长白山阔叶红松林近22年的气候动态

长白山阔叶红松林作为典型的温带森林生态系统,其长期的气候动态状况对研究全球变化具有重要的意义。本文采用中国科学院长白山森林生态系统定位站气象观测场1982~2003年的地面常规气象观测资料,对长白山阔叶红松林的光能因子(包括年日照时数、年日照百分率)、热量因子(包括年平均气温、1月、7月月平均气温、年极端最高、最低气温、年积温)、水分因子(包括年总降水量、年最大雪深、相对湿度、年总蒸发量)、以及年平均风速与风向等气候因子进行了分析,从而得出这些因子22年的平均值及其动态变化趋势,进而为相关领域的研究提供基础资料。

Comparison of 6Mo/MCM-22 and 6Mo/ZSM-5 in the MDA process

A comparison of methane dehydroaromatization (MDA) on 6Mo/MCM-22 and 6Mo/ZSM-5 was carried out using a gas mixture of 90%CH4, 2%CO2 and 8%Ar as the feed. The results indicate that the stability of 6Mo/MCM-22 is better than that of 6Mo/ZSM-5. A detailed study reveals that the ability for coke accommodation and the retention of the shape selectivity for aromatics formation is responsible for the stability of a MDA catalyst.

The role of coke in the deactivation of Mo/MCM-22 catalyst for methane dehydroaromatization with CO2

The effect of space velocity on reaction performance and coke deposition over 6Mo/MCM-22 catalyst in methane dehydro-aromatization (MDA) with CO2 were studied. The characterization of catalysts reacted at different space velocity after the same amount of methane feed by TG, TPO and Benzene/NH3-TPD techniques suggested that the inert coke maybe responsible for the deactivation of catalyst because of its blockage effect for pore system.

Shape selectivity in methane dehydroaromatization over Mo/MCM-22 catalysts during a lifetime experiment

Dehydroaromatization of CH4 with 2% CO2 on 6Mo/MCM-22 in a 100-h lifetime test was carried out at 993 K, atmospheric pressure and 1500 mL/gh. The duration of the lifetime test can be divided into an induction stage, stable stage and deactivation stage on the basis of the selectivities of hydrocarbons and coke. The characteristics of deposited coke with different time onstream were studied using TPO and TG techniques. There were two peaks corresponding to two kinds of coke recorded in TPO profiles, and the oxidation temperature of coke shifted to higher values with less hydrogen content with the increase of coke deposits. BET and Benzene-TPD techniques were employed to study the variation of specific surface area of the external and micropore surface versus time onstream. With the accumulation of coke deposits, although the pores became partially blocked and the internal surface decreased, methane could still enter the channel and was converted to benzene with shape selectivity until a critical value of coke deposition was reached.

科尔沁沙地22种菊科草本植物叶片形态特征研究

以内蒙古科尔沁沙地22种菊科草本植物为实验材料,研究这些植物的比叶面积、叶片厚度、叶片干物质含量、叶片体积、叶重比和叶片组织密度等特性之间的关系。结果表明,叶片体积和叶片厚度之间存在较强的正相关,其相关系数r=0.782。而叶片厚度与叶片组织密度、比叶面积与叶片组织密度、叶片体积与叶片组织密度之间则存在一定的负相关性,它们的相关系数分别为-0.767、-0.559和-0.505,其余各特性之间均不存在相关性。根据赋值后数据或者二元数据,运用聚类分析方法得出3个组群,并运用单因素方差分析方法检验各特性在各组间的显著性,叶片厚度、叶片体积、叶重比和叶片组织密度特性在组间存在极显著差异。

土壤养分对小偃22叶片光合特性影响的初步研究

在大田不同供肥条件下 ,于小麦灌浆后期对小麦旗叶光合特性参数进行了连续测定。结果表明 ,小麦叶片气体交换参数均有明显的日变化趋势 ,肥力条件对其日变化进程具有明显的调控作用。不施肥处理小麦叶片 Pn有明显午休现象 ,而低肥处理第一高峰不明显 ,没有明显午休现象 ;高肥处理的 Pn呈单峰曲线 ,峰值来得也较晚。养分条件可改善小麦叶片水分利用效率