Propriétés des monocouches auto-assemblées du liquide ionique 1-(12-mercaptododécyl)-3-méthylimidazolium

Les propriétés d'une nouvelle classe de chimie de surface basée sur les monocouches auto-assemblées de liquides ioniques (ILs-SAMs), ont été étudiées pour une utilisation dans la construction de biocapteurs basés sur la résonance des plasmons de surface (SPR). Les biocapteurs sont utiles pour détecter des biomolécules spécifiques dans une matrice biologique complexe. Cependant, le signal analytique de la biomolécule spécifique peut être masqué par l’adsorption non spécifique de la matrice biologique, produisant une réponse faussement positive. Par ailleurs, l'activité des récepteurs moléculaires est souvent réduite par des techniques d'immobilisation chimique. Ainsi, il est essentiel de déterminer une surface idéale pour la préparation de biocapteurs. Les liquides ioniques sont bien connus pour favoriser l'activité des récepteurs moléculaires et cette étude enquête si cette propriété importante peut se traduire sur des capteurs SPR. Différents liquides ioniques ont été utilisés pour former des monocouches auto-assemblées sur une surface d'or. Les ILs-SAMs sont tous basés sur les sels de mercapto-(chaîne alkyle)nCH2-méthylimidazolium avec différentes chaînes alkyles (n = 3, 6, 9, 12) et différents contre-anions (Br-, BF4-, PF6-, NTf2-). Des études cinétiques de l'adsorption non spécifique de sérum bovin ont été réalisées sur des capteurs SPR avec un instrument construit sur mesure, basé sur l'interrogation des longueurs d’ondes SPR sur un prisme d’inversion d’image (dove). Par la suite, l’anti-IgG de chèvre sélective à l’IgG humain a été utilisé en tant que modèle pour la confection de biocapteurs sur les ILs-SAMs. En solution, il est possible d’effectuer des échanges du contre-anion des liquides ioniques pour un contre-anion de plus en plus hydrophobe. Cependant, l’échange inverse, soit vers des anions de plus en plus hydrophile, s’avère impossible. Toutefois, il a été observé par les travaux présentés dans ce mémoire, que les liquides ioniques immobilisés sur une surface d'or ont la capacité d'échanger leurs contre-anions réversiblement, procurant une méthode simple de moduler leurs propriétés physico-chimiques. Ce phénomène a été observé par la mesure d’angles de contacts et par les techniques spectroscopiques de l’infrarouge moyen (mid-IR), des photoélectrons de rayon-X (XPS) et par la diffusion Raman exaltée par les surfaces (SERS) ii ainsi que par la spectrométrie de masse (MS). La connaissance des propriétés d’échange d’anion est importante pour prédire le comportement de ces surfaces de liquides ioniques dans les tampons et fluides biologiques.

An intrinsic biochemical concentration sensor using a polymer optical fibre Bragg grating

A new type of fibre-optic biochemical concentration sensor based on a polymer optical fibre Bragg grating (POFBG) is proposed. The wavelength of the POFBG varies as a function of analyte concentration. The feasibility of this sensing concept is demonstrated by a saline concentration sensor. When polymer fibre is placed in a water based solution the process of osmosis takes place in this water-fibre system. An osmotic pressure which is proportional to the solution concentration, will apply to the fibre in addition to the hydraulic pressure. It tends to drive the water content out of the fibre and into the surrounding solution. When the surrounding solution concentration increases the osmotic pressure increases to drive the water content out of the fibre, consequently increasing the differential hydraulic pressure and reducing the POFBG wavelength. This process will stop once there is a balance between the osmotic pressure and the differential hydraulic pressure. Similarly when the solution concentration decreases the osmotic pressure decreases, leading to a dominant differential hydraulic pressure which drives the water into the fibre till a new pressure balance is established. Therefore the water content in the polymer fibre - and consequently the POFBG wavelength - depends directly on the solution concentration. A POFBG wavelength change of 0.9 nm was measured for saline concentration varying from 0 to 22%. For a wavelength interrogation system with a resolution of 1 pm, a measurement of solution concentration of 0.03% can be expected.

An intrinsic biochemical concentration sensor using a polymer optical fibre Bragg grating

A new type of fibre-optic biochemical concentration sensor based on a polymer optical fibre Bragg grating (POFBG) is proposed. The wavelength of the POFBG varies as a function of analyte concentration. The feasibility of this sensing concept is demonstrated by a saline concentration sensor. When polymer fibre is placed in a water based solution the process of osmosis takes place in this water-fibre system. An osmotic pressure which is proportional to the solution concentration, will apply to the fibre in addition to the hydraulic pressure. It tends to drive the water content out of the fibre and into the surrounding solution. When the surrounding solution concentration increases the osmotic pressure increases to drive the water content out of the fibre, consequently increasing the differential hydraulic pressure and reducing the POFBG wavelength. This process will stop once there is a balance between the osmotic pressure and the differential hydraulic pressure. Similarly when the solution concentration decreases the osmotic pressure decreases, leading to a dominant differential hydraulic pressure which drives the water into the fibre till a new pressure balance is established. Therefore the water content in the polymer fibre - and consequently the POFBG wavelength - depends directly on the solution concentration. A POFBG wavelength change of 0.9 nm was measured for saline concentration varying from 0 to 22%. For a wavelength interrogation system with a resolution of 1 pm, a measurement of solution concentration of 0.03% can be expected.

