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为了探讨城市森林三维绿量的测算方式及精度,该文利用2001年8月沈阳市真彩航片和抽样调查,借助ARC/GIS,以“立体量推算立体量”的方法测算沈阳城市森林三维绿量.结果表明,不同城市森林类型的单位面积三维绿量以风景游憩林最高,为5.35 m3/m2,附属林4.93 m3/m2,道路林3.65 m3/m2,生态公益林3.62 m3/m2,生产经营林2.35m3/m2;城市森林分布区的单位面积三维绿量为4.25 m3/m2;城区单位面积城市森林三维绿量为0.35 m3/m2.沈阳城市森林总体三维绿量为161 296 716.85 m3,其中附属林为60 116 966.36 m3,占37.27%,生态公益林43 321 771.43 m3,占26.86%,风景游憩林30 482 879.04 m3,占18.90%,道路林23 841 208.75 m3,占14.78%,生产经营林3 533 891.27 m3,占2.19%.经检验,该方法精度达到85.50%(α=0.05).

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通过卵面微量添食葡萄糖、有益微生物 (EM)及CaCl2 3种物质 ,以半数致死时间 (LT50 )为指标 ,研究添食不同物质对柞蚕初孵蚁蚕抗逆性的影响。结果表明 ,卵面添食这 3种物质均能增强蚁蚕的抗低温能力 ,延长其在低温条件下的半数致死时间 (LT50 )。添食葡萄糖能显著延长蚁蚕对饥饿的LT50 ;添食EM能极显著延长蚁蚕对饥饿的LT50 ;添食CaCl2 对蚁蚕耐饥饿能力的影响不显著。各种添食物质对蚁蚕抗逆性的影响均存在浓度效应

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小尺寸目标跟踪是视觉跟踪中的难题。本文使用均值移动算法跟踪小尺寸目标。论文首先分析了基于均值移动的小尺寸目标跟踪算法的两个主要问题:跟踪算法中断和跟踪目标丢失。然后,论文在这两个方面对小尺寸目标跟踪算法进行改进。给出了一种新的直方图单元编号方法,使包含目标颜色分量的直方图单元分布得更为集中紧凑。当候选目标与目标模型不匹配时,给出一种平滑算法来处理候选目标的直方图。论文提出一种新的相似性度量函数,推导了相应的权值计算公式,在此基础上建立了基于均值移动的目标跟踪算法。多段真实场景视频序列的跟踪实验表明,本文提出的算法可以有效地跟踪小尺寸目标,跟踪精度也有一定提高。

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目的研究气候变化与人间鼠疫流行之间的关系。方法选择内蒙古和福建省分别作为我国北方和南方鼠疫疫源地和历史鼠疫病区的典型省,采用对比分析和相关分析的方法,研究气候变化(降水变化以旱涝指数表示,气温变化以冷暖指数表示)与人间鼠疫发病强度之间的关系。结果在北方地区,人间鼠疫发病强度与前一年和当年的旱涝指数及冷暖指数呈显著负相关;而在南方地区,人间鼠疫的发病强度仅与当年秋季的冷暖指数有显著负相关性。结论气候变化与鼠疫流行之间的关系有明显的区域差异。降水丰富及气候温暖利于北方鼠疫的流行与传播;降水变化对南方鼠疫的流行没有明显的影响,秋冬季的气温与南方鼠疫的流行强度有一定的正相关关系。

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研究了La3+或Eu3+与微过氧化酶-8(MP-8)相互作用并比较了它们与MP-8相互作用的强弱.紫外-可见(UV-Vis)吸收光谱和电化学的结果表明,不论在不含NaCl或含NaCl的溶液中,一个La3+或Eu3+优先与MP-8分子中血红素上两个丙酸基中的羧基氧发生强的键合作用,而过量的La3+或Eu3+与肽链上的羰基氧发生弱的相互作用.实验结果还清楚地证明Eu3+与MP-8的相互作用要强于La3+与MP-8的相互作用.

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A novel organic-inorganic composite film was formed by attaching Keegin-type heteropolyanion, SiW12O404- (devoted briefly as SiW12), on a glassy carbon electrode derivatized by 4-aminophenyl group. The composite film has an ionic bonding character between SiW12 and the surface amino group, which greatly improves the Blm stability and exhibits a more reversible electrochemical behavior. The modified electrode offers an excellent and stable electrocatalytic response for the reduction of nitrite. Possible mechanism was provided for the reaction of nitrite with SiW12O404-/aminophenyl composite film.

