Radiocarbon, isotope, biogenic, and 230Th measurements for sediment core RC10-196

The subarctic North Pacific Ocean holds a large CO2 reservoir that is currently isolated from the atmosphere by a low-salinity layer. It has recently been hypothesized that the reorganization of these high-CO2 waters may have played a crucial role in the degassing of carbon dioxide to the atmosphere during the last deglaciation. This reorganization would leave some imprint on paleo-productivity records. Here we present 230Th-normalized biogenic fluxes from an intermediate depth sediment core in the Northwest Pacific (RC10-196, 54.7°N, 177.1°E, 1007 m) and place them within the context of a synthesis of previously-published biogenic flux data from 49 deep-sea cores north of 20°N, ranging from 420 to 3968 m water depth. The 230Th-normalized opal, carbonate, and organic carbon fluxes from RC10-196 peak approximately 13,000 calendar years BP during the Bølling/Allerød (B/A) period. Our data synthesis suggests that biogenic fluxes were in general lowest during the last glacial period, increased somewhat in the Northwest Pacific during Heinrich Event 1, and reached a maximum across the entire North Pacific during the B/A period. We evaluate several mechanisms as possible drivers of deglacial change in biogenic fluxes in the North Pacific, including changes in preservation, sediment focusing, sea ice extent, iron inputs, stratification, and circulation shifts initiated in the North Atlantic and North Pacific. Our analysis suggests that while micronutrient sources likely contributed to some of the observed changes, the heterogeneity in timing of glaciogenic retreat and sea level make these mechanisms unlikely causes of region-wide contemporaneous peaks in export production. We argue that paleo-observations are most consistent with ventilation increases in both the North Pacific (during H1) and North Atlantic (during B/A) being the primary drivers of increases in biogenic flux during the deglaciation, as respectively they were likely to bring nutrients to the surface via increased vertical mixing and shoaling of the global thermocline.

Paleoceanographic data from cores M23414 and PS1243

Variations in the poleward-directed Atlantic heat transfer was investigated over the past 135 ka with special emphasis on the last and present interglacial climate development (Eemian and Holocene). Both interglacials exhibited very similar climatic oscillations during each preceding glacial terminations (deglacial TI and TII). Like TI, also TII has pronounced cold-warm-cold changes akin to events such as H1, Bølling/Allerød, and the Younger Dryas. But unlike TI, the cold events in TII were associated with intermittent southerly invasions of an Atlantic faunal component which underscores quite a different water mass evolution in the Nordic Seas. Within the Eemian interglaciation proper, peak warming intervals were antiphased between the Nordic Seas and North Atlantic. Moreover, inferred temperatures for the Nordic Seas were generally colder in the Eemian than in the Holocene, and vice versa for the North Atlantic. A reduced intensity of Atlantic Ocean heat transfer to the Arctic therefore characterized the Eemian, requiring a reassessment of the actual role of the ocean-atmosphere system behind interglacial, but also, glacial climate changes.

Element concentration and GDGT fractional abundances of sediment core GeoB3910-2

In dieser Arbeit wurde das Zeitintervall zwischen 20 und 10 ka vor heute einschließlich des Heinrichevent 1 und der Younger Dryas am Kern GeoB 3910-2 neu untersucht. An organischen Parametern, basierend auf der Verteilung von bakteriellen GDGTs, und Elementkonzentrationen wurde eine Rekonstruktion der klimatischen Bedingungen und Veränderungen im Hinterland von NO Brasilien durchgeführt. Es zeigt sich, dass sich die durchschnittliche Landtemperatur gleich der Oberflächenwassertemperatur verhält und im Gegensatz zu den Phasen von H6 bis H2 dem antarktischen Erwärmungstrend ab 17 ka vor heute folgt. Weiterhin konnte gezeigt werden, dass durch die südwärts Verlagerung der ITCZ während H1 und der YD die Niederschläge in NO Brasilen intensiviert wurden, was eine Ausbreitung der Flüsse und Änderung der Erosionsgebiete zur Folge hatte.

