Overcoming performance and convergence issues of discrete transform based modeling of crosslinking classical and reversible deactivated radical polymerizations

Population balances of polymer species in terms 'of discrete transforms with respect to counts of groups lead to tractable first order partial differential equations when ali rate constants are independent of chain length and loop formation is negligible [l]. Average molecular weights in the absence ofgelation are long known to be readily found through integration of an initial value problem. The extension to size distribution prediction is also feasible, but its performance is often lower to the one provided by methods based upon real chain length domain [2]. Moreover, the absence ofagood starting procedure and a higher numerical sensitivity hás decisively impaired its application to non-linear reversibly deactivated polymerizations, namely NMRP [3].

A new plant growth system rig based on thermodynamic solar energy: a study for energy efficiency assessment

At the present there is a high pressure toward the improvement of all production processes. Those improvements can target distinct factors along the production chain. In particular, and due to recent tight energy efficiency policies, those that involve energy efficiency. As can be expected, agricultural processes are not immune to this tendency. Even more when dealing with indoor productions. In this context, this work presents an innovative system that aims to improve the energy efficiency of a trees growing platform. This improvement in energy consumption is accomplished by replacing an electric heating system by one based on thermodynamic panels. The assessment of the heating fluid caudal and its temperature was experimentally obtained by means of a custom made scaled prototype whose actuators status are commanded by a Fuzzy-based controller. The obtained results suggest that the change in the heating paradigm will lead to overall savings that can easily reach 60% on the energy bill.