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Thirteen title complexes ROCOCH2CH2SnCl3 . L(R = C(1 similar to 5)alkyl;L = DBSO,HMPA) were synthesized and characterized by elemental analysis, IR,H-1 NMR. The crystal structure of n -PrOCOCH2CH2SnCl3 . DBSO was determined by the X-ray diffraction analysis. The crystal belongs to orthorhombic system,space group P2(1)2(1)2(1) with a = 1.062, b = 1.427, c = 1.635nm; Z = 4. The complex exists as a discrete molecule, and the tin atom attains a distorted octahedral geometry via the coordination of intramolecular carbonyl oxygen and the Lewis base donor atom. The transesterification of CH3OCOCH2CH2SnCl3 . L with alcohol was studied, and the intramolecular Lewis acid catalytic mechanism was suggested.

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合成了13个标题化合物POCOCH_2CH_2SnCl_3·L(R=C_(1~5)烷基;L=DBSO,HMPA),通过元素分析、IR和~1H NMR进行了表征.n-PrOCOCH_2CH_2SnCl_3·DBSO的晶体结构分析表明,该晶体属正交晶系;空间群P2_12_12_1;a=1.062,b=1.427,c=1.635nm;Z=4.该化合物为含有分子内碳基配位和Lewis碱配体配位的具有畸变八面体构型的单分子有机锡化合物.研究了CH_3OCOCH_2CH_2SnCl_3·L和醇的酯交换反应,提出了分子内Lewis酸催化的反应机理.

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The title complex, tris[2(eta5)-tert-butylcyclopentadi-enyl]-mu-chloro-1:2kappa2Cl-tris(tetrahydrofuran-1kappaO)lithiumneodymium, [Nd(C9H13)3(mu-Cl)Li(C4H8O)3], consists of the neutral moiety ((t)BuCp)3Nd linked to the cation [Li(thf)3]+ by a mu-Cl bridge

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本文利用聚苯胺薄膜化学修饰电极对巯基化合物的促进作用进行了研究,结果表明,这种促进作用是对巯基乙醇在PAn薄膜表面的氧化还原过程的一种加强,而这种加强作用是通过-SH与PAn中的N以质子形式加成的。

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用丙酮作溶剂,提取糖甜菜中含有的丰富酪氨酸氧化酶,将所得丙酮粉浆固定于氧电极,制成的酪氨酸电极,在0.05~0.5mmol/L浓度范围内与输出信号值有线性关系。研究了电极的制备及操作条件,电极寿命可达30天。

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A FeNiSiBV amorphous composite coating was developed by laser cladding of metallic powders on AISI 1020 low carbon steel substrate. The coatings were studied using X-ray diffraction, transmission electron microscopy and scanning electron microscopy. The coating reveals different microstructures along the depth of the coating. The transition zone exhibits good metallurgical bonding between the substrate and the coating. The layer consists of amorphous phase in majority and nanocrystalline phase/crystalline phase in minority. Accompanied with the nanocrystalline phase, the amorphous phase is concentrated in the middle of the coating. The crystalline phase in the coating is identified as Fe2B. A gradient distribution of the microhardness ranges from 1208 HV0.2 to 891 HV0.2 in the coating along the depth. The coating shows higher microhardness and better wear property than the substrate.

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目的 比较藏药“藏茵陈”原植物川西獐牙菜及近年市场出现混淆种类的ITS序列 ,为分子序列鉴定提供参照系统并为寻找新的药用植物来源提供分子证据。方法 利用PCR扩增和ABI377自动测序。结果 川西獐牙菜不同居群间的序列相同 ,与其混淆种类之间存在一定的分子序列差异 ,有其特定的分子序列 ;利用Paup程序聚类分析表明川西獐牙菜与抱茎獐牙菜聚在一起。结论 ITS序列可正确鉴定川西獐牙菜与其混淆种类 ,他们之间的分子序列差异为进一步设计特异性分子鉴定试剂盒提供了科学依据 ;抱茎獐牙菜可考虑作为“藏茵陈”药材的新植物来源。

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胶东地区脉岩属碱性超基性岩系(Na2O+K2O=4.67%~5.43%;SiO2=36.70%-39.99%),岩性为单一的橄榄辉石岩。从主量元素(包括CIPW标准矿物组成)和过渡元素组成来看,该岩系近似原始岩浆组成。电子探针结果显示:橄榄石为富镁质橄榄石(贵橄榄石)(Fo=71—90),单斜辉石为透辉石(次透辉石为主)。岩石富集大离子亲石元素(K、Rb、Sr、Th和Ba),但不具有高场强元素(Nb、Ta、Zr和Hf)的亏损,表明岩石形成于大陆板内环境。为地幔橄榄岩低度部分熔融(3.4%)的产物。同时,它具有大陆边缘弧的特性。暗示其为一种滞后型弧岩浆作用的产物。稀土元素特征显示,岩石强烈富集LREE,而相对亏损HREE,暗示了源区的富集特性。Eu/Eu^+=0.89—1.00,总体不表现明显的负Eu异常,暗示斜长石不是主要的分馏矿物相。结合板内碱性岩石的矿物结晶顺序认为,本区岩浆分馏以较弱的橄榄石分馏为主。