Age determination of sediment core SO75-26KL, Portuguese margin

A benthic isotope record has been measured for core SO75-26KL from the upper Portuguese margin (1099 m water depth) to monitor the response of thermohaline overturn in the North Atlantic during Heinrich events. Evaluating benthic delta18O in TS diagrams in conjunction with equilibrium deltac fractionation implies that advection of Mediterranean outflow water (MOW) to the upper Portuguese margin was significantly reduced during the last glacial (< 15% compared to 30% today). The benthic isotope record along core SO75-26KL therefore primarily monitors variability of glacial North Atlantic conveyor circulation. The 14C-accelerator mass spectrometry ages of 13.54±.07 and 20.46±.12 ka for two ice-rafted detritus (IRD) layers in the upper core section and an interpolated age of 36.1 ka for a third IRD layer deeper in the core are in the range of published 14C ages for Heinrich events H1, H2, and H4. Marked depletion of benthic delta13C by 0.7-1.1 per mil during the Heinrich events suggests reduced thermohaline overturn in the North Atlantic during these events. Close similarity between meltwater patterns (inferred from planktonic delta18O) at Site 609 and ventilation patterns (inferred from benthic delta13C) in core SO75-26KL implies coupling between thermohaline overturn and surface forcing, as is also suggested by ocean circulation models. Benthic delta13C starts to decrease 1.5-2.5 kyr before Heinrich events Hl and H4, fully increased values are reached 1.5-3 kyr after the events, indicating a successive slowdown of thermohaline circulation well before the events and resumption of the conveyor's full strength well after the events. Benthic delta13C changes in the course of the Heinrich events show subtle maxima and minima suggesting oscillatory behavior of thermohaline circulation, a distinct feature of thermohaline instability in numerical models. Inferrred gradual spin-up of thermohaline circulation after Hl and H4 is in contrast to abrupt wanning in the North Atlantic region that is indicated by sudden increases in Greenland ice core delta18O and in marine faunal records from the northern North Atlantic. From this we infer that thermohaline circulation can explain only in part the rapid climatic oscillations seen in glacial sections of the Greenland ice core record.

Stable isotope ratios and foraminiferal abundance of sediment cores from the Western Iberian Margin

Rapid climate changes at the onset of the last deglaciation and during Heinrich Event H4 were studied in detail at IMAGES cores MD95-2039 and MD95-2040 from the Western Iberian margin. A major reorganisation of surface water hydrography, benthic foraminiferal community structure, and deepwater isotopic composition commenced already 540 years before the Last Isotopic Maximum (LIM) at 17.43 cal. ka and within 670 years affected all environments. Changes were initiated by meltwater spill in the Nordic Seas and northern North Atlantic that commenced 100 years before concomitant changes were felt off western Iberia. Benthic foraminiferal associations record the drawdown of deepwater oxygenation during meltwater and subsequent Heinrich Events H1 and H4 with a bloom of dysoxic species. At a water depth of 3380 m, benthic oxygen isotopes depict the influence of brines from sea ice formation during ice-rafting pulses and meltwater spill. The brines conceivably were a source of ventilation and provided oxygen to the deeper water masses. Some if not most of the lower deep water came from the South Atlantic. Benthic foraminiferal assemblages display a multi-centennial, approximately 300-year periodicity of oxygen supply at 2470-m water depth. This pattern suggests a probable influence of atmospheric oscillations on the thermohaline convection with frequencies similar to Holocene climate variations. For Heinrich Events H1 and H4, response times of surface water properties off western Iberia to meltwater injection to the Nordic Seas were extremely short, in the range of a few decades only. The ensuing reduction of deepwater ventilation commenced within 500-600 years after the first onset of meltwater spill. These fast temporal responses lend credence to numerical simulations that indicate ocean-climate responses on similar and even faster time scales.

Distribution of pollen and spores in sediments of ODP Hole 175-1078C

The distribution of pollen in marine sediments is used to record vegetation change on the continent. Generally, a good latitudinal correspondence exists between the distribution patterns of pollen in the marine surface sediments and the occurrence of the source plants on the adjacent continent. To investigate land-sea interactions during deglaciation, we compare proxies for continental (pollen assemblages) and marine conditions (alkenone-derived sea surface temperatures) of two high-resolution, radiocarbon-dated sedimentary records from the tropical southeast Atlantic. The southern site is located West of the Cunene River mouth; the northern site is located West of the Angolan Huambe Mountains. It is inferred that the vegetation in Angola developed from Afroalpine and open savannah during the last Glacial maximum (LGM) via Afromontane Podocarpus forest during Heinrich Event 1 (H1), to an early increase of lowland forest after 14.5 ka. The vegetation record indicates dry and cold conditions during the LGM, cool and wet conditions during H1 and a gradual rise in temperature starting well before the Younger Dryas (YD) period. Terrestrial and oceanic climate developments seem largely running parallel, in contrast to the situation ca. 5° further South, where marine and terrestrial developments diverge during the YD. The cool and wet conditions in tropical West Africa, South of the equator, during H1 suggest that low-latitude insolation variation is more important than the slowdown of the thermohaline circulation for the climate in tropical Africa.

