The geochemistry of radioactive waste disposal

The present study attempted to identify the significant parameters which affect radionuclide migration from a low level radioactive waste disposal site located in a clay deposit. From initial sorption studies on smectite minerals, increased Kd with decreasing initial cation concentration was observed, and three sorption mechanisms were identified. The observation of anion dependent sorption was related to the existence of a mechanism in which an anion-cation pair are bound to the clay surface through the anion. The influence of competing cations, typical of inorganic groundwater constituents, depended on: (1) Ni/Co:Mn+(Mn+ = competing cation) ratio, (2) nature of M^n+, (3) total solution ionic strength. The presence of organic material in groundwater is well documented, but its effect on cation sorption has not been established. An initial qualitative investigation involving addition of simple organic ligands to Ni(Co)-hectorite samples demonstrated the formation of metal complexes in the clay interlayers, although some modified behaviour was observed. Further quantitative examination involving likely groundwater organic constituents and more comprehensive physical investigation confirmed this behaviour and enabled separation of the organic compounds used into two classes, according to their effect on cation sorption; (i) acids, (ii) amine compounds. X-ray photoelectron spectroscopy, scanning electron microscopy and Mossbauer spectroscopy were used to investigate the nature of transition metal ions sorbed onto montmorillonite and hectorite. Evidence strongly favoured the sorption of the hexaaquo cation, although a series of sorption sites of slightly different chemical characteristics were responsible for broadened peak widths observed in XPS and Mossbauer investigations. The surface sensitivity of XPS enabled recognition of the two surface sorption sites proposed in earlier sorption studies. Although thermal treatment of Fe^3+/Fe^2+-hectorite samples left iron atoms bonded to the silicate sheet structure, Mossbauer evidence indicated the presence of both ferric and ferrous iron in all samples.

Comparing transport emissions and impacts for energy recovery from domestic waste (EfW): centralised and distributed disposal options for two UK Counties

Many local authorities (LAs) are currently working to reduce both greenhouse gas emissions and the amount of municipal solid waste (MSW) sent to landfill. The recovery of energy from waste (EfW) can assist in meeting both of these objectives. The choice of an EfW policy combines spatial and non-spatial decisions which may be handled using Multi-Criteria Analysis (MCA) and Geographic Information Systems (GIS). This paper addresses the impact of transporting MSW to EfW facilities, analysed as part of a larger decision support system designed to make an overall policy assessment of centralised (large-scale) and distributed (local-scale) approaches. Custom-written ArcMap extensions are used to compare centralised versus distributed approaches, using shortest-path routing based on expected road speed. Results are intersected with 1-kilometre grids and census geographies for meaningful maps of cumulative impact. Case studies are described for two counties in the United Kingdom (UK); Cornwall and Warwickshire. For both case study areas, centralised scenarios generate more traffic, fuel costs and emitted carbon per tonne of MSW processed.