Extended range interrogation of wavelength division multiplexed fibre Bragg grating sensors using an arrayed waveguide grating

A technique for interrogating multiplexed fibre Bragg grating (FBG) sensors using an arrayed waveguide grating (AWG) is described. The approach considerably extends the sensing range from that achieved previously, while providing a strain resolution of 17nevHz at 30 Hz.

Extended range interrogation of wavelength division multiplexed fibre Bragg grating sensors using arrayed waveguide grating

A technique for interrogating multiplexed fibre Bragg grating (FBG) sensors using an arrayed waveguide grating (AWG) is described. The approach considerably extends the sensing range from that achieved previously, while providing a strain resolution of 17nε/√Hz at 30 Hz.

Highly sensitive liquid-level sensor based on dual-wavelength double-ring fiber laser assisted by beat frequency interrogation

A highly sensitive liquid-level sensor based on dual-wavelength single-longitudinal-mode fiber laser is proposed and demonstrated. The laser is formed by exploiting two parallel arranged phase-shift fiber Bragg gratings (ps-FBGs), acting as ultra-narrow bandwidth filters, into a doublering resonators. By beating the dual-wavelength lasing output, a stable microwave signal with frequency stability better than 5 MHz is obtained. The generated beat frequency varies with the change of dual-wavelength spacing. Based on this characteristic, with one ps-FBG serving as the sensing element and the other one acting as the reference element, a highly sensitive liquid level sensor is realized by monitoring the beat frequency shift of the laser. The sensor head is directly bonded to a float which can transfer buoyancy into axial strain on the fiber without introducing other elastic elements. The experimental results show that an ultra-high liquidlevel sensitivity of 2.12 × 107 MHz/m within the measurement range of 1.5 mm is achieved. The sensor presents multiple merits including ultra-high sensitivity, thermal insensitive, good reliability and stability. © 2012 Optical Society of America.

Wavelength-division and spatial multiplexing using tandem interferometers for Bragg grating sensor networks

We present a new method for the interrogation of large arrays of Bragg grating sensors. Eight gratings operating between the wavelengths of 1533 and 1555 nm have been demultiplexed. An unbalanced Mach—Zehnder interferometer illuminated by a single low-coherence source provides a high-phase-resolution output for each sensor, the outputs of which are sequentially selected in wavelength by a tunable Fabry-Perot interferometer. The minimum detectable strain measured was 90 ne-vHz at 7 Hz for a wavelength of 1535 nm.

Interferometric sensor interrogation using an arrayed waveguide grating

We experimentally investigate the use of an arrayed waveguide grating (AWG) to interrogate interferometric sensors. A single broad-band light source is used to illuminate the system. Reflected spectral information is directed to an AWG with integral photodetectors providing 40 electrical outputs. We show that using the dual-wavelength technique we can measure the length of a Fabry-Perot cavity by determining the optical phase changes of the scanned interferometric pattern, which produced a maximum unambiguous range of 1440 mum with an active sensor and a maximum unambiguous range of 300 mum with the introduction of a second processing interferometer, which allows the sensor to be passive.

Simultaneous interrogation of fiber Bragg grating sensors using an acoustooptic tunable filter

We describe a novel technique to provide demultiplexing of fiber Bragg grating sensors, interrogated using interferometric wavelength shift detection. Amplitude modulation of multiple radio frequency driving signals allows an acoustooptic tunable filter to provide wavelength demultiplexing. We demonstrated a noise limited strain resolution of 150 nanostrain/v(Hz) and a crosstalk better than -50 dB.

Interrogation of fibre Bragg grating sensors using an arrayed waveguide grating

We experimentally investigate the use of an arrayed waveguide grating (AWG) to interrogate fibre Bragg grating (FBG) sensors. A broadband light source is used to illuminate the FBG sensors. Reflected spectral information is directed to the AWG containing integral photodetectors providing 40 electrical outputs. Three methods are described to interrogate FBG sensors. The first technique makes use of the wavelength-dependent transmission profile of an AWG channel passband, giving a usable range of 500 µe and a dynamic strain resolution of 96 ne Hz-1/2 at 13 Hz. The second approach utilizes wide gratings larger than the channel spacing of the AWG; by monitoring the intensity present in several neighbouring AWG channels an improved range of 1890 µe was achieved. The third method improves the dynamic range by utilizing a heterodyne approach based on interferometric wavelength shift detection, providing an improved dynamic strain resolution of 17 ne Hz-1/2 at 30 Hz.