Isotopic composition and lithic grains concentration of sediment core SI90-09

Theories explaining the origin of the abrupt, massive discharges of ice-rafted detritus (IRD) into the glacial North Atlantic (the Heinrich layers (HLs)) generally point to the Laurentide ice sheet as the sole source of these events, until it was found that the IRDs also originated from Icelandic and European ice sheets (Bond and Lotti, 1995, doi:10.1126/science.267.5200.1005; Snoeckx et al., 1999, doi:10.1016/S0025-3227(98)00168-6; Grousset et al., 2000, doi:10.1130/0091-7613(2000)28<123:WTNAHE>2.0.CO;2). This apparent contradiction must be reconciled as it raises fundamental questions about the mechanism(s) of HL origin. We have analyzed two ~12 cm thick HLs in an ultrahigh-resolution mode (1-2 century intervals) in a mid-Atlantic ridge piston core. The d18O record (N. pachyderma left coiling) reveals strong excursions induced by the melting of the icebergs; these excursions are associated with a strong decrease in the amount of planktic foraminafersand with a 3°C cooling of the surface waters. Counts of coarse detrital grains reveal that IRD are deposited according to a typical sequence (1) volcanic glass, (2) quartz and feldspars, (3) detrital carbonate, that implies a chronology in the melting of the differentpan-Atlantic ice sheets. Sr and Nd isotopic composition confirm that in both Heinrich layers H1 and H2, "precursor" IRD came from first Europe/Iceland, followed then by Laurentide-derived IRD. An internal cyclicity can be identified: during H1 and H2, about four to six major, abrupt discharges occurred roughly on a century timescale. The d13C and d15N records reveal that dominant inputs of continent-derived organic matter are associated with IRD within the HLs, hiding the plankton productivity signal.

High-resolution planktic stable isotope and trace element record of ODP Hole 161-976

Multi-decadal to centennial planktic d18O and Mg/Ca records were generated at ODP976 in the Alboran Sea. The site is in the flow path of Atlantic inflow waters entering the Mediterranean and captured North Atlantic signals through the surface inflow and the atmosphere. The records reveal similar climatic oscillations during the last two glacial-to-interglacial transitions, albeit with a different temporal pacing. Glacial termination 1 (T1) was marked by Heinrich event 1 (H1), post-H1 Bolling/Allerod (B/A) warming and Younger Dryas (YD) cooling. During T2 the H11 d18O anomaly was twice as high and lasted 30% longer than during H1. The post-H11 warming marked the start of MIS5e while the subsequent YD-style cooling occurred during early MIS5e. The post-H11 temperature increase at ODP976 matched the sudden Asian Monsoon Termination II at 129 ka BP. Extending the 230Th-dated speleothem timescale to ODP976 suggests glacial conditions in the Northeast Atlantic region were terminated abruptly and interglacial warmth was reached in less than a millennium. The early-MIS5e cooling and freshening at ODP976 coincided with similar changes at North Atlantic sites suggesting this was a basin-wide event. By analogy with T1 we argue that this was a YD-type event that was shifted into the early stages of the last interglacial period. This scenario is consistent with evidence from northern North Atlantic and Nordic Sea sites that the continuing disintegration of the large Saalian Stage (MIS6) ice sheet in Eurasia delayed the advection of warm North Atlantic waters and full-strength convective overturn until later stages of MIS5e.

