14 resultados para non-additivity of Faradaic current

em Publishing Network for Geoscientific


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ODP Site 1124, located 600 km east of the North Island of New Zealand, records post-middle Oligocene variations in the Pacific Deep Western Boundary Current (DWBC) and New Zealand's climatic and tectonic evolution. Sediment parameters, such as terrigenous grain size, flux, magnetic fabric, and non-depositional episodes, are used to interpret DWBC intensity and Antarctic climate. Interpretations of DWBC velocities indicate that the Antarctic Circumpolar Current reached modern intensities at ~23 Ma, as the tectonic seaways expanded, completing the thermal isolation of Antarctica. Periods of more intense bottom water formation are suggested by the presence of hiatuses formed under the DWBC at 22.5-17.6, 16.5-15, and 14-11 Ma. The oldest interval of high current intensity occurs within a climatically warm period during which the intensity of thermohaline circulation around Antarctica increased as a result of recent opening of circum-Antarctic gateways. The younger hiatuses represent glacial periods on Antarctica and major fluctuations in the East Antarctic Ice Sheet, whereas intervals around the hiatuses represent times of relative warmth, but with continued current activity. The period between 11 to 9 Ma is characterized by conditions surrounding a high velocity DWBC around the time of the formation and stabilization of the West Antarctic Ice Sheet. The increased terrigenous input may result from either changing Antarctic conditions or more direct sediment transport from New Zealand. The Pacific DWBC did not exert a major influence on sedimentation at Site 1124 from 9 Ma to the present; the late Miocene to Pleistocene sequence is more influenced by the climatic and tectonic history of New Zealand. Despite the apparent potential for increased sediment supply to this site from changes in sediment channeling, increasing rates of mountain uplift, and volcanic activity, terrigenous fluxes remain low and constant throughout this younger period.

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During ODP Leg 123, abundant and well-preserved Neocomian radiolarians were recovered at Site 765 (Argo Abyssal Plain) and Site 766 (lower Exmouth Plateau). Assemblages are characterized by the numerical dominance of a small number of non-tethyan forms and by the scarcity of tethyan taxa. Remarkable contrasts exist between radiolarian assemblages extracted from claystones of Site 765 and reexamined DSDP Site 261, and faunas recovered from radiolarian sand layers, only found at Site 765. Clay faunas are unusual in their low diversity of apparently ecologically tolerant (or solution resistant?), ubiquist species, whereas sand faunas are dominated by non-tethyan taxa. Comparisons with Sites 766 and 261, as well as sedimentological observations, lead to the conclusion that this faunal contrast resulted from a difference in provenance, rather than from hydraulic sorting or selective dissolution. The ranges of 27 tethyan taxa from Site 765 were compared to the tethyan radiolarian zonation by Jud ( 1992 ) by means of the Unitary Associations Method. This calculation allows to directly date the Site 765 assemblages and to estimate the amount of truncation of ranges for tethyan taxa. Over 70% of the already few tethyan species of Site 765, have truncated ranges during the Valanginian-Hauterivian. Radiolarian assemblages recovered from claystones at Sites 765 and 261 in the Argo Basin apparently reflect restricted oceanic conditions during the latest Jurassic-Barremian. Neither sedimentary facies nor faunal associations bear any resemblance to what we know from typical tethyan sequences. We conclude that the Argo Basin was paleoceanographically separated from the Tethys during the Late Jurassic and part of the Early Cretaceous by its position at higher paleolatitudes and/or by enclosing land masses. Assemblages recovered from radiolarian sand layers are dominated by non-tethyan species that are interpreted as circumantarctic. Their first appearance in the late Berriasian-early Valanginian predates the oceanization of the Indo-Australian breakup (M11, late Valanginian), but coincides with a sharp increase in margin-derived pelagic turbidites. The Indo-Australian rift zone and the adjacent margins must have been submerged deeply enough to allow an intermittent influx of circumantarctic cold water into the Argo Basin, creating increased bottom current activity. Cold-water radiolarians carried into the Argo Basin upwelled along the margin, died, and accumulated in radiolarite layers due to winnowing by bottom currents. High rates of faunal change and the sharp increase of bottom current activity are thought to be synchronous with possible pronounced late Berriasian-early Valanginian lowstands in sea level. Hypothetically, both phenomena might have been caused by a tendency to glaciation on the Antarctic-Australian continent, which was for the first time isolated from the rest of Gondwana by oceanic seaways as a result of Jurassic-Early Cretaceous sea-floor spreading. The absence of most typical tethyan radiolarian species during the Valanginian-Hauterivian is interpreted as reflecting a time of strong influx of circumantarctic cold water following oceanization (M 11) and rapid spreading between Southeast India and West Australia. The reappearance and gradual abundance/diversity increase of tethyan taxa, along with the still dominant circumantarctic species are thought to result from overall more equitable climatic conditions during the Barremian-early Aptian and from the establishment of an oceanic connection with the Tethys Ocean during the early Aptian.

