Strength and deformation behavior of ODP Leg 110 sediments

The shape and morphology of the northern Barbados Ridge complex is largely controlled by the sediment yield and failure behavior in response to high lateral loads imposed by convergence. Loads in excess of sediment yield strength result in nonrecoverable deformations within the wedge, and failure strength acts as an upper limit beyond which stresses are released through thrust faults. Relatively high loading rates lead to delayed consolidation and in-situ pore pressures greater than hydrostatic. The sediment yield and failure behavior is described for any stress path by a generalized constitutive model. A yield locus delineates the onset of plastic (non-recoverable) deformation, as defined from the isotropic and anisotropic consolidation responses of high-quality 38-mm triaxial specimens; a failure envelope was obtained by shearing the same specimens in both triaxial compression and extension. The yield locus is shown to be rotated into extension space and is centered about a K-line greater than unity, suggesting that the in-situ major principal stress has rotated into the horizontal plane, and that the sediment wedge is being subjected to extensional effective stress paths.

(Table 1) Organic geochemistry of ODP Hole 134-832B and Site 134-833

Ocean Drilling Program (ODP) Leg 134 was located in the central part of the New Hebrides Island Arc, in the Southwest Pacific. Here the d'Entrecasteaux Zone of ridges, the North d'Entrecasteaux Ridge and South d'Entrecasteaux Chain, is colliding with the arc. The region has a Neogene history of subduction polarity reversal, ridge-arc collision, and back-arc spreading. The reasons for drilling in this region included the following: (1) to determine the differences in the style and time scale of deformation associated with the two ridge-like features (a fairly continuous ridge and an irregularly topographic seamount chain) that are colliding with the central New Hebrides Island Arc; (2) to document the evolution of the magmatic arc in relation to the collision process and possible Neogene reversal of subduction; and (3) to understand the process of dewatering of a small accretionary wedge associated with ridge collision and subduction. Seven sites were occupied during the leg, five (Sites 827-831) were located in the d'Entrecasteaux Zone where collision is active. Three sites (Sites 827, 828, and 829) were located where the North d'Entrecasteaux Ridge is colliding, whereas two sites (Sites 830 and 831) were located in the South d'Entrecasteaux Chain collision zone. Sites 828 (on North d'Entrecasteaux Ridge) and 831 (on Bougainville Guyot) were located on the Pacific Plate, whereas all other sites were located on a microplate of the North Fiji Basin. Two sites (Sites 832 and 831) were located in the intra-arc North Aoba Basin. Results of Leg 134 drilling showed that forearc deformation associated with the North d'Entrecasteaux Ridge and South d'Entrecasteaux Chain collision is distinct and different. The d'Entrecasteaux Zone is an Eocene subduction/obduction complex with a distinct submerged island arc. Collision and subduction of the North d'Entrecasteaux Ridge results in off scraping of ridge material and plating of the forearc with thrust sheets (flakes) as well as distinct forearc uplift. Some offscraped sedimentary rocks and surficial volcanic basement rocks of the North d'Entrecasteaux Ridge are being underplated to the New Hebrides Island forearc. In contrast, the South d'Entrecasteaux Chain is a serrated feature resulting in intermittent collision and subduction of seamounts. The collision of the Bougainville Guyot has indented the forearc and appears to be causing shortening through thrust faulting. In addition, we found that the Quaternary relative convergence rate between the New Hebrides Island Arc at the latitude of Espiritu Santo Island is as high as 14 to 16 cm/yr. The northward migration rate of the d'Entrecasteaux Zone was found the be ~2 to 4 cm/yr based on the newly determined Quaternary relative convergence rate. Using these rates we established the timing of initial d'Entrecasteaux Zone collision with the arc at ~3 Ma at the latitude of Epi Island and fixed the impact of the North d'Entrecasteaux Ridge upon Espiritu Santo Island at early Pleistocene (between 1.89 and 1.58 Ma). Dewatering is occurring in the North d'Entrecasteaux Ridge accretionary wedge, and the wedge is dryer than other previously studied accretionary wedges, such as Barbados. This could be the result of less sediment being subducted at the New Hebrides compared to the Barbados.