Sea surface temperature reconstruction from biomarker in sediments off Portugal

High resolution reconstructions of sea surface temperature (Uk'37-SST), coccolithophore associations and continental input (total organic carbon, higher plant n-alkanes, n-alkan-1-ols) in core D13882 from the shallow Tagus mud patch are compared to SST records from deep-sea core MD03-2699 and other western Iberian Margin cores. Results reveal millennial-scale climate variability over the last deglaciation, in particular during the LGIT. In the Iberian margin, Heinrich event 1 (H1) and the Younger Dryas (YD) represent two extreme episodes of cold sea surface condition separated by a marine warm phase that coincides with the Bølling-Allerød interval (B-A) on the neighboring continent. Following the YD event, an abrupt sea surface warming marks the beginning of the Holocene in this region. SSTs recorded in core D13882 changed, however, faster than those at deep-sea site MD03-2699 and at the other available palaeoclimate sequences from the region. While the SST values from most deep-sea cores reflect the latitudinal gradient detected in the Iberian Peninsula atmospheric temperature proxies during H1 and the B-A, the Tagus mud patch (core D13882) experienced colder SSTs during both events. This is most certainly related to a supplementary input of cold freshwater from the continent to the Tagus mud patch, a hypothesis supported by the high contents of terrigenous biomarkers and total organic carbon as well as by the dominance of tetra-unsaturated alkenone (C37:4) observed at this site. The comparison of all western Iberia SST records suggests that the SST increase that characterizes the B-A event in this region started 1000 yr before meltwater pulse 1A (mwp-1A) and reached its maximum values during or slightly after this episode of substantial sea-level rise. In contrast, during the YD/ Holocene transition, the sharp SST rise in the Tagus mud patch is synchronous with meltwater pulse IB. The decrease of continental input to the mud patch conflrms a sea level rise in the region. Thus, the synchronism between the maximum warming in the mid-latitudes off the western Iberian margin, the adjacent landmasses and Greenland indicates that mwp-lB and the associated sea-level rise probably initiated in the Northern Hemisphere rather than in the South.

Palynological and geochemical data of sediment core GeoB3910-2 located offshore Northeast Brazil

High resolution palynological and geochemical data of sediment core GeoB 3910-2 (located offshore Northeast Brazil) spanning the period between 19 600 and 14 500 calibrated year bp (19.6-14.5 ka) show a land-cover change in the catchment area of local rivers in two steps related to changes in precipitation associated with Heinrich Event 1 (H1 stadial). At the end of the last glacial maximum, the landscape in semi-arid Northeast Brazil was dominated by a very dry type of caatinga vegetation, mainly composed of grasslands with some herbs and shrubs. After 18 ka, considerably more humid conditions are suggested by changes in the vegetation and by Corg and C/N data indicative of fluvial erosion. The caatinga became wetter and along lakes and rivers, sedges and gallery forest expanded. The most humid period was recorded between 16.5 and 15 ka, when humid gallery (and floodplain) forest and even small patches of mountainous Atlantic rain forest occurred together with dry forest, the latter being considered as a rather lush type of caatinga vegetation. During this humid phase erosion decreased as less lithogenic material and more organic terrestrial material were deposited on the continental slope of northern Brazil. After 15 ka arid conditions returned. During the humid second phase of the H1 stadial, a rich variety of landscapes existed in Northeast Brazil and during the drier periods small pockets of forest could probably survive in favorable spots, which would have increased the resilience of the forest to climate change.

Study on the last deglaciation section of sediment core GeoB6211-2

The North Atlantic Ocean underwent an abrupt temperature increase of 9 °C at high latitudes within a couple of decades during the transition from Heinrich event 1 (H1) to the Bølling warm event, but the mechanism responsible for this warming remains uncertain. Here we address this issue, presenting high-resolution last deglaciation planktic and benthic foraminiferal records of temperature and oxygen isotopic composition of seawater (d18OSW) for the subtropical South Atlantic. We identify a warming of ~6.5 °C and an increase in d18Osw of 1.2 per mil at the permanent thermocline during the transition, and a simultaneous warming of ~3.5 °C with no significant change in d18Osw at intermediate depths. Most of the warming can be explained by tilting the South Atlantic east-west isopycnals from a flattened toward a steepened position associated with a collapsed (H1) and strong (Bølling) Atlantic meridional overturning circulation (AMOC). However, this zonal seesaw explains an increase of just 0.3 per mil in permanent thermocline d18Osw. Considering that d18Osw at the South Atlantic permanent thermocline is strongly influenced by the inflow of salty Indian Ocean upper waters, we suggest that a strengthening in the Agulhas leakage took place at the transition from H1 to the Bølling, and was responsible for the change in d18Osw recorded in our site. Our records high-light the important role played by Indian-Atlantic interocean exchange as the trigger for the resumption of the AMOC and the Bølling warm event. of the AMOC and the Bølling warm event.

