Numerical modeling of marine radiocarbon reservoir ages during the last deglaciation

A critical problem in radiocarbon dating is the spatial and temporal variability of marine reservoir ages (MRAs). We assessed the MRA evolution during the last deglaciation by numerical modeling, applying a self-consistent iteration scheme in which an existing radiocarbon chronology (derived by Hughen et al., Quat. Sci. Rev., 25, pp. 3216-3227, 2006) was readjusted by transient, 3-D simulations of marine and atmospheric Delta14C. To estimate the uncertainties regarding the ocean ventilation during the last deglaciation, we considered various ocean overturning scenarios which are based on different climatic background states (PD: modern climate, GS: LGM climate conditions). Minimum and maximum MRAs are included in file 'MRAminmax_21-14kaBP.nc'. Three further files include MRAs according to equilibrium simulations of the preindustrial ocean (file 'C14age_preindustrial.nc'; this is an update of our results published in 2005) and of the glacial ocean (files 'C14age_spinupLGM_GS.nc' and 'C14age_spinupLGM_PD.nc').

Age determination and stable isotope record of foraminifera of sediment core SO82_5-2

Surface and deepwater paleoclimate records in Irminger Sea core SO82-5 (59°N, 31°W) and Icelandic Sea core PS2644 (68°N, 22°W) exhibit large fluctuations in thermohaline circulation (THC) from 60 to 18 calendar kyr B.P., with a dominant periodicity of 1460 years from 46 to 22 calendar kyr B.P., matching the Dansgaard-Oeschger (D-O) cycles in the Greenland Ice Sheet Project 2 (GISP2) temperature record [Grootes and Stuiver, 1997, doi:10.1029/97JC00880]. During interstadials, summer sea surface temperatures (SSTsu) in the Irminger Sea averaged to 8°C, and sea surface salinities (SSS) averaged to ~36.5, recording a strong Irminger Current and Atlantic THC. During stadials, SSTsu dropped to 2°-4°C, in phase with SSS drops by ~1-2. They reveal major meltwater injections along with the East Greenland Current, which turned off the North Atlantic deepwater convection and hence the heat advection to the north, in harmony with various ocean circulation and ice models. On the basis of the IRD composition, icebergs came from Iceland, east Greenland, and perhaps Svalbard and other northern ice sheets. However, the southward drifting icebergs were initially jammed in the Denmark Strait, reaching the Irminger Sea only with a lag of 155-195 years. We also conclude that the abrupt stadial terminations, the D-O warming events, were tied to iceberg melt via abundant seasonal sea ice and brine water formation in the meltwater-covered northwestern North Atlantic. In the 1/1460-year frequency band, benthic ?18O brine water spikes led the temperature maxima above Greenland and in the Irminger Sea by as little as 95 years. Thus abundant brine formation, which was induced by seasonal freezing of large parts of the northwestern Atlantic, may have finally entrained a current of warm surface water from the subtropics and thereby triggered the sudden reactivation of the THC. In summary, the internal dynamics of the east Greenland ice sheet may have formed the ultimate pacemaker of D-O cycles.

Geochemistry of lavas from the Lau-Tonga arc and back-arc system

Detailed comparison of mineralogy, and major and trace geochemistry are presented for the modern Lau Basin spreading centers, the Sites 834-839 lavas, the modern Tonga-Kermadec arc volcanics, the northern Tongan boninites, and the Lau Ridge volcanics. The data clearly confirm the variations from near normal mid-ocean-ridge basalt (N-MORB) chemistries (e.g., Site 834, Central Lau Spreading Center) to strongly arc-like (e.g., Site 839, Valu Fa), the latter closely comparable to the modern arc volcanoes. Sites 835 and 836 and the East Lau Spreading Center represent transitional chemistries. Bulk compositions range from andesitic to basaltic, but lavas from Sites 834 and 836 and the Central Lau Spreading Center extend toward more silica-undersaturated compositions. The Valu Fa and modern Tonga-Kermadec arc lavas, in contrast, are dominated by basaltic andesites. The phenocryst and groundmass mineralogies show the strong arc-like affinities of the Site 839 lavas, which are also characterized by the existence of very magnesian olivines (up to Fo90-92) and Cr-rich spinels in Units 3 and 6, and highly anorthitic plagioclases in Units 2 and 9. The regional patterns of mineralogical and geochemical variations are interpreted in terms of two competing processes affecting the inferred magma sources: (1) mantle depletion processes, caused by previous melt extractions linked to backarc magmatism, and (2) enrichment in large-ion-lithophile elements, caused by a subduction contribution. A general trend of increasing depletion is inferred both eastward across the Lau Basin toward the modern arc, and northward along the Tongan (and Kermadec) Arc. Numerical modeling suggests that multistage magma extraction can explain the low abundances (relative to N-MORB) of elements such as Nb, Ta, and Ti, known to be characteristic of island arc magmas. It is further suggested that a subduction jump following prolonged slab rollback could account for the initiation of the Lau Basin opening, plausibly allowing a later influx of new mantle, as required by the recognition of a two-stage opening of the Lau Basin.