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The Owen Ridge south of Oman represents oceanic crust that was uplifted by compressional tectonic forces in the early Miocene. Build-out of the Indus Fan led to deposition of a thick sequence of turbidites over the site of the Ridge during the late Oligocene and early Miocene. Early Miocene uplift of the Ridge led to a pelagic cap of nannofossil chalks. Two short sequences of turbidites from the pre- and syn-uplift phases were chosen for detailed grain size analysis. The upper Oligocene section at Site 731 is composed of thin (centimeter-decimeter scale) graded mud turbidites separated by relatively thick (decimeter-meter scale) intervals of homogeneous, non-bioturbated clayey siltstones. These finer intervals are unusually silt-rich (about 60%) for ungraded material and were probably deposited as undifferentiated muds from a series of turbidity current tails. By contrast, the lower Miocene section at Site 722 is comprised of a sequence of interbedded turbidites and hemipelagic carbonates. Sharp-based silt turbidites are overlain by burrow-mottled marly nannofossil chalks. The Oligocene sequence may have accumulated in an overbank setting on the middle fan - the local topographic position favoring frequent deposition from turbidity current tails and occasional deposition from the body of a turbidity flow. Uplift of the Ridge in the early Miocene led to pelagic carbonate deposition interrupted only by turbidity currents capable of overcoming a topographic barrier. Further uplift eventually led to entirely pelagic carbonate deposition.

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Future atmospheric CO2 levels will most likely have complex consequences for marine organisms, particulary photosynthetic calcifying organisms. Corallina officinalis L. is an erect calcifying macroalga found in the inter- and subtidal regions of temperate rocky coastlines and provides important substrate and refugia for marine meiofauna. The main goal of the current study was to determine the physiological responses of C. officinalis to increased CO2 concentrations expected to occur within the next century and beyond. Our results show that growth and production of inorganic material decreased under high CO2 levels, while carbonic anhydrase activity was stimulated and negatively correlated to algal inorganic content. Photosynthetic efficiency based on oxygen evolution was also negatively affected by increased CO2. The results of this study indicate that C. officinalis may become less competitive under future CO2 levels, which could result in structural changes in future temperate intertidal communities.

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Grain-size records of the terrigenous and calcareous silt fraction, preservation of planktic foraminifera, and benthic foraminiferal stable-isotope data (delta13C, delta18O values of C. wuellerstorfi) at ODP Site 927 on the Ceará Rise (5°27.7'N, 44°28.8'W), are used to reconstruct variations in the history of bottom current strength, ventilation, and carbonate corrosiveness of deep waters during the time interval from 0.8 to 0.3 Ma. Glacial periods are characterized by generally smaller mean sizes of the terrigenous sortable silt fraction (mean(SS)), lower delta13C values, and poorer preservation of planktic foraminifera compared to interglacials. This indicates lower bottom current speeds, larger nutrient contents and more corrosive deep water. By contrast, larger mean(SS) sizes, higher delta13C values, and well preserved planktic foraminifera indicate strong circulation and a well ventilated deep-water mass during interglacials. The observed changes are most likely related to the weakening and strengthening of circulation of Lower North Atlantic Deep Water (LNADW). Cross-spectral analysis between the mean(SS) and benthic delta18O records reveals that minima in mean(SS) occur about 7.6 k.y. after the maximum in ice volume. This indicates a considerable lag time between ice-shield induced changes in LNADW production and subsequent changes in the velocity of LNADW flow in the western equatorial Atlantic. Striking changes in bottom current speed occur regularly during glacial to interglacial transitions. Extremely fine mean(SS) minima point to an almost complete shutdown of bottom current vigor in response to a cessation of LNADW production caused by an enhanced melt water release during the initial phases of deglaciation. However, each of the fine minima extremes is followed by a rapid shift to very high mean(SS) values that indicate strong bottom currents, and hence, vigorous LNADW flow during the early interglacials. After the onset of glacial Stage 12, generally poorer carbonate preservation and higher variability is registered. This coincides with a global decrease in carbonate preservation during the mid-Brunhes (mid-Brunhes dissolution event). Detailed grain-size analysis of the calcareous fine fraction (<63 µm) revealed a considerable reduction of particles in the fraction from 7 to 63 µm during periods of enhanced dissolution. This indicates a preferential dissolution of larger planktic foraminiferal fragments which leads to an enrichment of coccoliths in the calcareous fine fraction.

