Organic geochemical character of selected cores at DSDP Hole 75-530A

The Albian/Cenomanian strata in Hole 530A are organically richer than are the post-Cenomanian strata. Organic matter is thermally immature and appears to be of dominantly marine origin with either variable levels of oxidation or variable amounts of terrestrial input. Geochemical data alone cannot establish whether the black shales present in Hole 530A represent deposition within a stagnant basin or within an expanded oxygen-minimum layer

Organic geochemical character and hydrocarbon source potential of selected black shales at DSDP Hole 93-603B

LECO analysis, pyrolysis assay, and bitumen and elemental analysis were used to characterize the organic matter of 23 black shale samples from Deep Sea Drilling Project Leg 93, Hole 603B, located in the western North Atlantic. The organic matter is dominantly gas-prone and/or refractory. Two cores within the Turonian and Cenomanian, however, contained significant quantities of well-preserved, hydrogen-enriched, organic matter. This material is thermally immature and represents a potential oil-prone source rock. These sediments do not appear to have been deposited within a stagnant, euxinic ocean as would be consistent with an "oceanic anoxic event." Their organic geochemical and sedimentary character is more consistent with deposition by turbidity currents originating on the continental shelf and slope.

Organic geochemical characteristics at DSDP Holes 76-534A and 44-391C

Pyrolysis assay, bitumen analysis, and elemental analysis of kerogen were used to characterize the organic matter of selected core samples from Hole 534A (Leg 76) and Hole 391C (Leg 44) on the Blake-Bahama Plateau. The organic matter throughout the stratigraphic section appears to be principally of a terrestrial origin. The data from several isolated horizons in the Hatteras and Blake-Bahama Formations imply the presence of significant quantities of autochthonous marine organic matter. However, these horizons appear so limited that they cannot be considered potential liquid hydrocarbon source rocks. All the analyzed samples are immature and have not evolved sufficiently to enter into the main stage of hydrocarbon generation. The temporal and spatial restrictions of strata rich in marine organic matter suggest that they do not represent major expansions and contractions of anoxic bottom-water masses, but represent limited occurrences of anoxic conditions.

Organic- and carbonate-carbon values and extract data for DSDP Holes 63-467 and 63-471

Quantity, type, and maturity of the organic matter of middle Miocene to Quaternary sediments from the eastern North Pacific (Deep Sea Drilling Project Leg 63) were determined. Hydrocarbons and fatty acids in lipid extracts were analyzed by capillary column gas chromatography and combined gas chromatography/mass spectrometry. Kerogens were investigated by Rock-Eval pyrolysis and microscopy, and vitrinite reflectance values were determined. At Site 467, in the San Miguel Gap of the outer California Continental Borderland, organic carbon contents range from 1.46% to 5.40%. Normalized to organic carbon, total extracts increase from about 10 to 36 mg/g Corg with depth. The organic matter is a mixture of both marine and terrestrial origin, with the marine organic matter representing a high proportion in some of the samples. Steroid hydrocarbons - sterenes and steradienes in the upper part of the section and steranes in the deepest sample - are the most abundant compounds in the nonaromatic hydrocarbon fractions. Perylene, alkylated thiophenes, and aromatic steroid hydrocarbons dominate in the aromatic hydrocarbon fractions of the shallower samples; increasing maturation is indicated by a more petroleumlike aromatic hydrocarbon distribution. Microscopy revealed a high amount of liptinitic organic matter and confirmed the maturation trend as observed from analysis of the extracts. The vitrinite reflectance may be extrapolated to a bottom-hole value of nearly 0.5% Ro. The liquid hydrocarbon potential of the sediments at higher maturity levels is rated to be good to excellent. At Site 471, off Baja California, organic carbon values are between 0.70% and 1.12%. Extract values increase with depth, as at Site 467. The investigation of the soluble and insoluble organic matter, despite some compositional similarities, consistently revealed a more terrigenous influx compared with Site 467. Thus the potential for liquid hydrocarbon generation is lower, the organic matter being more gas-prone. The deepest sample analyzed indicates the onset of hydrocarbon generation. At this site, frequent sand intercalations offer pathways for migration and possibly reservoir formation.

Lithology, stratigraphy, organic carbon content, extract and liquid chromatography yields, and Rock-Eval pyrolysis at DSDP Holes 75-530A and 75-532

Seventeen sediment samples of Albian-Cenomanian to early Pliocene age from DSDP Hole 530A in the Angola Basin and six sediment samples of early Pliocene to late Pleistocene age from the Walvis Ridge were investigated by organic geochemical methods, including organic carbon determination, Rock-Eval pyrolysis, gas chromatography and combined gas chromatography/mass spectrometry of extractable hydrocarbons, and kerogen microscopy. The organic matter in all samples is strongly influenced by a terrigenous component from the nearby continent. The amount of marine organic matter present usually increases with the total organic carbon content, which reaches an extreme value of more than 10% in a Cenomanian black shale from Hole 530A. At Site 530 the extent of preservation of organic matter in the deep sea sediments is related to mass transport down the continental slope, whereas the high organic carbon contents in the sediments from Site 532 reflect both high bioproductivity in the Benguela upwelling regime and considerable supply of terrigenous organic matter. The maturation level of the organic matter is low in all samples.

Physiography of the Orca Seamount in the Bransfield Strait, Antarctic Peninsula

Extract from related chapter 5.5.2 in reference: The Orca Seamount was discovered in the central basin of the Bransfield Strait around the posit 62°26'S and 58°24'W on the west side of the Antarctic Peninsula, the most western area of the south polar continent. Through the discovery was made known in 1987, it was only during three bathymetric surveys with high resolution fan echosounders between 1993 and 1995 that the character and complete shape of a remarkable volcano seamount became evident. The data acquisition and processing revealed a spectacular crater of 350 m depth. The relative hight of this 3 km wide "caldera" rim is 550 m with a basal diameter of the seamount cone of 11 km. Its flanks are about 15° steep but in some places the slope reaches up to 36°. The nearly circular shape of the Orca edifice spreads outh with several pronounced spurs, trending parallel to the basin axis in a northeast-southwest direction. The Bransfield Strait is a trough-shaped basin of 400 km length and 2 km depth between the South Shetland Island Arc and the Antarctic Peninsula, formed by rifting behind the islands. The separation of the South Shetland island chain from the peninsula began possibly several million years ago. The active rifting is still going on however, and has caused recent earthquakes and volcanism along the Bransfield Strait. The Strait hosts a chain of submerged seamounts of volcanic origin with the presently inactive Ora Seamount as the most spectacular one. The South Shelfand Island owe their existence to a subduction related volcanism which is perhaps 5-10 times older than the age of Orca and the other seamounts along the central basin of the Bransfield Strait.