Heat flow values in the Sea of Okhotsk region

Tectonic structure and anomalous distributions of geophysical fields of the Sea of Okhotsk region are considered; the lack of reliable data on age of the lithosphere beneath basins of various origin in the Sea of Okhotsk is noted. Model calculations based on geological and geophysical data yielded 65 Ma (Cretaceous-Paleocene boundary) age for the Central Okhotsk rise underlain by the continental lithosphere. This estimate agrees with the age (the end of Cretaceous) derived from seismostratigraphic data. A comparative analysis of theoretical and measured heat flows in the Akademii Nauk Rise, underlain by the thinned continental crust, is performed. The analysis points to a higher (by 20%) value of the measured thermal background of the rise, which is consistent with high negative gradient of gravity anomalies in this area. Calculations yielded 36 Ma (Early Oligocene) age and lithosphere thickness of 50 km for the South Okhotsk depression, whose seafloor was formed by processes of back-arc spreading. The estimated age of the depression is supported by kinematic data on the region; the calculated thickness of the lithosphere coincides with the value estimated from data of magnetotelluric sounding here. This indicates that formation time (36 Ma) of the South Okhotsk depression was estimated correctly. Numerical modeling performed for determination of the basement age of rifting basins in the Sea of Okhotsk gave the following estimates: 18 Ma (Early Miocene) for the Deryugin Basin, 12 Ma (Middle Miocene) for the TINRO Basin, and 23 Ma (Late Oligocene) for the West Kamchatka Trough. These estimates agree with formation time (Oligocene-Quaternary) of the sedimentary cover in rifting basins of the Sea of Okhotsk derived from geological and geophysical data. Model temperature estimates are obtained for lithologic and stratigraphic boundaries of the sedimentary cover in the Deryugin and TINRO Basins and the West Kamchatka Trough; the temperature analysis indicates that the latter two structures are promising for oil and hydrocarbon gas generation; the West Kamchatka Trough possesses better reservoir properties compared to the TINRO and Deryugin Basins. The latter is promising for generation of hydrocarbon gas. Paleogeodynamic reconstructions of the Sea of Okhotsk region evolution are obtained for times of 90, 66, and 36 Ma on the base of kinematic, geomagnetic, structural, tectonic, geothermal, and other geological and geophysical data.

Sr-Nd isotopic analyses of sand-sized sediment from the San Francisco Bay coastal system