(Table 1) Chemical composition of plagioclase and amphibole-pyroxene containing samples from pyroxene-amphibole-asbestos rock collected in the Hess Deep

Recent sediments with distinct signs of hydrothermal alteration sampled in the Hess Deep(Galapagos Ridge, East Pacific Rise) contained a piece of ash-gray rock, which differed from other rock fragments by degree of consolidation, conchoidal fracture, and had properties of asbestos. Our studies found that the sample represented mixture of asbestos-like pyroxene of diopside-hedenbergite composition, amphibole of tremolite composition and a new mineral, which basic structure consisted of bands of triple pyroxene chains with the radical [Si6O16]. The latter can be regarded as intermediate between amphiboles and layered silicates. Also in some parts of the sample presence of trioctahedral vermiculite-chlorite was indicated. Genesis of the studied asbestos rock is considered from the standpoint of high-temperature hydrothermal-metasomatic alteration of sediment by post-magmatic mineralized halide solutions.

Mineralogy and geochemistry of ODP Hole 176-735B minerals

We present a synthesis of some 20,504 mineral analyses of ~500 Hole 735B gabbros, including 10,236 new analyses conducted for this paper. These are used to construct a mineral stratigraphy for 1.5-km-deep Hole 735B, the only long section of the lower crust drilled in situ in the oceans. At long wavelengths, generally >200 m, there is a good chemical correlation among the principal silicate phases, consistent with the in situ crystallization of three or four distinct olivine gabbro bodies, representing at least two major cycles of intrusion. Initial cooling and crystallization of these bodies must have been fairly rapid to form a crystal mush, followed by subsequent compaction and migration of late iron-titanium-rich liquids into shear zones and fractures through which they were emplaced to higher levels in the lower crust where they crystallized and reacted with the olivine gabbro host rock to form a wide variety of ferrogabbros. At the wave lengths of the individual intrusions, as represented by the several olivine gabbro sequences, there is a general upward trend of iron and sodium enrichment but a poor correlation between the compositions of the major silicate phases. This, together with a wide range in minor incompatible and compatible element concentrations in olivine and pyroxene at a given Mg#, is consistent with widespread permeable flow of late melt through these intrusions, in contrast to what has been documented for a 600-m section of reputedly fast-spreading ocean crust in the Oman Ophiolite. This unexpected finding could be related to enhanced compaction and deformation-controlled late-stage melt migration at the scale of intrusion at a slow-spreading ocean ridge, compared to the relatively static environment in the lower crust at fast-spreading ridges.

(Table 1) Geochemical and geothermometry data from fibrous calcite vein fills in the Dabashan Fold Belt, China

Fibrous calcite veins with organic inclusions have been widely considered as indicators of oil and gas generation and migration under overpressure. Abundant fibrous calcite veins containing organic-bearing inclusions occur in faulted Lower Paleozoic through Triassic hydrocarbon source rocks in the Dabashan Foreland Belt (DBF). d13CPDB and d18OPDB values of the fibrous calcite range from - 4.8 to -1.9 to per mil and - 12.8 to - 8.4 per mil respectively, which is lighter than that of associated carbonate host rocks ranging from - 1.7 to + 3.1 per mil and - 8.7 to - 4.5 per mil. A linear relationship between d13CPDB and d18OPDB indicates that the calcite veins were precipitated from a mixture of basinal and surface fluids. The fibrous calcite contains a variety of inclusions, such as solid bitumen, methane bearing all-liquid inclusions, and vapor-liquid aqueous inclusions. Homogenization temperatures of aqueous inclusions range from 140 to 196° with an average of 179°. Salinities of aqueous inclusions average 9.7 wt% NaCl. Independent temperatures from bitumen reflectance and inclusion phase relationships of aqueous and methane inclusions were used to determine fluid pressures. Results indicate high pressures, elevated above typical lithostatic confining pressure, from 150 to 200 MPa. The elevated salinity and high temperature and pressure conditions of the fibrous calcite veins argue against an origin solely from burial overpressure resulting from clay transformation and dehydration reactions. Instead fluid inclusion P-T data and geochemistry results and regional geology indicate abnormally high pressures during fluid migration. These findings indicate that tectonic stress generated fracture and fault fluid pathways and caused migration of organic bearing fluids from the DBF during the Yanshan orogeny.

