Online impedance spectroscopy estimation of a battery

Electrochemical impedance spectroscopy (EIS) is a helpful tool to understand how a battery is behaving and how it degrades. One of the disadvantages is that it is typically an 'off-line' process. This paper investigates an alternative method of looking at impedance spectroscopy of a battery system while it is on-line and operational by manipulating the switching pattern of the dc-dc converter to generate low frequency harmonics in conjunction with the normal high frequency switching pattern to determine impedance in real time. However, this adds extra ripple on the inductor which needs to be included in the design calculations. The paper describes the methodology and presents some experimental results in conjunction with EIS results to illustrate the concept.

Co3O4 nanostructures with a high rate performance as anode materials for lithium-ion batteries, prepared via book-like cobalt-organic frameworks

The self-assembly of cobalt coordination frameworks (Co-CPs) with a two-dimensional morphology is demonstrated by a solvothermal method. The morphology of the Co-CPs has been controlled by various solvothermal conditions. The two-dimensional nanostructures agglomerated by Co3O4 nanoparticles remained after the pyrolysis of the Co-CPs. The as-synthesized Co3O4 anode material is characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge measurements. The morphology of Co3O4 plays a crucial role in the high performance anode materials for lithium batteries. The Co3O4 nanoparticles with opened-book morphology deliver a high capacity of 597 mA h g-1 after 50 cycles at a current rate of 800 mA g-1. The opened-book morphology of Co3O4 provides efficient lithium ion diffusion tunnels and increases the electrolyte/Co3O4 contact/interfacial area. At a relatively high current rate of 1200 mA g-1, Co3O4 with opened-book morphology delivers an excellent rate capability of 574 mA h g-1.