A diverse suite of geochemical tracers, including 87Sr/86Sr and 143Nd/144Nd isotope ratios, the rare earth elements (REEs), and select trace elements were used to determine sand-sized sediment provenance and transport pathways within the San Francisco Bay coastal system. This study complements a large interdisciplinary effort (Barnard et al., 2012) that seeks to better understand recent geomorphic change in a highly urbanized and dynamic estuarine-coastal setting. Sand-sized sediment provenance in this geologically complex system is important to estuarine resource managers and was assessed by examining the geographic distribution of this suite of geochemical tracers from the primary sources (fluvial and rock) throughout the bay, adjacent coast, and beaches. Due to their intrinsic geochemical nature, 143Nd/144Nd isotopic ratios provide the most resolved picture of where sediment in this system is likely sourced and how it moves through this estuarine system into the Pacific Ocean. For example, Nd isotopes confirm that the predominant source of sand-sized sediment to Suisun Bay, San Pablo Bay, and Central Bay is the Sierra Nevada Batholith via the Sacramento River, with lesser contributions from the Napa and San Joaquin Rivers. Isotopic ratios also reveal hot-spots of local sediment accumulation, such as the basalt and chert deposits around the Golden Gate Bridge and the high magnetite deposits of Ocean Beach. Sand-sized sediment that exits San Francisco Bay accumulates on the ebb-tidal delta and is in part conveyed southward by long-shore currents. Broadly, the geochemical tracers reveal a complex story of multiple sediment sources, dynamic intra-bay sediment mixing and reworking, and eventual dilution and transport by energetic marine processes. Combined geochemical results provide information on sediment movement into and through San Francisco Bay and further our understanding of how sustained anthropogenic activities which limit sediment inputs to the system (e.g., dike and dam construction) as well as those which directly remove sediments from within the Bay, such as aggregate mining and dredging, can have long-lasting effects.

Methane concentration profiles and isotopic composition of sediment cores from the Black Sea

We present high resolution profiles for the methane concentration and the carbon isotope composition of methane from surface sediments and from the sediment-water transition in the Black Sea. At shallow water sites methane migrates from the sediment into the water column, and the magnitude of this upward migrating flux depends on the depth of the sulfate-methane transition (SMT) in the sediment. The isotope data reveal that the sediments at shallow water sites are a source for methane depleted in 13C relative to the isotope composition of methane in the water column. At deep water sites the methane concentration first decreases with depth in the sediment to reach lowest values at the Unit I to Unit II transition. Below this transition the concentration increases again. Numerical modeling of methane concentration and isotope data shows that high methane oxidation rates occur in the surface sediment layer, indicating that the removal of methane in the surface sediments is not related to the anaerobic oxidation of methane coupled to sulfate reduction that occurs a few meters deep in the sediment, at the SMT. Instead, near-surface methane consumption in the euxinic Black Sea sediments appears to be related to lithological stratification. Furthermore, a map of the diffusive methane fluxes in the Black Sea surface sediments indicates that approximately half of the Black Sea seafloor acts as a sink for methane and thus limits the flux of methane to the atmosphere.

Geochemical and rock magnetic investigation of sediment cores of the western South Atlantic

Geochemical and rock magnetic investigations of sediments from three sites on the continental margin off Argentina and Uruguay were carried out to study diagenetic alteration of iron minerals driven by anaerobic oxidation of methane (AOM). The western Argentine Basin represents a suitable sedimentary environment to study nonsteady-state processes because it is characterized by highly dynamic depositional conditions. Mineralogic and bulk solid phase data document that the sediment mainly consists of terrigenous material with high contents of iron minerals. As a typical feature of these deposits, distinct minima in magnetic susceptibility (k) are observed. Pore water data reveal that these minima in susceptibility coincide with the current depth of the sulfate/methane transition (SMT) where HS- is generated by the process of AOM. The released HS- reacts with the abundant iron (oxyhydr)oxides resulting in the precipitation of iron sulfides accompanied by a nearly complete loss of magnetic susceptibility. Modeling of geochemical data suggest that the magnetic record in this area is highly influenced by a drastic change in mean sedimentation rate (SR) which occurred during the Pleistocene/Holocene transition. We assume that the strong decrease in mean SR encountered during this glacial/interglacial transition induced a fixation of the SMT at a specific depth. The stagnation has obviously enhanced diagenetic dissolution of iron (oxyhydr)oxides within a distinct sediment interval. This assumption was further substantiated by numerical modeling in which the mean SR was decreased from 100 cm/kyr during glacial times to 5 cm/kyr in the Holocene and the methane flux from below was fixed to a constant value. To obtain the observed geochemical and magnetic patterns, the SMT must remain at a fixed position for ~9000 yrs. This calculated value closely correlates to the timing of the Pleistocene/Holocene transition. The results of the model show additionally that a constant high mean SR would cause a concave-up profile of pore water sulfate under steady state conditions.