Chemistry of gabbroic rocks from ODP Hole 118-735B

Gabbroic rocks and their late differentiates recovered at Site 735 represent 500 m of oceanic layer 3. The original cooling of a mid-ocean ridge magma chamber, its penetration by ductile shear zones and late intrusives, and the subsequent penetration of seawater through a network of cracks and into highly permeable magmatic hydrofracture horizons are recorded in the metamorphic stratigraphy of the core. Ductile shear zones are characterized by extensive dynamic recrystallization of primary phases, beginning in the granulite facies and continuing into the lower amphibolite facies. Increasing availability of seawater during dynamic recrystallization is reflected in depletions in 18O, increasing abundance of amphibole of variable composition and metamorphic plagioclase of intermediate composition, and more complete coronitic or pseudomorphous static replacement of magmatic minerals. Downcore correlation of synkinematic assemblages, bulk-rock oxygen isotopic compositions, and vein abundance suggest that seawater is introduced into the crust by way of small cracks and veins that mark the end of the ductile phase of deformation. This "deformation-enhanced" metamorphism dominates the upper 180 and the lower 100 m of the core. In the lower 300 m of the core, mineral assemblages of greenschist and zeolite facies are abundant within or adjacent to brecciated zones. Leucocratic veins found in these zones and adjacent host rock contain diopside, sodic plagioclase, epidote, chlorite, analcime, thomsonite, natrolite, albite, quartz, actinolite, sphene, brookite, and sulfides. The presence of zircon, Cl-apatite, sodic plagioclase, sulfides, and diopside in leucocratic veins having local magmatic textures suggests that some of the veins originated from late magmas or from hydrothermal fluids exsolved from such magmas that were subsequently replaced by (seawater-derived) hydrothermal assemblages. The frequent association of these late magmatic intrusive rocks within the brecciated zones suggests that they are both artifacts of magmatic hydrofracture. Such catastrophic fracture and hydrothermal circulation could produce episodic venting of hydrothermal fluids as well as the incorporation of a magmatically derived hydrothermal component. The enhanced permeability of the brecciated zones produced lower temperature assemblages because of larger volumes of seawater that penetrated the crust. The last fractures were sealed either by these hydrothermal minerals or by late carbonate-smectite veins, resulting in the observed low permeability of the core.

Geochemistry and isotopic composition of gabbros from ODP Hole 118-375B

Gabbros drilled from the shallow (720 m) east wall of the Atlantis II transform on the Southwest Indian Ridge (SWIR; 32°43.40', 57°16.00') provide the most complete record of the stratigraphy and composition of the oceanic lower crust recovered from the ocean basins to date. Lithologies recovered include gabbro, olivine gabbro, troctolite, trondhjemite, and unusual iron-titanium (FeTi) oxide-rich gabbro containing up to 30% FeTi oxides. The plutonic rock sequence represents a tholeiitic fractionation trend ranging from primitive magmas having Mg numbers of 67 to 69 that fractionated troctolites, to highly evolved liquids that crystallized two-pyroxene, FeTi oxide-rich gabbros and, ultimately, trondhjemite. Isotopic compositions of unaltered Leg 118 gabbros are distinct from Indian Ocean mid-ocean ridge basalts (MORB) in having higher 143Nd/144Nd (0.51301-0.51319) and lower 206Pb/204Pb values (17.35-17.67); 87Sr/86Sr values (0.7025-0.7030) overlap those of SWIR basalts, but are generally lower than MORBs from the Southeast Indian Ridge or the Rodrigues Triple Junction. More than one magma composition may have been introduced into the magma chamber during its crystallization history, as suggested by the higher 87Sr/86Sr, 206Pb/204Pb, and lower 143Nd/144Nd values of chromium-rich olivine gabbros from the bottom of Hole 735B. Whole-rock gabbro and plagioclase mineral separate 87Sr/86Sr values are uniformly low (0.7027-0.7030), irrespective of alteration and deformation. By contrast, 87Sr/86Sr values for clinopyroxene (0.7025-0.7039) in the upper half of Hole 735B are higher than coexisting plagioclase and reflect extensive replacement of clinopyroxene by amphibole. Hydrothermal veins and breccias have elevated 87Sr/86Sr values (0.7029-0.7035) and indicate enhanced local introduction of seawater strontium. Oxygen- and hydrogen-isotope results show that secondary amphiboles have uniform dD values of -49 to -54 per mil and felsic hydrothermal veins range from -46 to - 77 per mil. Oxygen-isotope data for secondary amphibole and visibly altered gabbros range to low values (+1.0-+5.5 per mil), and O-isotope disequilibrium between coexisting pyroxene and plagioclase pairs from throughout the stratigraphic column indicates that seawater interacted with much of the gabbro section, but at relatively low water/rock ratios. This is consistent with the persistence of low 87Sr/86Sr values, even in gabbros that were extensively deformed and altered.