Stable isotopes and Mg/Ca measurements of two sediment cores in the northeastern tropical Atlantic

Two SST records based on Mg/Ca of G. ruber (pink) from the continental slope off West Africa at 15°N and 12°N shed new light on the thermal bipolar seesaw pattern in the northeastern tropical Atlantic during periods of reduced Atlantic Meridional Overturning Circulation (AMOC) associated with Heinrich stadials H1 to H6. The two records indicate that the latitudinal position of the bipolar seesaw's zero-anomaly line, between cooling in the North and warming in the South, gradually shifted southward from H6 to H1. A conceptual model is presented that aims to provide a physically consistent mechanism for the southward migration of the seesaw's fulcrum. The conceptual model suggests latitudinal movements of the Intertropical Convergence Zone, driven by a combination of orbital-forced changes in the meridional temperature gradient within the realm of the Hadley cell and the expansion of the Northern Hemisphere cryosphere, as a major factor.

Stable oxygen isotope record and age determination of sediments from the North Atlantic Ocean

Sea surface temperature and salinity estimates reconstructed using planktonic foraminiferal abundance and delta18O records from core SU90-03 (40°N, 32°W, 2475 m water depth) reveal large climatic fluctuations linked to major instabilities in Northern Hemisphere ice sheets over the last 150 000 years. Episodes of enhanced ice rafted detritus (IRD) input were accompanied by discrete temperature minima, representing coolings of between 4 and 8°C, and reductions in surface salinity of up to 2.5-3.5 per mil. Several additional cooling episodes of a similar magnitude were documented during intervals of low IRD input that appear to be synchronous, within the limits of dating, with ice rafting events spatially confined to higher latitudes. Accelerator mass spectrometer 14C dates for Heinrich events (H1 - 14.2 ka, H2 - 21.4 ka, H3 - 26.7 ka, H4 - 34.8 ka, H5 - 47.2 ka) obtained from core SU90-03 agree well with other published age estimates and suggest a contemporaneous pattern of climate change throughout the North Atlantic during the last glacial period. This interpretation is supported by a comparison of IRD and palaeotemperature records from DSDP site 609 and core SU90-03, which clearly shows that the major climatic fluctuations identified at high latitudes were transmitted toward the subtropics. However, 14C dates suggest that ice rafting episodes may be diachronous to some extent. The northward migration of the polar front after the H1 event at 40°N in the mid-Atlantic occurred at 14 ka, approximately 500 years earlier than along the Portuguese margin, where the southerly advection of polar waters persisted within eastern boundary current system.

Abundance of organic-walled dinoflagellate cysts and geochemical analysis of sediment core GeoB5546-2

NW African climate shows orbital and millenial-scale variations, which are tightly connected to changes in marine productivity. We present an organic-walled dinoflagellate cyst (dinocyst) record from a sediment core off Cape Yubi at about 27°N in the Canary Basin covering the time period from 47 to 3ka before present (BP). The dinocyst record reflects differences in upwelling intensity and seasonality as well as the influence of fluvial input. Sea-level changes play an important role for the upwelling pattern and productivity signals at the core site. Within the studied time interval, four main phases were distinguished. (1) From 45 to 24ka BP, when sea-level was mostly about 75m lower than today, high relative abundances of cysts of heterotrophic taxa point to enhanced upwelling activity, especially during Heinrich Events, while relatively low dinocyst accumulation rates indicate that filament activity at the core location was strongly reduced. (2) At sea-level lowstand during the LGM to H1, dinocyst accumulation rates suggest that local filament formation was even more inhibited. (3) From the early Holocene to about 8ka BP, extraordinary high accumulation rates of most dinocyst species, especially of Lingulodinium machaerophorum, suggest that nutrient supply via fluvial input increased and rising sea-level promoted filament formation. At the same time, the upwelling season prolongated. (4) A relative increase in cysts of photoautotrophic taxa from about 8ka BP on indicates more stratified conditions while fluvial input decreased. Our study shows that productivity records can be very sensitive to regional features. From the dinocyst data we infer that marine surface productivity off Cape Yubi during glacial times was within the scale of modern times but extremely enhanced during deglaciation.