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To reconstruct the deep-water circulation for the last 3.5 Ma from deep-sea sediments of the eastern equatorial Atlantic, sea floor morphology, sub-bottom reflectors and the echo character have been mapped on the basis of 3.5 kHz records and sediment cores. Physical properties of sediments and synthetic seismograms derived from them enable us to decipher reflector sequences in environments of pelagic, current-resuspended and turbidity sedimentation. The individual reflectors originate from carbonate dissolution, hiatus, coarse sand layers and interferences. Those which are related to carbonate dissolution and hiatus provide evidence of water-mass boundaries by their distribution. Five phases of different deep-water circulation can be seen in the record of th elast 3.5 Ma, and these are related to climate history: 1. Between 3.7 Ma and 2.2 Ma a strong deep-water circulation indicates a northward flow of bottom water below 4200 m (AABW = Antarctic-Bottom Water) and a southward flow of deep-water above 4200 m (NADW = North-Atlantic Deep Water). 2. Between 1.6 and 1.4 Ma a southward flow of bottom water below 4500 m and a diminished southward flow above 4500 m can be detected. This water-mass geometry can be interpreted by an expansion of the NADW-masses and a displacement of the AABW-masses during the same time. 3. Since 1.4 Ma a northward flow of a bottom-water current developed again. This current flow created a leeside sediment ridge in the southern part of the Kane Gap and furrows in the northern part of it. 4. Between 400,000 and 200,000 yrs B. P. the oceanic and atmospheric circulation increased. The strengthened oceanic circulation caused and increase in carbonate dissolution, which is documented by a traceable reflector from 2800 m to 4500 m water depth. At the same time an increase of the atmospheric circulation caused a drastic rise in the pelagic sediment accumulation (> 100 %) through an intensification of upwelling. This runs parallel with a higher oceanic productivity in the northern equatorial divergence zone and an enhanced supply of fluvial and probably eolian sediments from the Senegal and Guinea. 5. Before 10,000 yrs B. P. an erosive northward flowing bottom-water current prevailed below 4500 m water depth. After 10,000 yrs B.P. the bottom-water flow was sluggish and non erosive.

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40Ar/39Ar analyses of tephra and clasts of volcanic rock provide age constraints for upper parts of the CRP-2A core. Single-crystal laser-fusion analyses of anorthoclase phenocrysts from three tephra-bearing layers yielded the most precise age constraints for CRP-2A. The dated tephra layers are: 1) a 2.7-m-thick interval of pumice and ash layers between 111.5 and 114.2 meters below sea floor (mbsf) (weighted mean age = 21.44 ± 0.05 Ma, +2.2); 2) a concentration of pumice near 193.4 mbsf (23.98 ± 0.13 Ma): and 3) a concentration of pumice near 280 mbsf (24,22 ± 0.03 Ma) (all ages are calibrated relative to Fish Canyon Tuff sanidine at 27.84 Ma). The 111 to 114 mbsf tephra is almost entirely non-reworked, and the 193 mbsf and 280 mbsf tephra concentrations are interpreted as being reworked and redeposited soon after eruption. All three of the tephra ages are therefore considered to be equivalent to depositional ages. The variation in precision of these three age determinations is largely a function of phenocryst size and abundance. The accuracy of these ages is equal to the accuracy of the current calibration of the 40Ar/39Ar methode (about ± 1 %). 40Ar/39Ar results from volcanic clasts provide three additional maximum age constraints for the CRP-2A core. Single-crystal laser-fusion of sanidine phenocrysts from a rhyolitic clast from 294 mbsf yielded a precise maximum depositional age of 24.98 ± 0.08 Ma, and plateau ages of groundmass concentrates from basaltic clasts near 36.02 mbsf and 125.92 mbsf yielded maximum depositional ages of 19.18 ± 0.12 Ma, and 22.56 ± 0.14 Ma, respectively. The 40Ar/39Ar data, in association with biostratigraphic, paleomagnetic, and isotopic age constraints for CRP-2A, confirm interpretation for rapid sedimentation rates in the 36 to 280 mbsf interval, particularly in the 193 to 280 mbsf interval where they support interpretations for sedimentation cycles spanning 100 k.y. intervals. In addition to the 19 to 25 Ma ages measured from thephra layers and clasts, provenance-related ages ranging from 150 to 450 Ma were determined from clasts and individual detrital or xenocrystic crystals from CRP-2A.

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