Lithology description, textural and structural observations, and indications for ground ice of sediment core CRP-2 (Table 1-4)

From the upper 300 m of CRP-2/2A, twenty-six samples of diamicts and deformation structures have been thin sectioned. These have been analysed for texture, structure, diagenesis and plasmic fabric. The combination of certain microstructures (e.g. turbate and linear) and plasmic fabric development is indicative of grounded ice. Clear evidence for two grounded ice events (three samples) was found in the upper Oligocene part of the core. The interpretation of ten more samples is less certain, but as for CRP-1, is taken to point to grounded ice as well. There is a strong correlation between these indications for grounded ice and the basal part of cycles in the sequence stratigraphy.

Particel size distribution and microstructures of sediments from ODP Leg 205 sites (Table 1)

Ocean Drilling Program Legs 170 and 205 offshore Costa Rica provide structural observations which support a new model for the geometry and deformation response to the seismic cycle of the frontal sedimentary prism and decollement. The model is based on drillcore, thin section, and electron microscope observations. The decollement damage zone is a few tens of meters in width, it develops mainly within the frontal prism. A clear cm-thick fault core is observed 1.6 km from the trench. The lower boundary of the fault core is coincident with the lithological boundary between the frontal prism and the hemipelagic and pelagic sediment of the Cocos plate. Breccia clast distributions in the upper portion of the decollement damage zone were studied through fractal analysis. This analysis shows that the fractal dimension changes with brecciated fragment size, implying that deformation was not accommodated by self-similar fracturing. A higher fractal dimensionality correlates with smaller particle size, which indicates that different or additional grain-size reduction processes operated during shearing. The co-existence of two distinct fracturing processes is also confirmed by microscopic analysis in which extension fracturing in the upper part of the damage zone farthest from the fault core is frequent, while both extension and shear fracturing occur approaching the fault core. The coexistence of extensional and shear fracturing seems to be best explained by fluid pressure variations in response to variations of the compressional regime during the seismic cycle. During the co-seismic event, sub-horizontal compression and fluid pressure increase, triggering shear fracturing and fluid expulsion. Fractures migrate upward with fluids, contributing to the asymmetric shape of the decollement, while slip propagates. In the inter-seismic interval the frontal prismrelaxes and fluid pressure drops. The frontal prismgoes into diffuse extension during the intervalwhen plate convergence is accommodated by creep along the ductile fault core. The fault core is typically a barrier to deformation, which is explained by its weak, but impermeable, nature. The localized development of a damage zone beneath the fault core is characterized by shear fracturing that appears as the result of local strengthening of the detachment.

Composition of soil samples from injection location

CO2 leakage from subsurface storage sites is one of the main concerns connected with the CCS technology. As CO2 leakages into near surface formations appear to be very unlikely within pilot CCS projects, the aim of this work is to emulate a leakage by injecting CO2 into a near surface aquifer. The two main questions pursued by the injection test are (1) to investigate the impact of CO2 on the hydrogeochemistry of the groundwater as a base for groundwater risk assessment and (2) to develop and apply monitoring methods and monitoring concepts for detecting CO2 leakages in shallow aquifers. The presented injection test is planned within the second half of 2010, as a joint project of the University of Kiel (Germany), the Helmholtz-Centre for Environmental Research (Leipzig, Germany) and the Engineering Company GICON (Dresden, Germany). The test site has been investigated in detail using geophysical methods as well as direct-push soundings, groundwater well installation and soil and groundwater analyses. The present paper presents briefly the geological and hydrogeological conditions at the test site as well as the planned injection test design and monitoring concept.

