Modeling of phase equilibrium and vapor adsorption on carbon black based on a combination of a lattice theory and equation of state

A thermodynamic approach is developed in this paper to describe the behavior of a subcritical fluid in the neighborhood of vapor-liquid interface and close to a graphite surface. The fluid is modeled as a system of parallel molecular layers. The Helmholtz free energy of the fluid is expressed as the sum of the intrinsic Helmholtz free energies of separate layers and the potential energy of their mutual interactions calculated by the 10-4 potential. This Helmholtz free energy is described by an equation of state (such as the Bender or Peng-Robinson equation), which allows us a convenient means to obtain the intrinsic Helmholtz free energy of each molecular layer as a function of its two-dimensional density. All molecular layers of the bulk fluid are in mechanical equilibrium corresponding to the minimum of the total potential energy. In the case of adsorption the external potential exerted by the graphite layers is added to the free energy. The state of the interface zone between the liquid and the vapor phases or the state of the adsorbed phase is determined by the minimum of the grand potential. In the case of phase equilibrium the approach leads to the distribution of density and pressure over the transition zone. The interrelation between the collision diameter and the potential well depth was determined by the surface tension. It was shown that the distance between neighboring molecular layers substantially changes in the vapor-liquid transition zone and in the adsorbed phase with loading. The approach is considered in this paper for the case of adsorption of argon and nitrogen on carbon black. In both cases an excellent agreement with the experimental data was achieved without additional assumptions and fitting parameters, except for the fluid-solid potential well depth. The approach has far-reaching consequences and can be readily extended to the model of adsorption in slit pores of carbonaceous materials and to the analysis of multicomponent adsorption systems. (C) 2002 Elsevier Science (USA).

Computer programs for analysis of droplets sprayed on water sensitive papers

The use of water-sensitive papers is an important tool for assessing the quality of pesticide application on crops, but manual analysis is laborious and time-consuming. Thus, this study aimed to evaluate and compare the results obtained from four software programs for spray droplet analysis in different scanned images of water-sensitive papers. After spraying, papers with four droplet deposition patterns (varying droplet spectra and densities) were analyzed manually and by means of the following computer programs: CIR, e-Sprinkle, DepositScan and Conta-Gotas. The diameter of the volume and number medians and the number of droplets per target area were studied. There is a strong correlation between the values measured using the different programs and the manual analysis, but there is a great difference between the numerical values measured for the same paper. Thus, it is not advisable to compare results obtained from different programs.

MESON PROPERTIES FROM A BAG MODEL COMPARED TO LATTICE THEORY AND HEAVY-ION EXPERIMENTS

A bag at temperature (T) with pressure B(T) = B(0)[1 - (T/T(c))4] is shown to be consistent with recent lattice data on the pi and the rho mesons. The limiting temperature, T(l), of the pion bag from the Bekenstein entropy bound is lower than that of other mesons. This agrees with the thermal distribution of pi, K and the rho in heavy ion collisions, which (unlike proton-nucleus or pp data) show a marked difference in T of pion and other mesons in the mid-rapidity region.

Computer programs for safety analysis.

Federal Highway Administration, Office of Implementation, Washington, D.C.

Computer programs for safety analysis: HISAM users manual and operators guide.

Federal Highway Administration, Washington, D.C.

Computer programs for safety analysis: HISAFE users manual and operators guide.

Federal Highway Administration, Office of Research and Development, McLean, Va.

Products from two computer programs which process digital bathymetric data /

"October 1981."

Report from Task Force on Hydrologic Computer Programs.

Mode of access: Internet.

Documentation of computer programs and automated data systems : proceedings of a symposium held at the National Bureau of Standards, Gaithersburg, MD, October 12, 1976 /

Mode of access: Internet.

Osiris III; an integrated collection of computer programs for the management and analysis of social science data.

v. 1. System and program description.--v. 2. Error Messages.--v. 3. Summary of control cards.--v. 4. Sample jobs.--v. 5. Formulas and statistical references.--v. 6. Primer.

Computer programs for assessing required mission sizes and damage to ground targets in tactical air current operations planning.

"Prepared under Contract AF 19(628)-4805 by the Cornell Aeronautical Laboratory, Inc., of Cornell University."

Computer programs used to analyze wind and bridge data acquired at Sitka, Alaska /

Mode of access: Internet.

Summary of selected computer programs produced by the U.S. Geological Survey for simulation of ground-water flow and quality, 1994 /

Mode of access: Internet.