Fiber Bragg grating sensor interrogation system using a CCD side detection method with Superimposed blazed gratings

We present, for the first time to our knowledge, experimental evidence showing that superimposed blazed fiber Bragg gratings may be fabricated and used to extend the dynamic range of a grating-based spectrometer. Blazed gratings of 4° and 8° were superimposed in germanosilicate fiber by ultraviolet inscription and used in conjunction with a coated charged-coupled device array to interrogate a wavelength-division-multiplexing sensor array. We show that the system can be used to monitor strain and temperature sensors simultaneously with an employable bandwidth which is extendable to 70 nm.

Optical fibre sensors and their interrogation

This thesis describes novel developments in the fabrication and understanding of type IA fibre Bragg gratings, the uses of said gratings as optical sensors and the interrogation of optical sensors using tilted fibre Bragg gratings. This thesis presents the most detailed study of type IA gratings performed to date and provides the basis of a dual grating optical sensor capable of independently measuring strain and temperature. Until this work it was not known how to reliably fabricate type IA gratings or how they would react to high ambient temperatures, nor was it known what effect external parameters such as fibre type, dopant levels, inscription laser intensity, or hydrogenation levels would have on the physical properties of the grating. This comprehensive study has yielded answers to all of these unknowns and produced several unexpected uses for type IA gratings, such as the use of the previously unreported strong loss band at 1400nm to locally heat fibres by optical absorption and thereby fabricate optically tuneable gratings which do not affect directly adjacent standard gratings. Blazed fibre Bragg gratings have been studied in detail and used to produce several high quality prototype sensor interrogation systems yielding stability an accuracy values unsurpassed by similar devices reported in literature. An accurate distribution map of light radiated by blazed gratings is shown for the first time and has been studied in respect of polarisation state showing that for certain easily achievable conditions a blazed grating spectrometer may be deemed to be polarisation insensitive. In a novel implementation of the system, it is shown that the dynamic wavelength range of a blazed grating spectrometer may be at least doubled by superimposing blazed gratings.

Resonant cavity Fibre Bragg grating sensor interrogation

This thesis presents a novel high-performance approach to time-division-multiplexing (TDM) fibre Bragg grating (FBG) optical sensors, known as the resonant cavity architecture. A background theory of FBG optical sensing includes several techniques for multiplexing sensors. The limitations of current wavelength-division-multiplexing (WDM) schemes are contrasted against the technological and commercial advantage of TDM. The author’s hypothesis that ‘it should be possible to achieve TDM FBG sensor interrogation using an electrically switched semiconductor optical amplifier (SOA)’ is then explained. Research and development of a commercially viable optical sensor interrogator based on the resonant cavity architecture forms the remainder of this thesis. A fully programmable SOA drive system allows interrogation of sensor arrays 10km long with a spatial resolution of 8cm and a variable gain system provides dynamic compensation for fluctuating system losses. Ratiometric filter- and diffractive-element spectrometer-based wavelength measurement systems are developed and analysed for different commercial applications. The ratiometric design provides a low-cost solution that has picometre resolution and low noise using 4% reflective sensors, but is less tolerant to variation in system loss. The spectrometer design is more expensive, but delivers exceptional performance with picometre resolution, low noise and tolerance to 13dB system loss variation. Finally, this thesis details the interrogator’s peripheral components, its compliance for operation in harsh industrial environments and several examples of commercial applications where it has been deployed. Applications include laboratory instruments, temperature monitoring systems for oil production, dynamic control for wind-energy and battery powered, self-contained sub-sea strain monitoring.

Low-cost interrogation of optical fibre Bragg grating sensors

Through the application of novel signal processing techniques we are able to measure physical measurands with both high accuracy and low noise susceptibility. The first interrogation scheme is based upon a CCD spectrometer. We compare different algorithms for resolving the Bragg wavelength from a low resolution discrete representation of the reflected spectrum, and present optimal processing methods for providing a high integrity measurement from the reflection image. Our second sensing scheme uses a novel network of sensors to measure the distributive strain response of a mechanical system. Using neural network processing methods we demonstrate the measurement capabilities of a scalable low-cost fibre Bragg grating sensor network. This network has been shown to be comparable with the performance of existing fibre Bragg grating sensing techniques, at a greatly reduced implementation cost.

A novel sensor interrogation technique using chirped fiber grating based sagnac loop

We demonstrate a novel and simple sensor interrogation scheme for fiber Bragg grating (FBG) based sensing systems. In this scheme, a chirped FBG based Sagnac loop is used as a wavelength-dependent receiver, and a stable and linear readout response is realised. It is a signijkant advantage of this scheme that the sensitivity and the measurement wavelength range can be easily adjhsted by controlling the chirp of the FBG or using an optical delay line in the Sagnac loop.