Magnetic properties of gabbros from ODP Hole 118-735B

A total of 500.7 m of continuous, vertical, oceanic gabbroic section was recovered during Leg 118. The gabbros obtained exhibited various degrees of alteration and deformation, which gave us a good opportunity to study the magnetic properties of oceanic gabbros. Many of these gabbros, which are mainly Fe-Ti oxide gabbros, have strong and unstable secondary magnetic components that were acquired during drilling. Stable inclinations, which are probably in-situ magnetic directions, show a single polarity, with an average value of 66° (±5°), meaning that the studied 501-m oceanic gabbroic block may be a candidate for the source of the marine magnetic anomaly. This may also imply that the metamorphism of oceanic gabbros causing acquisition of magnetization probably occurred within one geomagnetic polarity chron (about 0.3 to 0.7 m.y.) after these gabbros formed at the ridge, leading us to conclude that oceanic gabbros record the so-called Vine-Matthews-Morley type of initial magnetization at the ridge. The average intensity value of stable magnetic components of individual samples, which may be a minimum estimate for remanent magnetizations, is 1.6 A/m. Assuming this magnetic intensity value and a uniform magnetization within an oceanic gabbroic layer having a thickness of 4.5 km (i.e., whole layer 3), it is possible to explain most of the marine magnetic anomaly. If magnetic properties of the samples obtained from Hole 735B are common to oceanic gabbros, layer 3 may contribute more significantly to seafloor spreading magnetic anomalies than previously thought.

Geochemistry of Qeqertaa xenoliths

This study presents electron microprobe data for dunite xenoliths from a lamprophyre dyke located on the island of Qeqertaa, West Greenland. The minimum age of this dyke is Palaeoproterozoic and it experienced amphibolite facies metamorphism and deformation during that era. The samples consist of nearly 200 xenoliths with a size range of 0.5-8 cm. These dunite xenoliths have olivine Mg#, that range from 80.3 to 94.6 (n = 579) with a mean of 92.6. Orthopyroxene is found in three xenoliths and garnet in five others. The latter suggests the depth of the Qeqertaa xenolith suite to be near the diamond stability-field, which is substantiated by the finding of diamonds in bulk samples of the Qeqertaa dyke. This further indicates the presence of a lithospheric mantle domain dominated by high-Mg# dunite to this depth in Palaeoproterozoic time. Cr-rich spinel, in the 0.1-0.2 mm size range, is found within and between olivine grains in individual xenoliths. These Cr-spinels yield Fe-Mg exchange temperatures of 400-600°C. However, the presence of intermediate spinel compositions spanning the lower temperature solvus suggests that equilibration temperatures were >550°C. Fe3+#, expressed as 100xFe3+/(Fe3++Al+Cr)), is shown to be a useful parameter in order to screen for altered spinel (Fe3+#>10) with disturbed Mg# and Cr#. The screened spinel data (Fe3+#<10) show a distinctly different trend in terms of spinel Cr# versus Mg#, compared to unmetamorphosed xenoliths in Tertiary lavas and dikes from Ubekendt Ejland and Wiedemann Fjord, respectively, also located within the North Atlantic craton. This difference likely reflects amphibolite facies metamorphic resetting of the Qeqertaa xenolith suite by Fe-Mg exchange. Given the similarity of the Qeqertaa xenolith suite with the Ubekendt and Wiedemann suites, in terms of their olivine Mg# and spinel Cr# distribution, high-Mg# dunite is likely to be an important component of the subcontinental lithospheric mantle beneath the North Atlantic craton and appears to have spanned a vertical distance of at least 150 km in this region, even during the Palaeoproterozoic.