Distribution of biological, anthropogenic, and volcanic constituents in the San Francisco Bay Coastal System

Although conventional sediment parameters (mean grain size, sorting, and skewness) and provenance have typically been used to infer sediment transport pathways, most freshwater, brackish, and marine environments are also characterized by abundant sediment constituents of biological, and possibly anthropogenic and volcanic, origin that can provide additional insight into local sedimentary processes. The biota will be spatially distributed according to its response to environmental parameters such as water temperature, salinity, dissolved oxygen, organic carbon content, grain size, and intensity of currents and tidal flow, whereas the presence of anthropogenic and volcanic constituents will reflect proximity to source areas and whether they are fluvially- or aerially-transported. Because each of these constituents have a unique environmental signature, they are a more precise proxy for that source area than the conventional sedimentary process indicators. This San Francisco Bay Coastal System study demonstrates that by applying a multi-proxy approach, the primary sites of sediment transport can be identified. Many of these sites are far from where the constituents originated, showing that sediment transport is widespread in the region. Although not often used, identifying and interpreting the distribution of naturally-occurring and allochthonous biologic, anthropogenic, and volcanic sediment constituents is a powerful tool to aid in the investigation of sediment transport pathways in other coastal systems.

(Table 1) Ice flux, polynya area and sea-ice drift speed in the Kara Sea during winter (Jan-Apr) 1997-2001

The Shelf Seas of the Arctic are known for their large sea-ice production. This paper presents a comprehensive view of the Kara Sea sea-ice cover from high-resolution numerical modeling and space-borne microwave radiometry. As given by the latter the average polynya area in the Kara Sea takes a value of 21.2 × 10**3 km**2 ± 9.1 × 10**3 km**2 for winters (Jan.-Apr.) 1996/97 to 2000/01, being as high as 32.0 × 10**3 km**2 in 1999/2000 and below 12 × 10**3 km**2 in 1998/99. Day-to-day variations of the Kara Sea polynya area can be as high as 50 × 10**3 km**2. For the seasons 1996/97 to 2000/01 the modeled cumulative winter ice-volume flux out of the Kara Sea varied between 100 km**3/a and 350 km**3/a. Modeled high (low) ice export coincides with a high (low) average and cumulative polynya area, and with a low (high) sea-ice compactness in the Kara Sea from remote sensing data, and with a high (low) sea-ice drift speed across its northern boundary derived from independent model data for the winters 1996/97 to 2000/01.

Gridded bathymetry from multibeam echosounder EM122 data of the cruise MSM34/2 (2013)

Bathymetry based on data recorded during MSM34-2 between 27.12.2013 and 18.01.2014 in the Black Sea. The main objective of this cruise was the mapping and imaging of the gas hydrate distribution and gas accumulations as well as possible gas migration pathways. Objectives of Cruise: Gas hydrates have been the focus of scientific and economic interest for the past 15-20 years, mainly because the amount of carbon stored in gas hydrates is much greater than in other carbon reservoirs. Several countries including Japan, Korea and India have launched vast reasearch programmes dedicated to the exploration for gas hydrate resources and ultimately the exploitation of the gas hydrates for methane. The German SUGAR project that is financed the the Ministry of Education and Research (BmBF) and the Ministry of Economics (BmWi) aims at developing technology to exploit gas hydrate resources by injecting and storing CO2 instead of methane in the hydrates. This approach includes techniques to locate and quantify hydrate reservoirs, drill into the reservoir, extract methane from the hydrates by replacing it with CO2, and monitor the thus formed CO2-hydrate reservoir. Numerical modeling has shown that any exploitation of the gas hydrates can only be succesful, if sufficient hydrate resources are present within permeable reservoirs such as sandy or gravelly deposits. The ultimate goal of the SUGAR project being a field test of the technology developed within the project, knowledge of a suitable test site becomes crucial. Within European waters only the Norwegian margin and the Danube deep-sea fan show clear geophysical evidence for large gas hydrate accumulations, but only the Danube deep-sea fan most likely contains gas hydrates within sandy deposits. The main objective of cruise MSM34 therefore is locating and characterising suitable gas hydrate deposits on the Danube deep-sea fan.