(Table 4) Seasonal variation of sea spray sodium concentrations during 2004-2007 at Concordia Station, Antarctica

From November 2004 to December 2007, size-segregated aerosol samples were collected all-year-round at Dome C (East Antarctica) by using PM10 and PM2.5 samplers, and multi-stage impactors. The data set obtained from the chemical analysis provided the longest and the most time-resolved record of sea spray aerosol (sea salt Na+) in inner Antarctica. Sea spray showed a sharp seasonal pattern. The highest values measured in winter (Apr-Nov) were about ten times larger than in summer (Dec-Mar). For the first time, a size-distribution seasonal pattern was also shown: in winter, sea spray particles are mainly submicrometric, while their summer size-mode is around 1-2 µm. Meteorological analysis on a synoptic scale allowed the definition of atmospheric conditions leading sea spray to Dome C. An extreme-value approach along with specific environmental based criteria was taken to yield stronger fingerprints linking atmospheric circulation (means and anomalies) to extreme sea spray events. Air mass back-trajectory analyses for some high sea spray events allowed the identification of two major air mass pathways, reflecting different size distributions: micrometric fractions for transport from the closer Indian-Pacific sector, and sub-micrometric particles for longer trajectories over the Antarctic Plateau. The seasonal pattern of the SO4**2- /Na+ ratio enabled the identification of few events depleted in sulphate, with respect to the seawater composition. By using methanesulphonic acid (MSA) profile to evaluate the biogenic SO4**2- contribution, a more reliable sea salt sulphate was calculated. In this way, few events (mainly in April and in September) were identified originating probably from the "frost flower" source. A comparison with daily-collected superficial snow samples revealed that there is a temporal shift between aerosol and snow sea spray trends. This feature could imply a more complex deposition processes of sea spray, involving significant contribution of wet and diamond dust deposition, but further work has to be carried out to rule out the effect of wind re-distribution and to have more statistic significance.

(Table 1) Diatom events for AND1-1B, CIROS-2, DVDP-10, and DVDP-11 cores including observed and placed depths

Late Neogene stratigraphy of southern Victoria Land Basin is revealed in coastal and offshore drill cores and a network of seismic data in McMurdo Sound, Antarctica. These data preserve a record of ice sheet response to global climate variability and progressive cooling through the past 5 million years. Application of a composite standard age model for diatom event stratigraphy to the McMurdo Sound drill cores provides an internally precise mechanism to correlate stratigraphic data and derive an event history for the basin. These marine records are indirectly compared to data obtained from geological outcrop in the Transantarctic Mountains to produce an integrated history of Antarctic Ice Sheet response to climate variability from the early Pliocene to Recent. Four distinct chronostratigraphic intervals reflect stages and steps in a transition from a relatively warm early Pliocene Antarctic coastal climate to modern cold polar conditions. Several of these stages and steps correlate with global events identified via geochemical proxy data recovered from deep ocean cores in mid to low latitudes. These correlations allow us to consider linkages between the high southern latitudes and tropical regions and establish a temporal framework to examine leads and lags in the climate system through the late Neogene and Quaternary. The relative influence of climate-tectonic feedbacks is discussed in light of glacial erosion and isostatic rebound that also influence the history along the Southern Victoria Land coastal margin.