-dihydroxy-5,4’- dimethoxy-flavilium), which is the major pigment encountered in this plant. The present work aimed to study on supercritical extraction and conventional extraction (solid-liquid extraction) in leaves of Arrabidaea chica, evaluating the efficiency of the extractive processes, antioxidant activity and quantification of Carajurin contained in the extracts. Supercritical extraction used CO2 as solvent with addition of co-solvent (ethanol/water mixture) and were conducted by the dynamic method in a fixed bed extractor. The trials followed a 24-1 fractional factorial design, the dependent variables were: process yield, concentration of Carajurin and antioxidant activity; and independent variables were: pressure, temperature, concentration of co-solvent (v/v) and concentration of water in the co-solvent mixture (v/v). Yields (mass of dry extract/mass of raw material used) obtained from supercritical extraction ranged from 15.1% to 32%, and the best result was obtained at 250 bar and 40 °C, co-solvent concentration equal to 30% and concentration of water in the co-solvent mixture equal to 50%. Through statistical analysis, it was found that the concentration of co-solvent revealed significant effect on the yield. Yields obtained from conventional extractions were of 8.1% (water) and 5.5% (ethanol). Through HPLC (High-performance liquid chromatography) analysis, Carajurin was quantified in all the extracts and concentration values (Carajurin mass/mass of dry extract) ranged between 1% and 2.21% for supercritical extraction. For conventional extraction, Carajurin was not detected in the aqueous extract, while the ethanol extract showed Carajurin content of 7.04%, and therefore, more selective in Carajurin than the supercritical extraction. Evaluation of antioxidant power (radical 2,2-diphenyl-1-picrylhydrazyl – DPPH – sequestration method) of the supercritical extracts resulted in EC50 values (effective concentration which neutralizes 50% of free radicals) ranged from 38.34 to 86.13 μg/mL, while conventional extraction resulted in EC50 values of 167.34 (water) and 42.58 (ethanol) μg/mL. As for the quantification of total phenolic content (Folin-Ciocalteau analysis) of the supercritical extracts resulted in values ranged from 48.93 and 88.62 mg GAE/g extract (GAE = Gallic Acid Equivalents), while solid-liquid extraction resulted in values of 37.63 (water) and 80.54 (ethanol) mg GAE/g extract. The good antioxidant activity cannot be attributed solely to the presence of Carajurin, but also the existence of other compounds and antioxidants in Arrabidaea chica. By optimizing the experimental design, it was possible to identify the experiment that presented the best result considering the four dependent variables together. This experiment was performed under the following conditions: pressure of 200 bar, temperature of 40 °C, co-solvent concentration equal to 30% and concentration of water in the co-solvent mixture equal to 30%. It is concluded that, within the studied range, it is possible to purchase the optimum result using milder operating conditions, which implies lower costs and greater ease of operation.

Archaeological otoliths as environmental recorders: high resolution sampling of pacific cod (Gadus macrocephalus) otoliths from Kiska Island, Alaska

Archaeological fish otoliths have the potential to serve as proxies for both season of site occupation and palaeoclimate conditions. By sampling along the distinctive sub-annual seasonal bands of the otolith and completing a stable isotope (δ¹⁸O, δ¹³C) analysis, variations within the fish’s environment can be identified. Through the analysis of cod otoliths from two archaeological sites on Kiska Island, Gertrude Cove (KIS-010) and Witchcraft Point (KIS-005), this research evaluates a micromilling methodological approach to extracting climatic data from archaeological cod otoliths. In addition, δ¹⁸Ootolith data and radiocarbon dates frame a discussion of Pacific cod harvesting, site occupation, and changing climatic conditions on Kiska Island. To aid in the interpretation of the archaeological Pacific cod results, archaeological and modern Atlantic cod otoliths were also analyzed as a component of this study to develop. The Atlantic cod otoliths provided the methodological and interpretative framework for the study, and also served to assess the efficacy of this sampling strategy for archaeological materials and to add time-depth to existing datasets. The δ¹⁸Ootolith values successfully illustrate relative variation in ambient water temperature. The Pacific cod δ¹⁸O values demonstrate a weak seasonal signal identifiable up to year 3, followed by relatively stable values until year 6/7 when values continuously increase. Based on the δ¹⁸O values, the Pacific cod were exposed to the coldest water temperatures immediately prior to capture. The lack of a clear cycle of seasonal variation and the continued increase in values towards the otolith edge obscures the season of capture, and indicates that other behavioural, environmental, or methodological factors influenced the otolith δ¹⁸O values. It is suggested that Pacific cod would have been harvested throughout the year, and the presence of cod remains in Aleutian archaeological sites cannot be used as a reliable indicator of summer occupation. In addition, when the δ¹⁸O otolith values are integrated with radiocarbon dates and known climatic regimes, it is demonstrated that climatic conditions play an integral role in the pattern of occupation at Gertrude Cove. Initial site occupation coincides with the end of a neoglacial cooling period, and the most recent and continuous occupation coincides with the end of a localized warming period and the onset of the Little Ice Age (LIA).